Synthesis and Reactions of Allylic, Allenic, Vinylic, and Arylmetal Reagents from Halides and Esters via Transient Organopalladium Intermediates.
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Organoselenium ligands in catalysis.New chiral synthons for efficient introduction of bispropionates via stereospecific oxonia-cope rearrangementsEnantioselective synthesis of anti- and syn-homopropargyl alcohols via chiral Brønsted acid catalyzed asymmetric allenylboration reactions.Palladium-Catalyzed Modular Synthesis of Substituted Piperazines and Related Nitrogen Heterocycles.Challenges in the synthesis of a unique mono-carboxylic acid antibiotic, (+)-zincophorin.Gram-scale synthesis of iejimalide B.Olefin-Directed Palladium-Catalyzed Regio- and Stereoselective Oxidative Arylation of Allenes.The addition of bromine and iodine to palladacyclopentadienyl complexes bearing bidentate heteroditopic P-N spectator ligands derived from differently substituted quinolinic frames. The unexpected evolution of the reaction.Palladium-Catalyzed Oxidative Carbocyclization-Borylation of Enallenes to Cyclobutenes.Enzyme- and Ruthenium-Catalyzed Enantioselective Transformation of α-Allenic Alcohols into 2,3-Dihydrofurans.Palladium-Catalyzed Oxidative Domino Carbocyclization-Arylation of Bisallenes.Stereoselective one-pot synthesis of polypropionates.Silver-Catalyzed Enantioselective Propargylation Reactions of N-Sulfonylketimines.Thermal cyclization of phenylallenes that contain ortho-1,3-dioxolan-2-yl groups: new cascade reactions initiated by 1,5-hydride shifts of acetalic H atoms.Additions of allenyl/propargyl organometallic reagents to 4-oxoazetidine-2-carbaldehydes: novel palladium-catalyzed domino reactions in allenynes.Outstanding chiroptical properties: a signature of enantiomerically pure alleno-acetylenic macrocycles and monodisperse acyclic oligomers.Synthesis of phenanthrenes and polycyclic heteroarenes by transition-metal catalyzed cycloisomerization reactions.Catalyst- and solvent-dependent stereodivergence in the intramolecular Et(2)Zn/Pd(0) -promoted carbonyl propargylation: mechanistic implications.3-Aza π-allyl palladium derived from imino migration in palladium-carbene: MCRs toward multiple substituted indole skeleton.Palladium-catalyzed insertion of an allene into an aminal: aminomethylamination of allenes by C-N bond activation.Catalytic transient leaving group for atom-economic synthesis of allenes from 2-alkynols.Enantioselective Palladium-Catalyzed Carbonylative Carbocyclization of Enallenes via Cross-Dehydrogenative Coupling with Terminal Alkynes: Efficient Construction of α-Chirality of Ketones.Room temperature transmetallation from tris(pentafluorophenyl)borane to cyclometallated iridium(iii).Palladium-Catalyzed Enantioselective Alkoxycarbonylation of Propargylic Carbonates with (R)- or (S)-3,4,5-(MeO)3 -MeOBIPHEP.Lewis acid-catalyzed unexpected selective C-C bond cleavage: an efficient and mild construction of cyclopentenes.Rhodium(iii)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates.Practical Stannylation of Allyl Acetates Catalyzed by Nickel with Bu3 SnOMe.Temperature-controlled redox-neutral ruthenium(ii)-catalyzed regioselective allylation of benzamides with allylic acetates.Photoredox-catalyzed oxytrifluoromethylation of allenes: stereoselective synthesis of 2-trifluoromethylated allyl acetates.Palladium(0)-catalyzed cross-coupling of 1,1-diboronates with vinyl bromides and 1,1-dibromoalkenes.Fluorous chiral bisoxazolines: application in copper-catalyzed asymmetric α-hydrophosphonylation.Copper-catalyzed synthesis of allenylboronic acids. Access to sterically encumbered homopropargylic alcohols and amines by propargylboration.Diastereoselective Chain-Elongation Reactions Using Microreactors for Applications in Complex Molecule AssemblyReactivity of N-heterocyclic carbene–pyridine palladacyclopentadiene complexes toward halogen addition. The unpredictable course of the reactionStereoselectivity in (Z)-Vinylmetal Additions to the Dictyostatin C1-C9 β-Silyloxy AldehydeHighly Stereoselective Total Synthesis of (+)-9-epi-Dictyostatin and (-)-12,13-Bis-epi-dictyostatinCobalt-catalyzed nucleophilic addition of the allylic C(sp)-H bond of simple alkenes to ketones
P2860
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P2860
Synthesis and Reactions of Allylic, Allenic, Vinylic, and Arylmetal Reagents from Halides and Esters via Transient Organopalladium Intermediates.
description
2000 nî lūn-bûn
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2000 թուականի Օգոստոսին հրատարակուած գիտական յօդուած
@hyw
2000 թվականի օգոստոսին հրատարակված գիտական հոդված
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2000年の論文
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2000年論文
@yue
2000年論文
@zh-hant
2000年論文
@zh-hk
2000年論文
@zh-mo
2000年論文
@zh-tw
2000年论文
@wuu
name
Synthesis and Reactions of All ...... Organopalladium Intermediates.
@ast
Synthesis and Reactions of All ...... Organopalladium Intermediates.
@en
type
label
Synthesis and Reactions of All ...... Organopalladium Intermediates.
@ast
Synthesis and Reactions of All ...... Organopalladium Intermediates.
@en
prefLabel
Synthesis and Reactions of All ...... Organopalladium Intermediates.
@ast
Synthesis and Reactions of All ...... Organopalladium Intermediates.
@en
P356
P1433
P1476
Synthesis and Reactions of All ...... Organopalladium Intermediates.
@en
P2093
J A Marshall
P304
P356
10.1021/CR000003U
P577
2000-08-01T00:00:00Z