sameAs
P185
On the origin of the surprisingly sluggish redox reaction of the N2O/CO couple mediated by [Y2O2]+˙ and [YAlO2]+˙ cluster ions in the gas phaseGas-phase activation of methane by ligated transition-metal cationsDehydrogenation of methanol by vanadium oxide and hydroxide cluster cations in the gas phase.Gas-phase infrared photodissociation spectroscopy of tetravanadiumoxo and oxo-methoxo cluster anions.Two-state reactivity mechanisms of hydroxylation and epoxidation by cytochrome P-450 revealed by theory.Gas-phase catalysis by atomic and cluster metal ions: the ultimate single-site catalysts.Gas-phase reactions of cationic vanadium-phosphorus oxide clusters with C2H(x) (x=4, 6): a DFT-based analysis of reactivity patterns.Mechanistic aspects and elementary steps of N-H bond activation of ammonia and C-N coupling induced by gas-phase ions: a combined experimental/computational exercise.Ion-molecule reactions of "rollover" cyclometalated [Pt(bipy-H)](+) (bipy=2,2'-bipyridine) with dimethyl ether in comparison with dimethyl sulfide: an experimental/computational study.Thermal homo- and heterolytic C-H bond activation of ethane and propane by bare [P(4)O(10)](*+): regioselectivities, kinetic isotope effects, and density functional theory based potential-energy surfaces.Computational exploration of rearrangements related to the vitamin B12-dependent ethanolamine ammonia lyase catalyzed transformation.Car-Parrinello molecular dynamics study of the rearrangement of the valeramide radical cation.Structure and chemistry of the heteronuclear oxo-cluster [VPO4]•+: a model system for the gas-phase oxidation of small hydrocarbons.Decomposition of neutral, singly and doubly protonated benzoquinone in the gas phase.Diastereoselectivity in the McLafferty rearrangement of photoionized 3-methyl valeramide.Pronounced cluster-size effects: gas-phase reactivity of bare vanadium cluster cations V(n)+ (n = 1-7) toward methanol.Control of Product Distribution and Mechanism by Ligation and Electric Field in the Thermal Activation of Methane.Generation of the elusive meta-benzoquinone in the gas phase.Revision of the second ionization energy of toluene.Competitive complexation of gaseous Mn(II) by 1,10-phenanthroline, 2,2'-bipyridine, and 4,5-diazafluorene.Bond Activation by Metal-Carbene Complexes in the Gas Phase.Penetrating the Elusive Mechanism of Copper-Mediated Fluoromethylation in the Presence of Oxygen through the Gas-Phase Reactivity of Well-Defined [LCuO](+) Complexes with Fluoromethanes (CH(4-n)Fn, n = 1-3).Effect of adduct formation with molecular nitrogen on the measured collisional cross sections of transition metal-1,10-phenanthroline complexes in traveling wave ion-mobility spectrometry: N2 is not always an "inert" buffer gas.Gas-phase C-H and N-H bond activation by a high valent nitrido-iron dication and NH-transfer to activated olefins.Gaseous iron(II) and iron(III) complexes with BINOLate ligands.Innocent and less-innocent solvent ligands: a systematic investigation of cationic iron chloride/alcohol complexes by electrospray ionization mass spectrometry complemented by DFT calculations.Structural aspects of long-lived C7H8(2+) dications generated by the electron ionization of toluene.Spin-Selective, Competitive Hydrogen-Atom Transfer versus CH2 O-Generation from the CH4 /[ReO4 ]+ Couple at Ambient Conditions.Relativistic effects in gas-phase ion chemistry: an experimentalist's view.On the Electronic Origin of Remarkable Ligand Effects on the Reactivities of [NiL]+ Complexes (L=C6 H5 , C5 H4 N, CN) towards Methane.Tuning the oxidative power of free iron-sulfur clusters.Scholarly Integrity.Electrostatic and Charge-Induced Methane Activation by a Concerted Double C-H Bond Insertion.Metal-Free, Room-Temperature Oxygen-Atom Transfer in the N2 O/CO Redox Couple as Catalyzed by [Si2 Ox ].+ (x=2-5).Sequential Gas-Phase Activation of Carbon Dioxide and Methane by [Re(CO)2]+: The Sequence of Events Matters!On the Origin of Reactivity Enhancement/Suppression upon Sequential Ligation: [Re(CO)x ]+ /CH4 (x=0-3) Couples.Electronic Origin of the Competitive Mechanisms in the Thermal Activation of Methane by the Heteronuclear Cluster Oxide [Al2 ZnO4 ].Electronic Effects on Room-Temperature, Gas-Phase C-H Bond Activations by Cluster Oxides and Metal Carbides: The Methane Challenge.Metal-Dependent Strengthening and Weakening of M-H and M-C Bonds by an Oxo Ligand: Thermal Gas-Phase Activation of Methane by [OMH]+ and [MH]+ (M=Mo, Ti).Direct Room-temperature Conversion of Methane to Protonated Formaldehyde: the Unique Gas-Phase Chemistry of Mercury Among the Zinc Triad Oxide Cations.
P50
Q28709074-ADD2192E-38A5-4B63-920A-B875CF0BA396Q28756494-B8942A0A-C2AB-48EA-9513-53E594C8D99DQ33281242-34176F1E-498A-4EE3-A29D-2F481E7AE8A5Q33289741-15F922E6-CE59-4E2C-9D2B-0E408016FD5EQ34987326-294353D6-FE91-46B5-ACE2-722A0BE2CC89Q36075427-6291B8AD-101F-43D9-89D9-37D4EF0D56BCQ37094582-4F0C622C-2F39-4B3C-85BD-DED67ED9EDF7Q37965057-3F8FCA73-0763-44B3-AABE-AE3C46C66A19Q43148538-48437935-074D-442E-8ECD-D2B98C3D8FBFQ43271570-2D505B60-CCC1-4CDD-882C-E5EAEACE0D41Q44076667-703B8786-7A0C-4551-8FD5-59CE2D689989Q44591902-FD6FEFE2-946D-4698-AB15-3E7231BBCD98Q44754109-28104518-20E7-457A-B5CB-8A06C5C75971Q45172701-A68236C9-D654-4AB5-87B2-F8060A83606DQ45241534-0986BC04-9D98-4CD1-90BB-362AE3A57780Q46048990-856AED64-F778-4830-8358-1A96B1CF3E0FQ46360848-33329184-3507-43A7-9DD9-49E4D3EBABBBQ46435806-18BD5738-A026-47EA-AD0A-FC5D928AA66BQ46442144-2AF03FA8-1D29-4242-B0B2-E3BAB63175A1Q46583912-7C3A5008-4B9E-447E-A41D-3A82567D0108Q46596899-43B72BBC-1EBF-484D-A9AD-6317DE083506Q46598552-75384390-4EE3-4C6E-9DEE-9672A2AAC0E6Q46668325-56A804C1-45BA-41FE-AC90-D3EBED51E08AQ46712793-FCDE14EC-C1B4-4ACC-A65E-562C533DA809Q46863126-4B592FA5-2F2E-4DCC-8D10-3CD7CD8A75FCQ46885376-218CD8D3-4327-4D0A-8028-793D9400273BQ46970038-F13D882A-A901-4811-9C10-81BBE5281334Q47388367-65CA8849-CBE5-4F60-B191-C5B82B579C71Q47592903-59F26DF5-CEEC-4202-BE2A-22DBD5886F0FQ47725706-C90AD6AB-7442-49A5-BDB8-EB0C827688FAQ48045697-E207707A-5036-4DE2-9BC1-2C72067907A6Q48094600-24031BCA-6BAD-4365-9FBC-C01981A4602CQ48097171-5A7223A2-AFC7-4201-B270-F6C61D000E0AQ48266926-444DE371-0225-4861-B57A-BAD46307AFF1Q48283676-97ECCD59-ED72-4D0C-B323-0335D69E4D9FQ48293959-D797A129-8E76-44FE-83A7-FCFBC5D5C1E0Q48342686-D2CD4AF3-3361-4909-8372-F9BED6E9CAADQ48348945-FE36F24B-5ED8-4964-AD9E-44D07F077BE9Q48370797-4A01573D-D680-4CAE-B720-F17455C47344Q49833999-88C19609-B824-47D2-8824-5015E4D1A6F5
P50
description
Duits scheikundige
@nl
German chemist
@en
German chemist
@en-ca
German chemist
@en-gb
Saksamaa keemik
@et
ceimiceoir Gearmánach
@ga
chimist german
@ro
chimiste allemand
@fr
deutscher Chemiker
@de
kimist gjerman
@sq
name
Helmut Schwarz
@ast
Helmut Schwarz
@ca
Helmut Schwarz
@da
Helmut Schwarz
@de
Helmut Schwarz
@en
Helmut Schwarz
@es
Helmut Schwarz
@fr
Helmut Schwarz
@nb
Helmut Schwarz
@nds
Helmut Schwarz
@nl
type
label
Helmut Schwarz
@ast
Helmut Schwarz
@ca
Helmut Schwarz
@da
Helmut Schwarz
@de
Helmut Schwarz
@en
Helmut Schwarz
@es
Helmut Schwarz
@fr
Helmut Schwarz
@nb
Helmut Schwarz
@nds
Helmut Schwarz
@nl
prefLabel
Helmut Schwarz
@ast
Helmut Schwarz
@ca
Helmut Schwarz
@da
Helmut Schwarz
@de
Helmut Schwarz
@en
Helmut Schwarz
@es
Helmut Schwarz
@fr
Helmut Schwarz
@nb
Helmut Schwarz
@nds
Helmut Schwarz
@nl
P166
P463
P214
P227
P101
P1412
P1559
Helmut Schwarz
@de
P166
P184
P19
P21
P214
P227
P2381
P31
P463
P496
0000-0002-3369-7997