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The Allylcalcium Monocation: A Bridging Allyl Ligand with a Non-Bent Coordination GeometryBis(allyl)calciumInsertion of pyridine into the calcium allyl bond: regioselective 1,4-dihydropyridine formation and C-H bond activation.Trimethylsilylmethyl complexes of the rare-earth metals with sterically hindered N-heterocyclic carbene ligands: adduct formation and C-H bond activation.Neutral and cationic aluminium complexes containing a chiral (OSSO)-type bis(phenolato) ligand: synthesis, structures and polymerization activity.Molecular zinc dihydride stabilized by N-heterocyclic carbenes.Selective α-metalation of THF by a cationic zirconium complex supported by an (NNNN)-type macrocyclic ligand.Cationic methyl complexes of the rare-earth metals: an experimental and computational study on synthesis, structure, and reactivity.Enantiomerically pure titanium complexes containing an [OSSO]-type bis(phenolate) ligand: synthesis, structure, and formation of optically active oligostyrenes.Rare-earth metal complexes supported by 1,omega-dithiaalkanediyl-bridged bis(phenolato) ligands: synthesis, structure, and heteroselective ring-opening polymerization of rac-lactide.Synthesis, structure and hydrosilylation activity of neutral and cationic rare-earth metal silanolate complexes.Lanthanide Complexes Supported by a Trizinc-crown Ether as Catalysts for Alternating Copolymerization of Epoxide and CO₂: Telomerization Controlled by Carboxylate Anions.Mononuclear Alkali Metal Organoperoxides Stabilized by an NNNN-Macrocycle and Short Hydrogen Bonds from ROOH Molecules.Reactivity of a Molecular Magnesium Hydride Featuring a Terminal Magnesium-Hydrogen Bond.Unexpected alkane elimination from cationic group 13 dialkyls in a reaction with a macrocyclic polyamine.Silyl-Hydrosilane Exchange at a Magnesium Triphenylsilyl Complex Supported by a Cyclen-Derived NNNN-Type Macrocyclic Ligand.Ligand Influence on Carbonyl Hydroboration Catalysis by Alkali Metal Hydridotriphenylborates [(L)M][HBPh3 ] (M=Li, Na, K).Calcium Hydride Cation [CaH]+ Stabilized by an NNNN-type Macrocyclic Ligand: A Selective Catalyst for Olefin Hydrogenation.Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand.Formate complexes of titanium(iv) supported by a triamido-amine ligand.The Nature of the Heavy Alkaline Earth Metal-Hydrogen Bond: Synthesis, Structure, and Reactivity of a Cationic Strontium Hydride Cluster.Construction of a hybrid biocatalyst containing a covalently-linked terpyridine metal complex within a cavity of aponitrobindin.Ring-opening of cyclic ethers by aluminum hydridotriphenylborate.Formation of a Cationic Calcium Hydride Cluster with a "Naked" Triphenylsilyl Anion by Hydrogenolysis of Bis(triphenylsilyl)calcium.Group 3 metal initiators with an [OSSO]-type bis(phenolate) ligand for the stereoselective polymerization of lactide monomers.Alkali Metal Hydridotriphenylborates [(L)M][HBPh3] (M = Li, Na, K): Chemoselective Catalysts for Carbonyl and CO2 Hydroboration.Formation and Reactivity of a Molecular Magnesium Hydride with a Terminal Mg-H Bond.Lanthanum complexes containing a bis(phenolate) ligand with a ferrocene-1,1'-diyldithio backbone: synthesis, characterization, and ring-opening polymerization of rac-lactide.Magnesium hydridotriphenylborate [Mg(thf)6][HBPh3]2: a versatile hydroboration catalyst.Allyl complexes of scandium: synthesis and structure of neutral, cationic and anionic derivativesMolecular hydrides of divalent ytterbium supported by a macrocyclic ligand: synthesis, structure and olefin hydrofunctionalization catalysisDeprotonation of a formato ligand by a cis-coordinated carbyne ligand within a bis(phenolate) tungsten complexThe effect of bulk magnetic susceptibility on solid state NMR spectra of paramagnetic compoundsCationic, Neutral, and Anionic Allyl Magnesium Compounds: Unprecedented Ligand Conformations and Reactivity Toward Unsaturated HydrocarbonsThe Bis(allyl)bismuth Cation: A Reagent for Direct Allyl Transfer by Lewis Acid Activation and Controlled Radical PolymerizationDimerization of the Allylzinc Cation: Selective Coupling of Allyl Anions in a Metallo-Ene ReactionBis(allyl)zinc Revisited: Sigma versus Pi Bonding of Allyl CoordinationReversible 1,4-Insertion of Pyridine Into a Highly Polar Metal-Carbon Bond: Effect of the Second MetalBis(allyl)gallium Cation, Tris(allyl)gallium, and Tetrakis(allyl)gallate: Synthesis, Characterization, and ReactivityHomogeneous ethylene-polymerization catalysts based on alkyl cations of the rare-earth metals: are dicationic mono(alkyl) complexes the active species?
P50
Q29026563-28F289C8-AB61-4271-A556-2889FD26F03AQ29041420-B3865D95-5FA2-4947-8A0A-C127980B9183Q42909427-F4239891-93E8-4748-AF63-25C650892556Q43081071-7E04C3F5-B46E-44B5-9305-A0A82B255BA7Q43261983-B9378C59-1404-4916-8B1E-6D4B11EB796FQ45834376-C8466B8C-0CE1-4713-AA6B-5179D4FC0F4FQ45923703-EC097538-4D48-4852-99BF-B5C22F770C5EQ46348116-A4C7A1E5-CAA8-4EEB-975D-C4318F981844Q46499019-652072E8-9C27-4CBF-B401-E05A6C962859Q46722328-447BB182-EAFF-4A4F-85B0-8DEF4C6BEA0CQ46931553-5F5A0FB4-1C51-46CC-A1D2-0637EFAD272AQ47206087-8041C683-89B3-4C34-B920-DFA3CD4F9DF1Q48105400-546E2CB1-C06F-4E16-BE61-CD59EE32ACB9Q48143075-56EF9EA3-478A-47A3-B527-2163AF6BC3DFQ48157629-9DD1FA17-0934-45F4-8C72-60E05741524AQ48204926-52190213-DC64-4CA8-99A4-F10DEE9ADD9CQ48253555-B1CB8296-9D3B-4DEB-A47D-77BAAD4ED8FFQ48289299-5FF7BA21-316F-40CE-B414-782862AC3947Q48314064-D7DA4C29-12B2-4ECF-BCF3-B2C227619EF5Q50065656-581D5A83-0964-43A5-AFC5-A3B50941E8E7Q50141220-F47D744E-DFE3-4BA3-8A7C-DA5298B9900CQ51554613-7C70329E-95D9-489B-8023-3129F5B93F64Q52782883-B1E4CBDC-E532-4765-A219-37412AE1552AQ52946736-5905CBCD-E3FC-463A-9017-CC700466B2BDQ53096312-7F6BA0B5-AD82-44E3-8076-8C2D81C8DBB1Q53582650-4C3A69FA-F191-45BB-9521-E46418C1C446Q53635336-E932C142-F996-4C20-8053-8F397FFC6ACCQ53806712-97050C6C-9E96-46E4-95B9-B5F169D7FD4BQ54357741-A7EA5325-7164-46FD-B6D5-A47B547C828AQ56522183-7D3053FD-4ACE-43E6-9C51-EA43D17160D9Q57025598-2966706A-5C4E-472C-940D-2DD682FE9476Q57045699-5A0F4FBA-72F4-4E2B-B988-3BA7FD77B19CQ57102999-BF83BCF0-E357-4988-A323-E169707C9755Q57903839-708245DB-90D2-4B4A-A4D3-749EF8328098Q57903842-08753F84-5A2A-4DFE-8F9A-AC3AB7858D6BQ57903846-B20C5750-DB35-4CF8-A61E-F4ACCF9374B6Q57903848-35E5BFF7-A386-4518-AD6C-6161B4CA4774Q57903852-F9EDD43A-E99C-498E-B9BF-9CFB4947603DQ57903854-0EBC2199-2312-438D-9100-A1CFE0593905Q79243590-B8E0F44E-B479-4A53-A441-9CEEF2578516
P50
description
researcher
@en
name
Spaniol TP
@nl
Thomas Paul Spaniol
@en
type
label
Spaniol TP
@nl
Thomas Paul Spaniol
@en
altLabel
Spaniol TP
@en
prefLabel
Spaniol TP
@nl
Thomas Paul Spaniol
@en
P106
P31
P496
0000-0001-9761-1366