about
The occurrence and representation of three-centre two-electron bonds in covalent inorganic compoundsComputational studies of the unusual water adduct [Cp2TiMe(OH2)](+): the roles of the solvent and the counterion.Pressure-driven formation and stabilization of superconductive chromium hydridesSynthesis, characterization, and photophysical properties of three platinum(II) complexes bearing fluorescent analogues of the Di-2-pyridylmethane ligand.Facile C-H bond cleavage via a proton-coupled electron transfer involving a C-H...Cu(II) interaction.Cross-coupling of C(sp)-H Bonds with Organometallic Reagents via Pd(II)/Pd(0) Catalysis**Characterization of a rhodium(I) sigma-methane complex in solution.Unusual Reactivity of a Potent Platinum-Acridine Hybrid Antitumor AgentThe coordination chemistry of saturated molecules.Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds.Identification of the dominant photochemical pathways and mechanistic insights to the ultrafast ligand exchange of Fe(CO)5 to Fe(CO)4EtOHPd(II)-Catalyzed Cross-Coupling of C(sp(2) )-H Bonds and Alkyl-, Aryl- and Vinyl-Boron Reagents via Pd(II)/Pd(0) CatalysisCrystal structure of bis-(aceto-phenone 4-benzoyl-thio-semicarbazonato-κ(2) N (1),S)nickel(II)Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality.True and masked three-coordinate T-shaped platinum(II) intermediatesThe gold-hydrogen bond, Au-H, and the hydrogen bond to gold, Au∙∙∙H-X.Intramolecular C-C agostic complexes: C-C sigma interactions by another name.Experiment and computation: a combined approach to study the reactivity of palladium complexes in oxidation states 0 to IV.Organometallic synthesis, reactivity and catalysis in the solid state using well-defined single-site speciesAddition of aluminium, zinc and magnesium hydrides to rhodium(iii)Methyl Complexes of the Transition Metals.Planar-chiral ferrocenylphosphine-borane complexes featuring agostic-type B-HE (E = Hg, Sn) interactions.Binuclear β-diketiminate complexes of copper(i).Bis[1-(4-chloro-benz-yl)pyridinium] bis-(1,2,5-thia-diazole-3,4-dithiol-ato)nickelate(II).Characterization of B-H agostic compounds involved in the dehydrogenation of amine-boranes by group 4 metallocenes.Complexes of Ni(i): a "rare" oxidation state of growing importance.Thermochemistry and molecular structure of a remarkable agostic interaction in a heterobifunctional ruthenium-boron complex.Synthesis and Characterization of Dimethylbis(2-pyridyl)borate Nickel(II) Complexes: Unimolecular Square-Planar to Square-Planar Rotation around Nickel(II)Hydrogen bonds to Au atoms in coordinated gold clusters.Exploring the full catalytic cycle of rhodium(i)-BINAP-catalysed isomerisation of allylic amines: a graph theory approach for path optimisation.Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex.Redox and structural properties of mixed-valence models for the active site of the [FeFe]-hydrogenase: progress and challenges.Solid-state molecular organometallic chemistry. Single-crystal to single-crystal reactivity and catalysis with light hydrocarbon substrates.Crystal structure of cis-bis-[4-phenyl-2-(1,2,3,4-tetra-hydro-naphthalen-1-yl-idene)hydrazinecarbo-thio-amidato-κ(2) N (1),S]nickel(II) monohydrate tetra-hydro-furan disolvateCharacterizing pressure-induced uranium C-H agostic bonds.Pd(II)-catalyzed highly selective arylation of allyl esters via C-H functionalization of unreactive arenes with retention of the traditional leaving group.Coordination of neutral, methylene bridged bis-guanidyls at palladium.Isolation of two agostic isomers of an organometallic cation: different structures and colors.Carbonylation of alkyl halides with [Fe(CO)3(NO)]-: in silico identification of a common intermediate.The key role of Au-substrate interactions in catalytic gold subnanoclusters.
P2860
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P2860
description
2007 nî lūn-bûn
@nan
2007 թուականի Ապրիլին հրատարակուած գիտական յօդուած
@hyw
2007 թվականի ապրիլին հրատարակված գիտական հոդված
@hy
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
name
Agostic interactions in transition metal compounds
@ast
Agostic interactions in transition metal compounds
@en
Agostic interactions in transition metal compounds
@nl
type
label
Agostic interactions in transition metal compounds
@ast
Agostic interactions in transition metal compounds
@en
Agostic interactions in transition metal compounds
@nl
prefLabel
Agostic interactions in transition metal compounds
@ast
Agostic interactions in transition metal compounds
@en
Agostic interactions in transition metal compounds
@nl
P2860
P356
P1476
Agostic interactions in transition metal compounds
@en
P2093
Gerard Parkin
Maurice Brookhart
P2860
P304
P356
10.1073/PNAS.0610747104
P407
P577
2007-04-24T00:00:00Z