about
A Six-Coordinate Peroxynitrite Low-Spin Iron(III) Porphyrinate Complex-The Product of the Reaction of Nitrogen Monoxide (·NO(g)) with a Ferric-Superoxide Species.Phenol-Induced O-O Bond Cleavage in a Low-Spin Heme-Peroxo-Copper Complex: Implications for O2 Reduction in Heme-Copper Oxidases.Direct Determination of Electron-Transfer Properties of Dicopper-Bound Reduced Dioxygen Species by a Cryo-Spectroelectrochemical Approach.Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-O(peroxo) Breakage versus Reductive O-O Cleavage Chemistry.Substrate and Lewis Acid Coordination Promote O-O Bond Cleavage of an Unreactive L2CuII2(O22-) Species to Form L2CuIII2(O)2 Cores with Enhanced Oxidative Reactivity.Copper(I)/NO(g) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex: Redox Reversal Giving Copper(I)/NO(g) Disproportionation.Synthetic Fe/Cu Complexes: Toward Understanding Heme-Copper Oxidase Structure and FunctionSpin Interconversion of Heme-Peroxo-Copper Complexes Facilitated by Intramolecular Hydrogen-Bonding InteractionsInfluence of intramolecular secondary sphere hydrogen-bonding interactions on cytochrome oxidase inspired low-spin heme-peroxo-copper complexesIntramolecular Hydrogen Bonding Enhances Stability and Reactivity of Mononuclear Cupric Superoxide ComplexesDimethylanilinic N-Oxides and Their Oxygen Surrogacy Role in the Formation of a Putative High-Valent Copper-Oxygen SpeciesCopper(I) Complex Mediated Nitric Oxide Reductive Coupling: Ligand Hydrogen Bonding Derived Proton Transfer Promotes N2O(g) ReleaseHeme-Cu Binucleating Ligand Supports Heme/O2 and FeII-CuI/O2 Reactivity Providing High- and Low-Spin FeIII-Peroxo-CuII ComplexesA mononuclear nonheme {FeNO}6 complex: synthesis and structural and spectroscopic characterizationLigand Identity-Induced Generation of Enhanced Oxidative Hydrogen Atom Transfer Reactivity for a CuII2(O2•-) Complex Driven by Formation of a CuII2(-OOH) Compound with a Strong O-H BondEnhanced Rates of C-H Bond Cleavage by a Hydrogen-Bonded Synthetic Heme High-Valent Iron(IV) Oxo ComplexTuning the Geometric and Electronic Structure of Synthetic High-Valent Heme Iron(IV)-Oxo Models in the Presence of a Lewis Acid and Various Axial LigandsFormation and Reactivity of New Isoporphyrins: Implications for Understanding the Tyr-His Cross-Link Cofactor Biogenesis in Cytochrome c OxidaseDirect Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O2 and NO and Mechanistic Insights into Metal-Mediated Peroxynitrite DecompositionHeme-FeIII Superoxide, Peroxide and Hydroperoxide Thermodynamic Relationships: FeIII-O2•- Complex H-Atom Abstraction ReactivityImpact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O-H and C-H Substrates
P50
Q46014439-2B0AC4D0-CF81-4376-9113-FB0463FDD418Q46188634-14ECB50E-CC07-4DC7-8E06-CEF24E0E5F70Q46274084-F2A1EB33-7366-424D-869B-5DC4971407B2Q46342369-3DCBEA7E-1560-44DD-99C8-F1C00120ACB9Q46418071-55A27044-6907-440F-B4C6-1D9C990AC943Q48216892-71D33803-2F6A-4AB6-9FF9-8B17748E4DC7Q58101818-C54A5643-F304-4E82-984F-5AAAD62F3AB3Q64093719-9AE8C951-F925-449E-8F7D-3224AD96E9A0Q64277534-2E3FF6C9-5518-43E0-AF92-63133CE276BBQ89349196-C1F515B1-897A-4DD5-81C2-46405387F8C9Q90452018-5759DB72-798E-4B9B-A568-03782D8B3832Q90764625-79565FDE-407A-469D-94DF-3399F52958F8Q90969182-84E98EF7-2719-40F5-97BC-D7C848EAA01FQ91419537-5E107950-7394-4681-8F39-BB3142BCB1F7Q91829594-C13AE34A-A723-4C29-B96B-704D54E5923CQ91984796-178165DA-DD63-4707-8C26-26A2518A1BA8Q92298115-A510D0EF-BB4E-4E96-A1F2-498065C9EDEAQ92439036-D5E28496-1080-4710-9524-DCD5CFF7D27EQ92488738-CC5ECE6B-8658-450C-8964-C1477406713DQ92493483-0E233D5A-0689-49BE-8AE9-7D384F191EDEQ93012573-E6CB5582-13A7-4A04-96B4-F8356629EC22
P50
description
researcher
@en
wetenschapper
@nl
name
Kenneth D Karlin
@en
Kenneth D Karlin
@nl
type
label
Kenneth D Karlin
@en
Kenneth D Karlin
@nl
prefLabel
Kenneth D Karlin
@en
Kenneth D Karlin
@nl
P31
P496
0000-0002-5675-7040