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Catalytic conversion of nitrogen to ammonia by an iron model complex.

Catalytic conversion of nitrogen to ammonia by an iron model complex.

http://www.wikidata.org/entity/Q34368657

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Mechanism of nitrogen fixation by nitrogenase: the next stage Moving protons and electrons in biomimetic systems Unique behaviour of dinitrogen-bridged dimolybdenum complexes bearing pincer ligand towards catalytic formation of ammonia Nitric oxide activation by distal redox modulation in tetranuclear iron nitrosyl complexes Facile scission of isonitrile carbon-nitrogen triple bond using a diborane(4) reagent.Characterization of an Fe≡N-NH2 Intermediate Relevant to Catalytic N2 Reduction to NH3.The Irony of Iron - Biogenic Iron Oxides as an Iron Source to the Ocean.A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench (57)Fe Mössbauer Data, and a Hydride Resting State Catalytic N2-to-NH3 Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET.Reactivity of hydride bridges in a high-spin [Fe3(μ-H)3]3+ cluster: reversible H2/CO exchange and Fe-H/B-F bond metathesis Ambient nitrogen reduction cycle using a hybrid inorganic-biological system.Insight into the Iron-Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands EPR, ENDOR, and electronic structure studies of the Jahn-Teller distortion in an Fe(V) nitride Alkali metal control over N-N cleavage in iron complexes.Binding of dinitrogen to an iron-sulfur-carbon site Nitrogenase-mimic iron-containing chalcogels for photochemical reduction of dinitrogen to ammonia.Linear and T-Shaped Iron(I) Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis and Structure Characterization.Stepwise N-H Bond Formation From N2-Derived Iron Nitride, Imide and Amide Intermediates to Ammonia.Synthesis, structure and reactivity of Fe(II/III)-NH3 complexes bearing a tripodal sulfonamido ligand.Synthetic biology for the directed evolution of protein biocatalysts: navigating sequence space intelligently.The discovery of Mo(III) in FeMoco: reuniting enzyme and model chemistry.Complexes of ambiphilic ligands: reactivity and catalytic applications.Coordination chemistry insights into the role of alkali metal promoters in dinitrogen reduction.Catalytic NH3 synthesis using N2/H2 at molecular transition metal complexes - concepts for lead structure determination using computational chemistry.Structures, Reactions, and Mechanisms: Stereochemistry in the Broadest Sense at the 51st Bürgenstock Conference.Functional group migrations between boron and metal centres within transition metal-borane and -boryl complexes and cleavage of H-H, E-H and E-E' bonds.N-H Bond Dissociation Enthalpies and Facile H Atom Transfers for Early Intermediates of Fe-N2 and Fe-CN Reductions.Nitrogenase FeMoco investigated by spatially resolved anomalous dispersion refinement.Nitrogenase Cofactor: Inspiration for Model Chemistry.An Fe-N₂ Complex That Generates Hydrazine and Ammonia via Fe═NNH₂: Demonstrating a Hybrid Distal-to-Alternating Pathway for N₂ Reduction.Group 6 metal pentacarbonyl complexes of air-stable primary, secondary, and tertiary ferrocenylethylphosphines.Proton-Coupled Reduction of an Iron Cyanide Complex to Methane and Ammonia.Exploring Electron/Proton Transfer and Conformational Changes in the Nitrogenase MoFe Protein and FeMo-cofactor Through Cryoreduction/EPR Measurements.Low-temperature N2 binding to two-coordinate L2Fe(0) enables reductive trapping of L2FeN2(-) and NH3 generation.Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor.Diiron bridged-thiolate complexes that bind N2 at the Fe(II)Fe(II), Fe(II)Fe(I), and Fe(I)Fe(I) redox states.Evaluating molecular cobalt complexes for the conversion of N2 to NH3 Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation.Exploring secondary-sphere interactions in Fe-N x H y complexes relevant to N2 fixation Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand.

P2860

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P2860

Catalytic conversion of nitrogen to ammonia by an iron model complex.

http://www.wikidata.org/entity/Q34368657

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2013 nî lūn-bûn

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2013 թուականի Սեպտեմբերին հրատարակուած գիտական յօդուած

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2013 թվականի սեպտեմբերին հրատարակված գիտական հոդված

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2013年の論文

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2013年論文

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2013年論文

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2013年論文

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2013年論文

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2013年論文

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2013年论文

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name

Catalytic conversion of nitrogen to ammonia by an iron model complex.

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Catalytic conversion of nitrogen to ammonia by an iron model complex.

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Catalytic conversion of nitrogen to ammonia by an iron model complex.

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type

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Catalytic conversion of nitrogen to ammonia by an iron model complex.

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Catalytic conversion of nitrogen to ammonia by an iron model complex.

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Catalytic conversion of nitrogen to ammonia by an iron model complex.

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Catalytic conversion of nitrogen to ammonia by an iron model complex.

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Catalytic conversion of nitrogen to ammonia by an iron model complex.

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Catalytic conversion of nitrogen to ammonia by an iron model complex.

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Catalytic conversion of nitrogen to ammonia by an iron model complex.

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P2093

John S Anderson

http://www.w3.org/2001/XMLSchema#string

Jonas C Peters

http://www.w3.org/2001/XMLSchema#string

Jonathan Rittle

http://www.w3.org/2001/XMLSchema#string

P2860

How many metals does it take to fix N2? A mechanistic overview of biological nitrogen fixation

Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

Catalytic reduction of dinitrogen to ammonia at a single molybdenum center

Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

Mechanism of Mo-dependent nitrogenase

Molybdenum cofactors, enzymes and pathways.

Mechanism of Molybdenum Nitrogenase.

Terminal iron dinitrogen and iron imide complexes supported by a tris(phosphino)borane ligand.

N₂reduction and hydrogenation to ammonia by a molecular iron-potassium complex.

P2888

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10.1038/NATURE12435

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