about
Rapid Asymmetric Transfer Hydroformylation (ATHF) of Disubstituted Alkenes Using Paraformaldehyde as a Syngas Surrogate.A convenient catalyst system for microwave accelerated cross-coupling of a range of aryl boronic acids with aryl chloridesHydrogenation of unactivated enamines to tertiary amines: rhodium complexes of fluorinated phosphines give marked improvements in catalytic activity.New phosphine-diamine and phosphine-amino-alcohol tridentate ligands for ruthenium catalysed enantioselective hydrogenation of ketones and a concise lactone synthesis enabled by asymmetric reduction of cyano-ketones.The first organocatalytic carbonyl-ene reaction: isomerisation-free C-C bond formations catalysed by H-bonding thio-ureas.Palladium(II) complexes of new bulky bidentate phosphanes: active and highly regioselective catalysts for the hydroxycarbonylation of styrene.Simultaneous control of regioselectivity and enantioselectivity in the hydroxycarbonylation and methoxycarbonylation of vinyl arenes.Highly enantioselective hydrogenation and transfer hydrogenation of cycloalkyl and heterocyclic ketones catalysed by an iridium complex of a tridentate phosphine-diamine ligand.Palladium-catalysed synthesis of aryl-alkyl ethers using alkoxysilanes as nucleophiles.A mechanistic investigation into the elimination of phosphonium salts from rhodium-TRIPHOS complexes under methanol carbonylation conditions.The electron-poor phosphines P{C6H3(CF3)2-3,5}3 and P(C6F5)3 do not mimic phosphites as ligands for hydroformylation. A comparison of the coordination chemistry of P{C6H3(CF3)2-3,5}3 and P(C6F5)3 and the unexpectedly low hydroformylation activity ofPalladium complexes of new bulky fluorinated diphosphines give particularly active and regioselective catalysts for hydroxycarbonylation of styrene.Mixed-metal MIL-100(Sc,M) (M=Al, Cr, Fe) for Lewis acid catalysis and tandem C-C bond formation and alcohol oxidation.Evaluation of C4 diphosphine ligands in rhodium catalysed methanol carbonylation under a syngas atmosphere: synthesis, structure, stability and reactivity of rhodium(I) carbonyl and rhodium(III) acetyl intermediates.A Highly Active Manganese Catalyst for Enantioselective Ketone and Ester Hydrogenation.Highly regioselective rhodium-catalysed hydroformylation of unsaturated esters: the first practical method for quaternary selective carbonylation.Catalytic constructive deoxygenation of lignin-derived phenols: new C-C bond formation processes from imidazole-sulfonates and ether cleavage reactions.Diastereoselective and Branched-Aldehyde-Selective Tandem Hydroformylation-Hemiaminal Formation: Synthesis of Functionalized Piperidines and Amino Alcohols.A Bifunctional MOF Catalyst Containing Metal-Phosphine and Lewis Acidic Active SitesOn the Functional Group Tolerance of Ester Hydrogenation and Polyester Depolymerisation Catalysed by Ruthenium Complexes of Tridentate Aminophosphine LigandsSelf-assembly of organocatalysts: fine-tuning organocatalytic reactionsHighly enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes using dipalladium complexes as precatalystsEnantioselective hydrogenation and transfer hydrogenation of bulky ketones catalysed by a ruthenium complex of a chiral tridentate ligandAn asymmetric hydroformylation catalyst that delivers branched aldehydes from alkyl alkenesOn the NH effect in ruthenium-catalysed hydrogenation of ketones: rational design of phosphine-amino-alcohol ligands for asymmetric hydrogenation of ketonesConvenient and improved protocols for the hydrogenation of esters using Ru catalysts derived from (P,P), (P,N,N) and (P,N,O) ligandsAsymmetric hydroformylation of an enantiomerically pure bicyclic lactam: efficient synthesis of functionalised cyclopentylaminesRhodium/phospholane-phosphite catalysts give unusually high regioselectivity in the enantioselective hydroformylation of vinyl arenesManganese Catalyzed Hydrogenation of Enantiomerically Pure EstersHigh iso Aldehyde Selectivity in the Hydroformylation of Short-Chain Alkenes
P50
Q41854390-4AB37DCE-E8BE-42B0-995F-E4F5C778A1A9Q42013973-C94D38D8-B27C-48CC-89BE-CA048A3EFA8FQ42100750-70A06FDC-E30D-44ED-B024-999CA4653E95Q42547714-8674D242-D633-4FA8-A18D-386C677EBF30Q42920929-55F58907-1B2D-46E2-96DF-19BD11389D65Q43279314-28E77D68-DB2F-4562-8A3E-F7979B696788Q44094450-41AC5BDA-FD88-4EDE-B00D-EE8D1167EAC6Q44678920-5FB6F37E-2A0D-4117-8B79-CD70D0AF32FDQ45979202-DD0CBC6E-7DE5-4B4A-B7C0-21782FD802E4Q46394631-D1725920-43C9-4552-AC48-DEA606DCFF16Q46396314-588AAEE3-EC01-4844-B192-93EAEF107206Q46669214-287069C9-5FCF-47E9-BF50-3A3FD1BF0A55Q46821095-64C99512-C2E0-43BF-AD11-EEE7FD970A01Q46878427-681BF82E-A38B-42E0-8E05-19C18343CE29Q48255400-402D54A7-8BB9-4D16-9F18-ABE5766AB772Q50714518-5B947E43-74DA-42EF-842B-D921E56E70F1Q53027064-8786FEE0-6A37-433F-AC9B-758EFE45BC30Q53287568-50348BDE-69E3-4230-80F0-786CB1ABB267Q60142648-6BDFDD24-20D8-403A-8842-08106BF802BFQ61943031-8495CB5D-336A-46C8-85F6-FD6D35A8BA84Q79435550-78D2494B-F65C-42AA-B45A-7F875943B331Q82072679-D388D129-7208-4B23-B15A-6389A0B01D4FQ82918336-39D286E4-FBB1-4969-8B01-7011FE2080C9Q83354099-3E037E01-CBF7-4443-B99C-69109423925EQ84488198-23FF6F0A-A655-4B01-8F61-C5718FD888B5Q84529350-883F0923-1B48-455A-AD78-BEB48E3491EDQ85181865-461573BA-06E7-4A03-86F7-1035F73C196EQ86993046-F6AFF0F1-1138-48AC-8C91-23D2BB27D37FQ88405754-FC282171-C1C7-4312-B6C2-B4B2A2E8FAB1Q90612025-841AD4C9-E5A0-46DA-AC96-CF6D63AF6102
P50
description
investigador
@es
researcher
@en
wetenschapper
@nl
name
Matthew L Clarke
@en
Matthew L Clarke
@nl
type
label
Matthew L Clarke
@en
Matthew L Clarke
@nl
prefLabel
Matthew L Clarke
@en
Matthew L Clarke
@nl
P31
P496
0000-0002-2444-1244