about
Tamed arene and heteroarene trifluoromethylation.Taming of fluoroform: direct nucleophilic trifluoromethylation of Si, B, S, and C centers.Long-lived trifluoromethanide anion: a key intermediate in nucleophilic trifluoromethylations.Copper-Catalyzed Aerobic C-H Trifluoromethylation of Phenanthrolines.Rapid and efficient trifluoromethylation of aromatic and heteroaromatic compounds using potassium trifluoroacetate enabled by a flow system.Introduction of fluorine and fluorine-containing functional groups.Recent advances in trifluoromethylation of organic compounds using Umemoto's reagents.Photocatalytic fluoroalkylation reactions of organic compounds.Copper-mediated perfluoroalkylation of heteroaryl bromides with (phen)CuRF.Trifluoromethylation of Heterocycles in Water at Room TemperatureLigand-Controlled Regioselective Copper-Catalyzed Trifluoromethylation To Generate (Trifluoromethyl)allenes.Organocatalyzed Trifluoromethylation of Ketones and Sulfonyl Fluorides by Fluoroform under a Superbase System.Synthesis of Aryldifluoroamides by Copper-Catalyzed Cross-Coupling.Cu-catalyzed trifluoromethylation of aryl iodides with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide.Photochemical Perfluoroalkylation with Pyridine N-Oxides: Mechanistic Insights and Performance on a Kilogram Scale.Merging visible-light photocatalysis and transition-metal catalysis in the copper-catalyzed trifluoromethylation of boronic acids with CF3I.Copper-Catalyzed Synthesis of Trifluoroethylarenes from Benzylic Bromodifluoroacetates.Copper-Catalyzed Decarboxylative Trifluoromethylation of Propargyl Bromodifluoroacetates.Copper(II)-catalyzed trifluoromethylation of N-aryl imines.Direct synthesis of a trifluoromethyl copper reagent from trifluoromethyl ketones: application to trifluoromethylation.Sandmeyer trifluoromethylation of arenediazonium tetrafluoroborates.On Pentakis(pentafluoroethyl)stannate, [Sn(C2 F5 )5 ]- , and the Gas-Free Generation of Pentafluoroethyllithium, LiC2 F5.Two-step conversion of carboxylic esters into distally fluorinated ketones via ring cleavage of cyclopropanol intermediates: application of sulfinate salts as fluoroalkylating reagents.The critical effect of the countercation in the direct cupration of fluoroform with [Cu(OR)2 ](-).Copper-Mediated Aromatic 1,1-Difluoroethylation with (1,1-Difluoroethyl)trimethylsilane (TMSCF2 CH3 ).Oxidative trifluoromethylation of unactivated olefins: an efficient and practical synthesis of α-trifluoromethyl-substituted ketones.Copper-mediated aerobic (phenylsulfonyl)difluoromethylation of arylboronic acids with difluoromethyl phenyl sulfone.Decarboxylative Trifluoromethylating Reagent [Cu(O2 CCF3 )(phen)] and Difluorocarbene Precursor [Cu(phen)2 ][O2 CCF2 Cl].A catalytic fluoride-rebound mechanism for C(sp3)-CF3 bond formation.Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I).The first nucleophilic C-H perfluoroalkylation of aromatic compounds via (arene)tricarbonylchromium complexes.Synthesis and Reactivity of Fluoroalkyl Copper Complexes by the Oxycupration of Tetrafluoroethylene.Metal-catalyzed Decarboxylative Fluoroalkylation Reactions.Direct heptafluoroisopropylation of arylboronic acids via hexafluoropropene (HFP).Lewis Acid Catalyzed Asymmetric Three-Component Coupling Reaction: Facile Synthesis of α-Fluoromethylated Tertiary Alcohols.Easy access to the copper(III) anion [Cu(CF3 )4 ](-).Combination of fluoroalkylation and Kornblum-DeLaMare reaction: a new strategy for the construction of (Z)-β-perfluoroalkyl enaminones.Oxidative trifluoromethylation and fluoroolefination of unactivated olefins.Highly mono-selective ortho-trifluoromethylation of benzamides via 8-aminoquinoline assisted Cu-promoted C-H activations.CuCl-catalyzed ortho trifluoromethylation of arenes and heteroarenes with a pivalamido directing group.
P2860
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P2860
description
2011 nî lūn-bûn
@nan
2011 թուականի Դեկտեմբերին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի դեկտեմբերին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
name
Direct cupration of fluoroform.
@ast
Direct cupration of fluoroform.
@en
type
label
Direct cupration of fluoroform.
@ast
Direct cupration of fluoroform.
@en
prefLabel
Direct cupration of fluoroform.
@ast
Direct cupration of fluoroform.
@en
P2093
P356
P1476
Direct cupration of fluoroform.
@en
P2093
Alessandro Zanardi
Eddy Martin
Maxim A Novikov
Vladimir V Grushin
P304
20901-20913
P356
10.1021/JA2081026
P407
P577
2011-12-02T00:00:00Z