Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond.
about
Carbon-carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylationsSynthetic and mechanistic aspects of the regioselective base-mediated reaction of perfluoroalkyl- and perfluoroarylsilanes with heterocyclic N-oxides4-Trifluoromethyl-p-quinols as dielectrophiles: three-component, double nucleophilic addition/aromatization reactions.Advances in catalytic enantioselective fluorination, mono-, di-, and trifluoromethylation, and trifluoromethylthiolation reactions.Radical cascade cyclization of 1,n-enynes and diynes for the synthesis of carbocycles and heterocycles.Ligand-Controlled Regioselective Copper-Catalyzed Trifluoromethylation To Generate (Trifluoromethyl)allenes.Iodine(III) Reagents in Radical ChemistryA scalable and operationally simple radical trifluoromethylation.Organocatalyzed Trifluoromethylation of Ketones and Sulfonyl Fluorides by Fluoroform under a Superbase System.Fluorine-decoupled carbon spectroscopy for the determination of configuration at fully substituted, trifluoromethyl- and perfluoroalkyl-bearing carbons: comparison with 19F-1H heteronuclear Overhauser effect spectroscopy.Catalytic asymmetric synthesis of CF3-substituted tertiary propargylic alcohols via direct aldol reaction of α-N3 amidePhotochemical Perfluoroalkylation with Pyridine N-Oxides: Mechanistic Insights and Performance on a Kilogram Scale.Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF2H-Containing Alcohols.Synthesis of Ethers via Reaction of Carbanions and Monoperoxyacetals.Perfluoroalkylation of Aryl-N,N-dimethyl Hydrazones Using Hypervalent Iodine(III) Reagents or Perfluoroalkyl Iodides.Fluorinated Vinylsilanes from the Copper-Catalyzed Defluorosilylation of Fluoroalkene Feedstocks.Anionic Derivatives of Perfluorinated Trimethylgold.In situ generation and reactions of p-(trifluoromethyl)benzyl electrophiles: an efficient access to p-(trifluoromethyl)benzyl compounds.The Nucleophilicity of Persistent α-Monofluoromethide Anions.Decarboxylative Trifluoromethylating Reagent [Cu(O2 CCF3 )(phen)] and Difluorocarbene Precursor [Cu(phen)2 ][O2 CCF2 Cl].Electrophilic trifluoromethylation of carbonyl compounds and their nitrogen derivatives under copper catalysis.Fluorination of some highly functionalized cycloalkanes: chemoselectivity and substrate dependence.Photoinduced Cobalt(III)-Trifluoromethyl Bond Activation Enables Arene C-H Trifluoromethylation.Palladium-catalyzed regioselective C-H fluoroalkylation of indoles at the C4-position.Trifluoromethylthiolation and Trifluoromethylselenolation of α-Diazo Esters Catalyzed by Copper.Selective and Reversible Fluoride Complexation from Water by a Cyclic Tri(phosphonio)methanide Dication.Azidoperfluoroalkanes: Synthesis and Application in Copper(I)-Catalyzed Azide-Alkyne Cycloaddition.Taming Metal/Fluorine Carbenoids.The Versatile Behavior of Platinum Alkyne Complexes towards XeF2 : Formation of Fluorovinyl and Fluorido Complexes.Divergent synthesis from reactions of 2-trifluoromethyl-1,3-conjugated enynes with N-acetylated 2-aminomalonates.TMSCF3 as a Convenient Source of CF2 =CF2 for Pentafluoroethylation, (Aryloxy)tetrafluoroethylation, and Tetrafluoroethylation.Phenyliodonium diacetate mediated carbotrifluoromethylation of N-acylhydrazones.Synthesis of α-Trifluoromethylated Ketones from Vinyl Triflates in the Absence of External Trifluoromethyl Sources.Palladium-Catalyzed Trifluoromethylation of (Hetero)Arenes with CF3 Br.Cu/Pd Synergistic Dual Catalysis: Asymmetric α-Allylation of an α-CF3 Amide.Preparation, Structure, and Reactivity of Pseudocyclic Benziodoxole Tosylates: New Hypervalent Iodine Oxidants and Electrophiles.A redox-economical synthesis of trifluoromethylated enamides with the Langlois reagent.Perfluoroalkylation of Alkenes by Frustrated Lewis Pairs.The first nucleophilic C-H perfluoroalkylation of aromatic compounds via (arene)tricarbonylchromium complexes.Denitrogenative hydrofluorination of aromatic aldehyde hydrazones using (difluoroiodo)toluene.
P2860
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P2860
Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond.
description
2014 nî lūn-bûn
@nan
2014 թուականի Ապրիլին հրատարակուած գիտական յօդուած
@hyw
2014 թվականի ապրիլին հրատարակված գիտական հոդված
@hy
2014年の論文
@ja
2014年論文
@yue
2014年論文
@zh-hant
2014年論文
@zh-hk
2014年論文
@zh-mo
2014年論文
@zh-tw
2014年论文
@wuu
name
Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond.
@ast
Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond.
@en
Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond.
@nl
type
label
Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond.
@ast
Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond.
@en
Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond.
@nl
prefLabel
Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond.
@ast
Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond.
@en
Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond.
@nl
P2093
P356
P1433
P1476
Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond.
@en
P2093
P304
P356
10.1021/CR400473A
P50
P577
2014-04-22T00:00:00Z