A case study in biomimetic total synthesis: polyolefin carbocyclizations to terpenes and steroids
about
Squalene-hopene cyclasesEnantioselective thiourea-catalyzed cationic polycyclizationsRadicals: Reactive Intermediates with Translational PotentialEvidence that epoxide-opening cascades promoted by water are stepwise and become faster and more selective after the first cyclization.Asymmetric oxidative cation/olefin cyclization of polyenes: evidence for reversible cascade cyclizationElectrophilic Pt(II) complexes: precision instruments for the initiation of transformations mediated by the cation-olefin reaction.Skeletal diversity via cationic rearrangements of substituted dihydropyrans.REGIOSELECTIVE MULTICOMPONENT DOMINO REACTIONS PROVIDING RAPID AND EFFICIENT ROUTES TO FUSED ACRIDINESExploration of cascade cyclizations terminated by tandem aromatic substitution: total synthesis of (+)-schweinfurthin A.Modeling linear and cyclic PKS intermediates through atom replacement.Experimental and theoretical studies on the Nazarov cyclization/Wagner-Meerwein rearrangement sequence.Terminating platinum-initiated cation-olefin reactions with simple alkenes.Carbonyl Activation in Electrophilic Polyene Cyclizations: A Toolbox for the Design of Isoprenoid Libraries.Tetramethyleneethane Equivalents: Recursive Reagents for Serialized Cycloadditions.Reversibility effects on the stereoselectivity of Pt(II)-mediated cascade poly-ene cyclizationsGold(I)-catalyzed formation of bicyclo[4.2.0]oct-1-enes.Cascade cyclizations of acyclic and macrocyclic alkynones: studies toward the synthesis of phomactin A.Computational Studies on the Pt(II)-Catalyzed Cycloisomerization of 1,6-dienes into Bicyclopropanes: A Mechanistic Quandary Evaluated by DFT.A gold-catalysed enantioselective Cope rearrangement of achiral 1,5-dienes.Enantioselective synthesis of an ophiobolin sesterterpene via a programmed radical cascadeFluorine conformational effects in organocatalysis: an emerging strategy for molecular design.C-H activation: a complementary tool in the total synthesis of complex natural products.Transition metal-promoted biomimetic steps in total syntheses.Terpenoid biosynthesis off the beaten track: unconventional cyclases and their impact on biomimetic synthesis.A synthesis of the ABC tricyclic core of the clionastatins serves to corroborate their proposed structures.Stereoselective Halogenation in Natural Product Synthesis.Diastereoselective Pt catalyzed cycloisomerization of polyenes to polycycles.Enantioselective polyene cyclizations.Lupeol and Its Role in Chronic Diseases.Schinortriterpenoids: A Case Study in Synthetic Design.Computational studies on the cyclization of squalene to the steroids and hopenes.β-Amyrin biosynthesis: catalytic mechanism and substrate recognition.Recent applications of the 1,2-carbon atom migration strategy in complex natural product total synthesis.Catalytic Alkene Cyclization Reactions for the Stereoselective Synthesis of Complex "Terpenoid-like" Heterocycles.Bifunctional asymmetric catalysis: amplification of Brønsted basicity can orthogonally increase the reactivity of a chiral Brønsted acid.Highly selective domino multicyclizations for forming polycyclic fused acridines and azaheterocyclic skeletons.Synthesis at the molecular frontier.Enantioselective polyene cyclization via organo-SOMO catalysis.Gold(I)-catalyzed enantioselective polycyclization reactions.Modular Terpenoid Construction via Catalytic Enantioselective Formation of All-Carbon Quaternary Centers: Total Synthesis of Oridamycin A, Triptoquinones B and C, and Isoiresin.
P2860
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P2860
A case study in biomimetic total synthesis: polyolefin carbocyclizations to terpenes and steroids
description
2005 nî lūn-bûn
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2005 թուականի Դեկտեմբերին հրատարակուած գիտական յօդուած
@hyw
2005 թվականի դեկտեմբերին հրատարակված գիտական հոդված
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2005年の論文
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2005年論文
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2005年論文
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2005年論文
@zh-hk
2005年論文
@zh-mo
2005年論文
@zh-tw
2005年论文
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name
A case study in biomimetic tot ...... tions to terpenes and steroids
@ast
A case study in biomimetic tot ...... tions to terpenes and steroids
@en
A case study in biomimetic tot ...... tions to terpenes and steroids
@nl
type
label
A case study in biomimetic tot ...... tions to terpenes and steroids
@ast
A case study in biomimetic tot ...... tions to terpenes and steroids
@en
A case study in biomimetic tot ...... tions to terpenes and steroids
@nl
prefLabel
A case study in biomimetic tot ...... tions to terpenes and steroids
@ast
A case study in biomimetic tot ...... tions to terpenes and steroids
@en
A case study in biomimetic tot ...... tions to terpenes and steroids
@nl
P2860
P3181
P356
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P1476
A case study in biomimetic tot ...... tions to terpenes and steroids
@en
P2093
Jeffrey N Johnston
Ryan A Yoder
P2860
P304
P3181
P356
10.1021/CR040623L
P407
P577
2005-12-01T00:00:00Z