A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagents
about
Radicals: Reactive Intermediates with Translational PotentialPhotoredox Catalysis in Organic ChemistryRedox-Active Esters in Fe-Catalyzed C-C Coupling.Ni-Catalyzed C-C Couplings Using Alkyl Electrophiles.Transition metal-catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry.Cross-coupling of aromatic esters and amides.Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes.Pd-Catalyzed Decarbonylative Cross-Couplings of Aroyl ChloridesPyridine sulfinates as general nucleophilic coupling partners in palladium-catalyzed cross-coupling reactions with aryl halides.Nickel-Catalyzed Cross-Coupling of Redox-Active Esters with Boronic Acids.Scalable, Electrochemical Oxidation of Unactivated C-H Bonds.Decarboxylative alkenylation.Application of visible-light photosensitization to form alkyl-radical-derived thin films on goldResidue-Specific Peptide Modification: A Chemist's Guide.Metallaphotoredox-catalysed sp(3)-sp(3) cross-coupling of carboxylic acids with alkyl halides.Photoinduced, Copper-Catalyzed Decarboxylative C-N Coupling to Generate Protected Amines: An Alternative to the Curtius Rearrangement.Trifluoromethylation of a Well-Defined Square-Planar Aryl-NiII Complex involving NiIII /CF3. and NiIV -CF3 Intermediate Species.Alkyl-(Hetero)Aryl Bond Formation via Decarboxylative Cross-Coupling: A Systematic Analysis.Photoredox catalysis enabled alkylation of alkenyl carboxylic acids with N-(acyloxy)phthalimide via dual decarboxylation.Ligand-Enabled β-C-H Arylation of α-Amino Acids Without Installing Exogenous Directing Groups.Nickel-Catalyzed Barton Decarboxylation and Giese Reactions: A Practical Take on Classic Transforms.Coupling of Challenging Heteroaryl Halides with Alkyl Halides via Nickel-Catalyzed Cross-Electrophile Coupling.Alkyl Esterification of Vinylarenes Enabled by Visible-Light-Induced Decarboxylation.Iron-Catalyzed Decarboxylative Alkyl Etherification of Vinylarenes with Aliphatic Acids as the Alkyl Source.Transition-Metal-Free Radical C(sp3)-C(sp2) and C(sp3)-C(sp3) Coupling Enabled by 2-Azaallyls as Super-Electron-Donors and Coupling-Partners.Direct assembly of multiply oxygenated carbon chains by decarbonylative radical-radical coupling reactions.Decarboxylative Alkynylation.Practical Alkoxythiocarbonyl Auxiliaries for Iridium(I)-Catalyzed C-H Alkylation of Azacycles.Decarboxylative borylation.Reductive Decarboxylative Alkynylation of N-Hydroxyphthalimide Esters with Bromoalkynes.Deaminative Strategy for the Visible-Light-Mediated Generation of Alkyl Radicals.Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C-N Bond Activation.2-Azadienes as Reagents for Preparing Chiral Amines: Synthesis of 1,2-Amino Tertiary Alcohols by Cu-Catalyzed Enantioselective Reductive Couplings with Ketones.Nickel-catalyzed acetamidation and lactamization of arylboronic acids.Total synthesis of complex terpenoids employing radical cascade processes.Carbodiimide insertion into sulfonimides: one-step route to azepine derivatives via a two-atom saccharin ring expansion.Nickel-Catalyzed Enantioselective Cross-Coupling of N-Hydroxyphthalimide Esters with Vinyl Bromides.Nickel-catalyzed difunctionalization of allyl moieties using organoboronic acids and halides with divergent regioselectivities.Ni-catalysed regioselective 1,2-diarylation of unactivated olefins by stabilizing Heck intermediates as pyridylsilyl-coordinated transient metallacycles.Ni-Catalyzed Electrochemical Decarboxylative C-C Couplings in Batch and Continuous Flow.
P2860
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P2860
A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagents
description
2016 nî lūn-bûn
@nan
2016 թուականի Մայիսին հրատարակուած գիտական յօդուած
@hyw
2016 թվականի մայիսին հրատարակված գիտական հոդված
@hy
2016年の論文
@ja
2016年論文
@yue
2016年論文
@zh-hant
2016年論文
@zh-hk
2016年論文
@zh-mo
2016年論文
@zh-tw
2016年论文
@wuu
name
A general alkyl-alkyl cross-co ...... esters and alkylzinc reagents
@ast
A general alkyl-alkyl cross-co ...... esters and alkylzinc reagents
@en
type
label
A general alkyl-alkyl cross-co ...... esters and alkylzinc reagents
@ast
A general alkyl-alkyl cross-co ...... esters and alkylzinc reagents
@en
prefLabel
A general alkyl-alkyl cross-co ...... esters and alkylzinc reagents
@ast
A general alkyl-alkyl cross-co ...... esters and alkylzinc reagents
@en
P2093
P2860
P3181
P356
P1433
P1476
A general alkyl-alkyl cross-co ...... esters and alkylzinc reagents
@en
P2093
Brad D Maxwell
Jacob T Edwards
Martin D Eastgate
Phil S Baran
Shuhei Kawamura
P2860
P304
P3181
P356
10.1126/SCIENCE.AAF6123
P407
P577
2016-05-13T00:00:00Z