Preparation and Applications of Functionalized Organozinc CompoundsEfficient Synthesis of Functionalized Organozinc Compounds by the Direct Insertion of Zinc into Organic Iodides and BromidesSynthesis of a new class of chiral 1,5-diphosphanylferrocene ligands and their use in enantioselective hydrogenation.Synthesis of well-ordered COF monolayers: surface growth of nanocrystalline precursors versus direct on-surface polycondensation.Convenient electrophilic fluorination of functionalized aryl and heteroaryl magnesium reagents.New Applications of Polyfunctional Organometallic Compounds in Organic Synthesis Frequently used abbreviations are defined at the end of the article.Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.Isoreticular two-dimensional covalent organic frameworks synthesized by on-surface condensation of diboronic acids.One-pot Negishi cross-coupling reactions of in situ generated zinc reagents with aryl chlorides, bromides, and triflates.Synthesis of solid 2-pyridylzinc reagents and their application in Negishi reactionsRegio- and chemoselective metalation of arenes and heteroarenes using hindered metal amide bases.Functionalization of heterocyclic compounds using polyfunctional magnesium and zinc reagents.Oriented thin films of a benzodithiophene covalent organic framework.Selective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives.Synthesis and biological evaluation of novel anticancer bivalent colchicine-tubulizine hybrids.Stereoselective Synthesis and Retentive Trapping of α-Chiral Secondary Alkyllithiums Leading to Stereodefined α,β-Dimethyl Carboxylic Esters.Room temperature synthesis of covalent-organic framework films through vapor-assisted conversion.Stereoselective synthesis of tetrasubstituted alkenes via a sequential carbocupration and a new sulfur-lithium exchange.Preparation of 2-magnesiated 1,3,5-triazines via an iodine-magnesium exchange.Preparation of primary amides from functionalized organozinc halides.Preparation of functionalized cyclic enol phosphates by halogen-magnesium exchange and directed deprotonation reactions.Synthesis of dibenzothiophenes and related classes of heterocycles by using functionalized dithiocarbamates.Phosphorodiamidate-directed metalation of N-heterocycles using Mg- and Zn-TMP bases.Nickel-catalyzed cross-coupling between functionalized primary or secondary alkylzinc halides and primary alkyl halides.Electrophilic aromatic substitutions of aryltrifluoroborates with retention of the BF3- group: quantification of the activating and directing effects of the trifluoroborate group.Substrate-controlled highly diastereoselective synthesis of primary and secondary diorganozinc reagents by hydroboration/boron-zinc exchange sequence.Synthesis of enantiomerically enriched propargylamines by copper-catalyzed addition of alkynes to enamines.Facile and racemization-free conversion of chiral nitriles into pyridine derivatives.Preparation of functionalized indoles and azaindoles by the intramolecular copper-mediated carbomagnesiation of ynamides.t-BuOK-mediated hydrophosphination of functionalized alkenes: a novel synthesis of chiral P,N- and P,P-ligands.Diastereoselective remote C-H activation by hydroboration.Practical highly enantioselective synthesis of terminal propargylamines. An expeditious synthesis of (S)-(+)-coniine.2,3-Functionalization of furans, benzofurans and thiophenes via magnesiation and sulfoxide-magnesium exchange.Metalated N-heterocyclic reagents prepared by the frustrated Lewis pair TMPMgCl·BF3 and their addition to aromatic aldehydes and activated ketones.Kinetics of bromine-magnesium exchange reactions in substituted bromobenzenes.Functionalized alkenylzinc reagents bearing carbonyl groups: preparation by direct metal insertion and reaction with electrophiles.Regio- and chemoselective metalation of chloropyrimidine derivatives with TMPMgCl x LiCl and TMP(2)Zn x 2 MgCl(2) x 2 LiCl.Efficient mono- and bis-functionalization of 3,6-dichloropyridazine using (tmp)2Zn.2MgCl2.2LiCl.Direct zincation of functionalized aromatics and heterocycles by using a magnesium base in the presence of ZnCl2.Full functionalization of the 7-azaindole scaffold by selective metalation and sulfoxide/magnesium exchange.
P50
Q29542165-2366B821-96FE-4DD6-9FAA-9542B6632F71Q29998939-94A4202F-0E57-4C88-85F9-9DDDC8F237D6Q30675571-7AD4C5F0-34B1-488F-A96B-B3612921F51BQ34062941-4F032C97-E6E4-4E7F-88E3-57B8F2446CC0Q34099303-EBE2E6DA-4F88-44F3-9E22-34B4F92117D9Q34136165-F3CDAD73-CBBB-4287-B618-00B92D723142Q34264193-F2270102-FC23-43ED-8947-EB522CD7396BQ34330957-8F13CC45-608F-4985-A92E-9E4E639879F4Q34806886-7DB66DFE-E4F9-4ADE-A655-57A1A95A83BDQ37406502-5BC5CD5D-99E5-4D3B-983E-B4A475D08C7AQ37939746-E2B0CBA1-6CF2-4227-93A0-EFB00FD30037Q37942897-0BA0B5A8-3CB5-476E-8DAB-323EE7937C30Q38587756-8B473F57-9279-4A81-BA01-DF1F25E40FECQ39149980-AB21EEA1-8088-4FB2-81A4-5953F778481CQ39324188-B4FD89F6-8CA4-47C4-8D5F-4A6DC6DFEEE4Q39798948-49A6A861-1D2C-498A-AA47-6B102BDD11B2Q41832391-082C48D7-4AAC-4F16-A96D-502C0240C71BQ42043471-FD04FB1D-AA86-4AB6-9E51-C3DF01FB2334Q42838899-D8F7CD04-906E-4A9A-BBBA-FB2435E47FE7Q42939687-7783801D-DCD2-447D-B1F8-BFB0892511A9Q43043004-E296ED69-5ECD-42BB-B8B1-89C651BED828Q43049371-43D90F02-6515-4194-AB4F-1815C86FAFEBQ43113424-68764848-8788-4604-B140-B438996C7445Q43845477-20FAB699-EF22-4B38-AADB-77BCFCE065CAQ43996356-394A7003-9398-41FA-88F1-A5D1B4ED710AQ44515476-7279D05A-67DF-4C4A-8491-B39A5EF2A844Q44515479-3EDE1E76-92BA-4AD5-8C9B-98940FD5BDD9Q44662889-2C7C4506-AA75-4EE7-9865-C3735A8F0DD3Q44744907-AA575E6E-DFE5-429D-B56D-7939C958208AQ44961135-5CE4CD0F-5374-4C7C-AE8A-052CFD0A03C0Q45047775-7D133768-8F31-4666-9345-F566AC378A27Q45111199-02E4F98C-B344-456E-9B49-46476AA0E7B9Q45971897-371D60FF-DDA6-4773-B92B-477BE10E975CQ46031646-14D38718-E898-4B46-9528-61E069753FFFQ46091012-339DBEEE-974B-40AD-89D8-328B80A9297DQ46140420-248B3E5A-BCAF-4FD9-B717-979449EF18D0Q46179772-EFAEC47B-70FC-43F4-AC34-01A78C472082Q46220014-47859B4C-3C01-43E4-AA35-72B4A37F8CF6Q46227397-9C393ABF-2B9A-4ADB-8DCB-CB67205C0990Q46301155-3AD885D6-E160-43F0-BC18-D415D466FD41
P50
description
Frans scheikundige
@nl
French chemist
@en
French chemist
@en-ca
French chemist
@en-gb
Prantsusmaa keemik
@et
ceimiceoir Francach
@ga
chimico francese
@it
chimist francez
@ro
chimiste français
@fr
deutsch-französischer Chemiker
@de
name
Paul Knochel
@ast
Paul Knochel
@ca
Paul Knochel
@da
Paul Knochel
@de
Paul Knochel
@en
Paul Knochel
@es
Paul Knochel
@fr
Paul Knochel
@hu
Paul Knochel
@it
Paul Knochel
@nds
type
label
Paul Knochel
@ast
Paul Knochel
@ca
Paul Knochel
@da
Paul Knochel
@de
Paul Knochel
@en
Paul Knochel
@es
Paul Knochel
@fr
Paul Knochel
@hu
Paul Knochel
@it
Paul Knochel
@nds
altLabel
Knochel
@de
prefLabel
Paul Knochel
@ast
Paul Knochel
@ca
Paul Knochel
@da
Paul Knochel
@de
Paul Knochel
@en
Paul Knochel
@es
Paul Knochel
@fr
Paul Knochel
@hu
Paul Knochel
@it
Paul Knochel
@nds
P108
P166
P463
P1006
P214
P227
P244
P268
P269
P1006
P1412
P1559
Paul Knochel
@fr
P166
P19
P21
P213
0000 0001 1625 3326