Wherefore Art Thou Copper? Structures and Reaction Mechanisms of Organocuprate Clusters in Organic Chemistry
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Nickel-catalyzed cross-couplings involving carbon-oxygen bondsStructural effects in lithiocuprate chemistry: the elucidation of reactive pentametallic complexes.Low temperature organocopper-mediated two-component cross coupling/cycloisomerization approach toward N-fused heterocycles.Selectivity guidelines and a reductive elimination-based model for predicting the stereochemical course of conjugate addition reactions of organocuprates to gamma-alkoxy-alpha,beta-enoates.Efficient continuous-flow synthesis of novel 1,2,3-triazole-substituted β-aminocyclohexanecarboxylic acid derivatives with gram-scale productionFarewell to the HSAB treatment of ambident reactivity.Copper-catalyzed divergent kinetic resolution of racemic allylic substrates.High-valent organometallic copper and palladium in catalysis.Design, synthesis, and investigation of protein kinase C inhibitors: total syntheses of (+)-calphostin D, (+)-phleichrome, cercosporin, and new photoactive perylenequinones.Perylenequinone natural products: total syntheses of the diastereomers (+)-phleichrome and (+)-calphostin D by assembly of centrochiral and axial chiral fragments.Copper-mediated difluoromethylation of aryl and vinyl iodides.Synthesis and molecular modelling of double-functionalised nucleosides with aromatic moieties in the 5'-(S)-position and minor groove interactions in DNA zipper structures.Preparation of functionalized indoles and azaindoles by the intramolecular copper-mediated carbomagnesiation of ynamides.Intermediates Formed in the Reactions of Organocuprates with α,β-Unsaturated Nitriles.Catalytic Enantioselective Conjugate Alkynylation of α,β-Unsaturated 1,1,1-Trifluoromethyl Ketones with Terminal Alkynes.Copper-Mediated Introduction of the CF2 PO(OEt)2 Motif: Scope and Limitations.Cuprophilic and pi-stacking interactions in the formation of supramolecular stacks from dicoordinate organocopper complexes.Molecular salt effects in the gas phase: tuning the kinetic basicity of [HCCLiCl]⁻ and [HCCMgCl₂]⁻ by LiCl and MgCl₂.Catalytic enantioselective β-alkylation of α,β-unsaturated aldehydes by combination of transition-metal- and aminocatalysis: total synthesis of bisabolane sesquiterpenes.Evidence of Cu(I)/Cu(II) Redox Process by X-ray Absorption and EPR Spectroscopy: Direct Synthesis of Dihydrofurans from β-Ketocarbonyl Derivatives and Olefins.Exploiting the unusual effects of fluorine in methodology.Base-free Knoevenagel condensation catalyzed by copper metal surfaces.Aromatic C–H bond cleavage by using a Cu(i) ate-complexConjugate Additions to Alkylidene Bis(Sulfoxides)Amidocuprates for DirectedorthoCupration: Structural Study, Mechanistic Investigation, and Chemical Requirements
P2860
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P2860
Wherefore Art Thou Copper? Structures and Reaction Mechanisms of Organocuprate Clusters in Organic Chemistry
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2000 nî lūn-bûn
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2000 թուականի Նոյեմբերին հրատարակուած գիտական յօդուած
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2000 թվականի նոյեմբերին հրատարակված գիտական հոդված
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2000年の論文
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2000年論文
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2000年論文
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2000年論文
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2000年論文
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2000年論文
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Wherefore Art Thou Copper? Str ...... Clusters in Organic Chemistry
@ast
Wherefore Art Thou Copper? Str ...... Clusters in Organic Chemistry
@en
Wherefore Art Thou Copper? Str ...... Clusters in Organic Chemistry
@nl
type
label
Wherefore Art Thou Copper? Str ...... Clusters in Organic Chemistry
@ast
Wherefore Art Thou Copper? Str ...... Clusters in Organic Chemistry
@en
Wherefore Art Thou Copper? Str ...... Clusters in Organic Chemistry
@nl
prefLabel
Wherefore Art Thou Copper? Str ...... Clusters in Organic Chemistry
@ast
Wherefore Art Thou Copper? Str ...... Clusters in Organic Chemistry
@en
Wherefore Art Thou Copper? Str ...... Clusters in Organic Chemistry
@nl
P2860
P1433
P1476
Wherefore Art Thou Copper? Str ...... Clusters in Organic Chemistry
@en
P2093
P2860
P304
P356
10.1002/1521-3773(20001103)39:21<3750::AID-ANIE3750>3.0.CO;2-L
P407
P577
2000-11-03T00:00:00Z