Enantioselective organocatalytic α-fluorination of cyclic ketones.
about
Catalysis for fluorination and trifluoromethylationHow cinchona alkaloid-derived primary amines control asymmetric electrophilic fluorination of cyclic ketones.An in situ directing group strategy for chiral anion phase-transfer fluorination of allylic alcoholsFluoro-substituted ketones from nitriles using acidic and basic reaction conditionsA highly regio- and stereoselective synthesis of α-fluorinated imides via fluorination of chiral enamidesPalladium-catalyzed enantioselective 1,1-fluoroarylation of aminoalkenes.Catalytic Asymmetric Mannich Reactions with Fluorinated Aromatic Ketones: Efficient Access to Chiral β-Fluoroamines.Reagent-controlled enantioselectivity switch for the asymmetric fluorination of β-ketocarbonyls by chiral primary amine catalysis.Cinchona-based primary amine catalysis in the asymmetric functionalization of carbonyl compounds.Introduction of fluorine and fluorine-containing functional groups.Advances in catalytic enantioselective fluorination, mono-, di-, and trifluoromethylation, and trifluoromethylthiolation reactions.Asymmetric palladium-catalyzed directed intermolecular fluoroarylation of styrenes.A Simple Primary Amine Catalyst for Enantioselective α-Hydroxylations and α-Fluorinations of Branched Aldehydes.Forging Fluorine-Containing Quaternary Stereocenters by a Light-Driven Organocatalytic Aldol Desymmetrization ProcessAsymmetric fluorination of α-branched cyclohexanones enabled by a combination of chiral anion phase-transfer catalysis and enamine catalysis using protected amino acids.Enantioselective Palladium-Catalyzed Oxidative β,β-Fluoroarylation of α,β-Unsaturated Carbonyl Derivatives.Regio- and enantioselective aminofluorination of alkenes.Enantioselective organocatalytic fluorination-induced Wagner-Meerwein rearrangement.Homologated amino acids with three vicinal fluorines positioned along the backbone: development of a stereoselective synthesis.Generation of 4-((trifluoromethyl)thio)-2H-benzo[e][1,2]thiazine 1,1-dioxides via a reaction of trifluoromethanesulfanylamide with 2-(2-alkynyl)benzenesulfonamide.Ketones as directing groups in photocatalytic sp3 C-H fluorination.A doubly axially chiral phosphoric acid catalyst for the asymmetric tandem oxyfluorination of enamides.An efficient and practical approach to trifluoromethylthiolation of α-haloketones/α-haloarylmethanes.Intermolecular Palladium-Catalyzed Oxidative Fluorocarbonylation of Unactivated Alkenes: Efficient Access to β-Fluorocarboxylic Esters.Catalytic Enantioselective α-Fluorination of 2-Acyl Imidazoles via Iridium Complexes.Manganese-catalyzed oxidative benzylic C-H fluorination by fluoride ions.Oxidative enantioselective α-fluorination of aliphatic aldehydes enabled by N-heterocyclic carbene catalysis.Synthesis of 3-((trifluoromethyl)thio)indoles via a reaction of 2-alkynylaniline with trifluoromethanesulfanylamide.Reagent-controlled regiodivergent ring expansions of steroids.White Emitters by Tuning the Excited-State Intramolecular Proton-Transfer Fluorescence Emission in 2-(2′-Hydroxybenzofuran)benzoxazole Dyes
P2860
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P2860
Enantioselective organocatalytic α-fluorination of cyclic ketones.
description
2011 nî lūn-bûn
@nan
2011 թուականի Յունուարին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի հունվարին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
name
Enantioselective organocatalytic α-fluorination of cyclic ketones.
@ast
Enantioselective organocatalytic α-fluorination of cyclic ketones.
@en
type
label
Enantioselective organocatalytic α-fluorination of cyclic ketones.
@ast
Enantioselective organocatalytic α-fluorination of cyclic ketones.
@en
prefLabel
Enantioselective organocatalytic α-fluorination of cyclic ketones.
@ast
Enantioselective organocatalytic α-fluorination of cyclic ketones.
@en
P2093
P2860
P356
P1476
Enantioselective organocatalytic α-fluorination of cyclic ketones.
@en
P2093
David W C MacMillan
Jay C Conrad
Piotr Kwiatkowski
Teresa D Beeson
P2860
P304
P356
10.1021/JA111163U
P407
P577
2011-01-19T00:00:00Z