about
Mechanistic Investigations of the Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Benzyl Acrylates.Parametrization of Non-covalent Interactions for Transition State Interrogation Applied to Asymmetric Catalysis.Palladium-Catalyzed Enantioselective Redox-Relay Heck Alkynylation of Alkenols To Access Propargylic Stereocenters.The development and mechanistic investigation of a palladium-catalyzed 1,3-arylfluorination of chromenes.Pursuit of Noncovalent Interactions for Strategic Site-Selective CatalysisMultidimensional Correlations in Asymmetric Catalysis through Parameterization of Uncatalyzed Transition States.Ruthenium-Catalyzed C-H Hydroxylation in Aqueous Acid Enables Selective Functionalization of Amine Derivatives.Parameterization of Acyclic Diaminocarbene Ligands Applied to a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization.Enantioselective Synthesis of N,S-Acetals by an Oxidative Pummerer-Type Transformation using Phase-Transfer Catalysis.Quantitative Modeling of Bis(pyridine)silver(I) Permanganate Oxidation of Hydantoin Derivatives: Guidelines for Predicting the Site of Oxidation in Complex Substrates.Physical Organic Approach to Persistent, Cyclable, Low-Potential Electrolytes for Flow Battery Applications.Inverting Conventional Chemoselectivity in Pd-Catalyzed Amine Arylations with Multiply Halogenated Pyridines.Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes.Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines.Parameterization and Analysis of Peptide-Based Catalysts for the Atroposelective Bromination of 3-Arylquinazolin-4(3H)-ones.Formation of Chiral Allylic Ethers via an Enantioselective Palladium-Catalyzed Alkenylation of Acyclic Enol Ethers.Predictive and mechanistic multivariate linear regression models for reaction development.Palladium-Catalyzed Enantioselective Relay Heck Arylation of Enelactams: Accessing α,β-Unsaturated δ-Lactams.Enantioselective fluorination of homoallylic alcohols enabled by the tuning of non-covalent interactionsCombining traditional 2D and modern physical organic-derived descriptors to predict enhanced enantioselectivity for the key aza-Michael conjugate addition in the synthesis of Prevymis™ (letermovir)Enantioselective C2-alkylation of indoles via a redox-relay Heck reaction of 2-indole triflatesMechanistic Study of Ruthenium-Catalyzed C–H Hydroxylation Reveals an Unexpected Pathway for Catalyst ArrestEnantioselective Markovnikov Addition of Carbamates to Allylic Alcohols for the Construction of α-Secondary and α-Tertiary Amines.Correction to "Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines"Mechanism-Based Design of a High-Potential Catholyte Enables a 3.2 V All-Organic Nonaqueous Redox Flow BatteryCorrection to "Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates"Enantioselective Allenoate-Claisen Rearrangement Using Chiral Phosphate CatalystsCorrection to "Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes"Palladium-catalyzed enantioselective alkenylation of alkenylbenzene derivativesA Cancer-Selective Zinc Ionophore Inspired by the Natural Product Naamidine ACatalytic Carbonyl-Olefin Metathesis of Aliphatic Ketones: Iron(III) Homo-Dimers as Lewis Acidic SuperelectrophilesInvestigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) IntermediatesMechanistic Studies into the Oxidative Addition of Co(I) Complexes: Combining Electroanalytical Techniques with ParameterizationPredictive Multivariate Linear Regression Analysis Guides Successful Catalytic Enantioselective Minisci Reactions of DiazinesEnantiodivergent Pd-catalyzed C-C bond formation enabled through ligand parameterizationSite-selective acylation of natural products with BINOL-derived phosphoric acidsEnantioselective construction of remote tertiary carbon-fluorine bondsCorrection to "Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction"Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type ReactionA Physical Organic Approach to Tuning Reagents for Selective and Stable Methionine Bioconjugation
P50
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P50
description
researcher
@en
wetenschapper
@nl
name
Matthew S Sigman
@en
Matthew S Sigman
@nl
type
label
Matthew S Sigman
@en
Matthew S Sigman
@nl
prefLabel
Matthew S Sigman
@en
Matthew S Sigman
@nl
P31
P496
0000-0002-5746-8830