Hydrogens detected by subatomic resolution protein crystallography in a [NiFe] hydrogenase
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Electrochemical insights into the mechanism of NiFe membrane-bound hydrogenasesHydride bridge in [NiFe]-hydrogenase observed by nuclear resonance vibrational spectroscopy"Newton's cradle" proton relay with amide-imidic acid tautomerization in inverting cellulase visualized by neutron crystallography.[NiFe]-hydrogenases revisited: nickel-carboxamido bond formation in a variant with accrued O2-tolerance and a tentative re-interpretation of Ni-SI statesMechanism of hydrogen activation by [NiFe] hydrogenasesHydrogen atoms can be located accurately and precisely by x-ray crystallographyReactivity of hydride bridges in a high-spin [Fe3(μ-H)3]3+ cluster: reversible H2/CO exchange and Fe-H/B-F bond metathesisPentlandite rocks as sustainable and stable efficient electrocatalysts for hydrogen generation.Photoactivation of the Ni-SIr state to the Ni-SIa state in [NiFe] hydrogenase: FT-IR study on the light reactivity of the ready Ni-SIr state and as-isolated enzyme revisited.A strenuous experimental journey searching for spectroscopic evidence of a bridging nickel-iron-hydride in [NiFe] hydrogenase.Diiron azadithiolates as models for the [FeFe]-hydrogenase active site and paradigm for the role of the second coordination sphereModels of the Ni-L and Ni-SIa States of the [NiFe]-Hydrogenase Active SiteLong-Range Electrostatics-Induced Two-Proton Transfer Captured by Neutron Crystallography in an Enzyme Catalytic Site.Mechanism of H2 Production by Models for the [NiFe]-Hydrogenases: Role of Reduced Hydrides.X-ray dynamical diffraction in amino acid crystals: a step towards improving structural resolution of biological molecules via physical phase measurements.Proton Transfer in the Catalytic Cycle of [NiFe] Hydrogenases: Insight from Vibrational Spectroscopy.Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides.Structure and function of [NiFe] hydrogenases.Mechanistic Insights and Computational Design of Transition-Metal Catalysts for Hydrogenation and Dehydrogenation Reactions.In search of metal hydrides: an X-ray absorption and emission study of [NiFe] hydrogenase model complexes.Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase.Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases.Discovery of Dark pH-Dependent H(+) Migration in a [NiFe]-Hydrogenase and Its Mechanistic Relevance: Mobilizing the Hydrido Ligand of the Ni-C IntermediateRetuning the Catalytic Bias and Overpotential of a [NiFe]-Hydrogenase via a Single Amino Acid Exchange at the Electron Entry/Exit Site.Distal [FeS]-Cluster Coordination in [NiFe]-Hydrogenase Facilitates Intermolecular Electron Transfer.The direct role of selenocysteine in [NiFeSe] hydrogenase maturation and catalysis.Synthetic Models for Nickel-Iron Hydrogenase Featuring Redox-Active Ligands.Computational Design of Iron Diphosphine Complexes with Pendant Amines for Hydrogenation of CO2 to Methanol: A Mimic of [NiFe] Hydrogenase.A Ni(i)Fe(ii) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases.Cofactor composition and function of a H2-sensing regulatory hydrogenase as revealed by Mössbauer and EPR spectroscopy.Why is a proton transformed into a hydride by [NiFe] hydrogenases? An intrinsic reactivity analysis based on conceptual DFT.Experimental and DFT Investigations Reveal the Influence of the Outer Coordination Sphere on the Vibrational Spectra of Nickel-Substituted Rubredoxin, a Model Hydrogenase Enzyme.Equilibrium between inactive ready Ni-SIr and active Ni-SIa states of [NiFe] hydrogenase studied by utilizing Ni-SIr-to-Ni-SIa photoactivation.Dithiolato-bridged nickel-iron complexes as models for the active site of [NiFe]-hydrogenases.Interplay of hemilability and redox activity in models of hydrogenase active sites.Characterization of a Borane σ Complex of a Diiron Dithiolate: Model for an Elusive Dihydrogen Adduct.The structure of hydrogenase-2 from Escherichia coli: implications for H2-driven proton pumping.Comparisons of MN2S2vs. bipyridine as redox-active ligands to manganese and rhenium in (L-L)M'(CO)3Cl complexes.Direct comparison of the performance of a bio-inspired synthetic nickel catalyst and a [NiFe]-hydrogenase, both covalently attached to electrodes.Molecular engineered nanomaterials for catalytic hydrogen evolution and oxidation.
P2860
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P2860
Hydrogens detected by subatomic resolution protein crystallography in a [NiFe] hydrogenase
description
2015 nî lūn-bûn
@nan
2015 թուականի Ապրիլին հրատարակուած գիտական յօդուած
@hyw
2015 թվականի ապրիլին հրատարակված գիտական հոդված
@hy
2015年の論文
@ja
2015年論文
@yue
2015年論文
@zh-hant
2015年論文
@zh-hk
2015年論文
@zh-mo
2015年論文
@zh-tw
2015年论文
@wuu
name
Hydrogens detected by subatomi ...... graphy in a [NiFe] hydrogenase
@ast
Hydrogens detected by subatomi ...... graphy in a [NiFe] hydrogenase
@en
Hydrogens detected by subatomi ...... graphy in a [NiFe] hydrogenase
@nl
type
label
Hydrogens detected by subatomi ...... graphy in a [NiFe] hydrogenase
@ast
Hydrogens detected by subatomi ...... graphy in a [NiFe] hydrogenase
@en
Hydrogens detected by subatomi ...... graphy in a [NiFe] hydrogenase
@nl
prefLabel
Hydrogens detected by subatomi ...... graphy in a [NiFe] hydrogenase
@ast
Hydrogens detected by subatomi ...... graphy in a [NiFe] hydrogenase
@en
Hydrogens detected by subatomi ...... graphy in a [NiFe] hydrogenase
@nl
P2860
P3181
P356
P1433
P1476
Hydrogens detected by subatomi ...... graphy in a [NiFe] hydrogenase
@en
P2093
Hideaki Ogata
Koji Nishikawa
P2860
P2888
P3181
P356
10.1038/NATURE14110
P407
P577
2015-04-23T00:00:00Z
P6179
1007789457