Structural and functional analogues of the active sites of the [Fe]-, [NiFe]-, and [FeFe]-hydrogenases
about
Mechanism of nitrogen fixation by nitrogenase: the next stageHydride bridge in [NiFe]-hydrogenase observed by nuclear resonance vibrational spectroscopyCell-free H-cluster synthesis and [FeFe] hydrogenase activation: all five CO and CN⁻ ligands derive from tyrosineAn iron-iron hydrogenase mimic with appended electron reservoir for efficient proton reduction in aqueous mediaSynthesis, Characterization, and Reactivity of Functionalized Trinuclear Iron-Sulfur Clusters - A New Class of Bioinspired Hydrogenase ModelsFrontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixationEnhanced photochemical hydrogen production by a molecular diiron catalyst incorporated into a metal-organic frameworkFrom natural to artificial photosynthesisSingly versus Doubly Reduced Nickel Porphyrins for Proton Reduction: Experimental and Theoretical Evidence for a Homolytic Hydrogen-Evolution ReactionThe influence of oxygen on [NiFe]-hydrogenase cofactor biosynthesis and how ligation of carbon monoxide precedes cyanationTerminal vs bridging hydrides of diiron dithiolates: protonation of Fe2(dithiolate)(CO)2(PMe3)4.Biomimetic peptide-based models of [FeFe]-hydrogenases: utilization of phosphine-containing peptides.Reactivity of hydride bridges in a high-spin [Fe3(μ-H)3]3+ cluster: reversible H2/CO exchange and Fe-H/B-F bond metathesisA model for the CO-inhibited form of [NiFe] hydrogenase: synthesis of CO3Fe(micro-StBu)3Ni{SC6H3-2,6-(mesityl)2} and reversible CO addition at the Ni site.Artificial hydrogenases.Towards artificial leaves for solar hydrogen and fuels from carbon dioxide.Polythiophenes containing in-chain cobaltabisdicarbollide centers.Water splitting by visible light: a nanophotocathode for hydrogen production.An electrochemical study of frustrated Lewis pairs: a metal-free route to hydrogen oxidationProtonation of nickel-iron hydrogenase models proceeds after isomerization at nickel.In vitro hydrogen production--using energy from the sun.Artificial photosynthesis: from molecular catalysts for light-driven water splitting to photoelectrochemical cells.Computational investigation of [FeFe]-hydrogenase models: characterization of singly and doubly protonated intermediates and mechanistic insights.Hydrogen Production Catalyzed by Bidirectional, Biomimetic Models of the [FeFe]-Hydrogenase Active Site.Fe-H/D stretching and bending modes in nuclear resonant vibrational, Raman and infrared spectroscopies: comparisons of density functional theory and experiment.Borane-protected cyanides as surrogates of H-bonded cyanides in [FeFe]-hydrogenase active site models.Metal-metal bonds in biology.N-Substituted Derivatives of the Azadithiolate Cofactor from the [FeFe] Hydrogenases: Stability and ComplexationCatalytic hydrogen oxidation: dawn of a new iron age.{μ-2-[4-(Benzothia-zol-2-yl)benz-yl]-2-aza-propane-1,3-dithiol-ato-1:2κS,S':S,S'}bis-[tricarbonyl-iron(I)]Bis{μ-[4-(1,3-benzothia-zol-2-yl)phen-yl]methane-thiol-ato-κS,S':S,S'}bis-[tricarbonyl-iron(I)](Fe-Fe)Synthesis and Photophysical Study of a [NiFe] Hydrogenase Biomimetic Compound Covalently Linked to a Re-diimine PhotosensitizerElectrocatalytic mechanism of reversible hydrogen cycling by enzymes and distinctions between the major classes of hydrogenases.EPR/ENDOR, Mössbauer, and quantum-chemical investigations of diiron complexes mimicking the active oxidized state of [FeFe]hydrogenase.Connecting [NiFe]- and [FeFe]-hydrogenases: mixed-valence nickel-iron dithiolates with rotated structuresReaction of Aryl Diazonium Salts and Diiron(I) Dithiolato Carbonyls: Evidence for Radical Intermediates.A strenuous experimental journey searching for spectroscopic evidence of a bridging nickel-iron-hydride in [NiFe] hydrogenase.Crystal structure of [μ2-3,3-dimethyl-4-(propan-2-yl-idene)thietane-2,2-dithiol-ato-κ(4) S:S':S:S']bis[tricarbonyl-iron(I)](Fe-Fe)Combining acid-base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase.Stereochemistry of electrophilic attack at 34e⁻ dimetallic complexes: the case of diiron dithiolato carbonyls + MeS⁺.
P2860
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P2860
Structural and functional analogues of the active sites of the [Fe]-, [NiFe]-, and [FeFe]-hydrogenases
description
2009 nî lūn-bûn
@nan
2009 թուականի Յունիսին հրատարակուած գիտական յօդուած
@hyw
2009 թվականի հունիսին հրատարակված գիտական հոդված
@hy
2009年の論文
@ja
2009年論文
@yue
2009年論文
@zh-hant
2009年論文
@zh-hk
2009年論文
@zh-mo
2009年論文
@zh-tw
2009年论文
@wuu
name
Structural and functional anal ...... iFe]-, and [FeFe]-hydrogenases
@ast
Structural and functional anal ...... iFe]-, and [FeFe]-hydrogenases
@en
Structural and functional anal ...... iFe]-, and [FeFe]-hydrogenases
@nl
type
label
Structural and functional anal ...... iFe]-, and [FeFe]-hydrogenases
@ast
Structural and functional anal ...... iFe]-, and [FeFe]-hydrogenases
@en
Structural and functional anal ...... iFe]-, and [FeFe]-hydrogenases
@nl
prefLabel
Structural and functional anal ...... iFe]-, and [FeFe]-hydrogenases
@ast
Structural and functional anal ...... iFe]-, and [FeFe]-hydrogenases
@en
Structural and functional anal ...... iFe]-, and [FeFe]-hydrogenases
@nl
P3181
P356
P1433
P1476
Structural and functional anal ...... iFe]-, and [FeFe]-hydrogenases
@en
P2093
Christopher J Pickett
Cédric Tard
P304
P3181
P356
10.1021/CR800542Q
P407
P577
2009-06-01T00:00:00Z