Highly enantioselective copper-catalyzed electrophilic trifluoromethylation of β-ketoesters.
about
Structural reevaluation of the electrophilic hypervalent iodine reagent for trifluoromethylthiolation supported by the crystalline sponge method for X-ray analysisIntroduction of fluorine and fluorine-containing functional groups.Hypervalent iodine: a powerful electrophile for asymmetric α-functionalization of carbonyl compounds.Recent advances in trifluoromethylation of organic compounds using Umemoto's reagents.Recent advances in trifluoromethylation reactions with electrophilic trifluoromethylating reagents.Advances in catalytic enantioselective fluorination, mono-, di-, and trifluoromethylation, and trifluoromethylthiolation reactions.Photo-organocatalytic Enantioselective Perfluoroalkylation of β-Ketoesters.Synthesis and applications of α-trifluoromethylated alkylboron compoundsNitro-enabled catalytic enantioselective formal umpolung alkenylation of β-ketoesters.Towards an asymmetric organocatalytic α-cyanation of β-ketoesters.Copper-mediated deoxygenative trifluoromethylation of benzylic xanthates: generation of a C-CF(3) bond from an O-based electrophile.Copper-boxmi complexes as highly enantioselective catalysts for electrophilic trifluoromethylthiolations.Efficient copper-catalyzed direct intramolecular aminotrifluoromethylation of unactivated alkenes with diverse nitrogen-based nucleophiles.Catalytic asymmetric hydrogenation of α-CF3- or β-CF3-substituted acrylic acids using rhodium(I) complexes with a combination of chiral and achiral ligands.Directing-group-assisted copper-catalyzed olefinic trifluoromethylation of electron-deficient alkenes.Copper-catalyzed trifluoromethylation-cyclization of enynes: highly regioselective construction of trifluoromethylated carbocycles and heterocycles.Oxidative trifluoromethylation of unactivated olefins: an efficient and practical synthesis of α-trifluoromethyl-substituted ketones.Electrophilic trifluoromethylation of carbonyl compounds and their nitrogen derivatives under copper catalysis.Copper-catalyzed trifluoromethylation of N-arylacrylamides "on water" at room temperature.Copper(i)-catalyzed asymmetric exo-selective [3+2] cycloaddition of azomethine ylides with β-trifluoromethyl β,β-disubstituted enones.Mechanism-Based Enantiodivergence in Manganese Reduction Catalysis: A Chiral Pincer Complex for the Highly Enantioselective Hydroboration of Ketones.Magnesium-Catalyzed Electrophilic Trifluoromethylation: Facile Access to All-Carbon Quaternary Centers in Oxindoles.Selective Oxytrifluoromethylation of Allylamines with CO2.Enantioselective Formation of CF3-Bearing All-Carbon Quaternary Stereocenters via C-H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation.Asymmetric conjugate additions of 2-substituted benzofuran-3(2H)-ones to α,β-unsaturated ketones catalyzed by chiral copper complexes.Diastereo- and Enantioselective Copper(I)-Catalyzed Intermolecular [3+2] Cycloaddition of Azomethine Ylides with β-Trifluoromethyl β,β-Disubstituted Enones.An efficient approach for the construction of trifluoromethylated all-carbon quaternary stereocenters: enantioselective Ni(ii)-catalyzed Michael addition of 2-acetyl azaarene to β,β-disubstituted nitroalkenes.Lewis Acid Catalyzed Asymmetric Three-Component Coupling Reaction: Facile Synthesis of α-Fluoromethylated Tertiary Alcohols.Copper-catalyzed trifluoromethylation of trisubstituted allylic and homoallylic alcohols.Highly Enantioselective α-Cyanation with 4-Acetylphenyl Cyanate.Enantioselective electrophilic trifluoromethylthiolation of β-ketoesters: a case of reactivity and selectivity bias for organocatalysis.Radical Desulfur-Fragmentation and Reconstruction of Enol Triflates: Facile Access to α-Trifluoromethyl Ketones.
P2860
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P2860
Highly enantioselective copper-catalyzed electrophilic trifluoromethylation of β-ketoesters.
description
2012 nî lūn-bûn
@nan
2012 թուականի Յունիսին հրատարակուած գիտական յօդուած
@hyw
2012 թվականի հունիսին հրատարակված գիտական հոդված
@hy
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
name
Highly enantioselective copper ...... romethylation of β-ketoesters.
@ast
Highly enantioselective copper ...... romethylation of β-ketoesters.
@en
Highly enantioselective copper ...... romethylation of β-ketoesters.
@nl
type
label
Highly enantioselective copper ...... romethylation of β-ketoesters.
@ast
Highly enantioselective copper ...... romethylation of β-ketoesters.
@en
Highly enantioselective copper ...... romethylation of β-ketoesters.
@nl
prefLabel
Highly enantioselective copper ...... romethylation of β-ketoesters.
@ast
Highly enantioselective copper ...... romethylation of β-ketoesters.
@en
Highly enantioselective copper ...... romethylation of β-ketoesters.
@nl
P2093
P356
P1476
Highly enantioselective copper ...... romethylation of β-ketoesters.
@en
P2093
Hubert Wadepohl
Lutz H Gade
Qing-Hai Deng
P304
10769-10772
P356
10.1021/JA3039773
P407
P577
2012-06-19T00:00:00Z