A user-friendly, all-purpose Pd-NHC (NHC=N-heterocyclic carbene) precatalyst for the negishi reaction: a step towards a universal cross-coupling catalyst.
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Rational exploration of N-heterocyclic carbene (NHC) palladacycle diversity: a highly active and versatile precatalyst for Suzuki-Miyaura coupling reactions of deactivated aryl and alkyl substrates.A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes.Studies for the synthesis of marine natural productsHighly enantioselective synthesis of γ-, δ-, and ε-chiral 1-alkanols via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA)-Cu- or Pd-catalyzed cross-coupling.Total synthesis of a noricumazole A library and evaluation of HCV inhibition.Synthesis of a library of fluorescent 2-aryl-3-trifluoromethylnaphthofurans from naphthols by using a sequential pummerer-annulation/cross-coupling strategy and their photophysical properties.Nickel-catalyzed cross-couplings involving carbon-oxygen bondsFacile Access to Sterically Hindered Aryl Ketones via Carbonylative Cross-Coupling: Application to the Total Synthesis of Luteolin.Studies Toward the Syntheses of Pluramycin Natural Products. The First Total Synthesis of Isokidamycin.A new library of arsine, stibine-stabilized N-heterocyclic carbene palladium complexes: synthesis, structures and activities in C-C and C-N coupling reactions.Carbonylative cross-coupling of ortho-disubstituted aryl iodides. convenient synthesis of sterically hindered aryl ketones.Fluorescent oligo and poly-thiophenes and their utilization for recording biological events of diverse origin-when organic chemistry meets biology.The development of bulky palladium NHC complexes for the most-challenging cross-coupling reactions.Insights into the elementary steps in Negishi coupling through kinetic investigations.Imidazolium salts and their polymeric materials for biological applications.Synthesis of Lobeline, Lobelane and their Analogues. A Review.Transition metal-catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry.Cascades of Interrupted Pummerer Reaction-Sigmatropic Rearrangement.Synthesis and evaluation of a series of homologues of lobelane at the vesicular monoamine transporter-2.Trifluoromethylthiolation of aryl iodides and bromides enabled by a bench-stable and easy-to-recover dinuclear palladium(i) catalyst.The preparation of 3-substituted-1,5-dibromopentanes as precursors to heteracyclohexanes.[Pd(Cl)2{P(NC5H10)(C6H11)2}2]--a highly effective and extremely versatile palladium-based Negishi catalyst that efficiently and reliably operates at low catalyst loadings.Exploring nitrogen ligand diversity in trans-N-heterocyclic carbene-amine platinum complexes: synthesis, characterization, and application to fluorescence.Modular synthesis of triarylmethanes through palladium-catalyzed sequential arylation of methyl phenyl sulfone.Preparation of functionalized indoles and azaindoles by the intramolecular copper-mediated carbomagnesiation of ynamides.Is Pd(II)-promoted σ-bond metathesis mechanism operative for the Pd-PEPPSI complex-catalyzed amination of chlorobenzene with aniline? Experiment and theory.Ruthenium complexes of an abnormally bound, anionic N-heterocyclic carbene.New, potentially chelating NHC ligands; synthesis, complexation studies, and preliminary catalytic evaluation.Efficient Synthesis of Diaryl Ketones by Nickel-Catalyzed Negishi Cross-Coupling of Amides by Carbon-Nitrogen Bond Cleavage at Room Temperature Accelerated by a Solvent Effect.Forward molecular design for highly efficient OLED emitters: a theoretical analysis of photophysical properties of platinum(II) complexes with N-heterocyclic carbene ligands.N-heterocyclic carbene Pt(II) complexes from caffeine: synthesis, structures and photoluminescent properties.Nickel-catalyzed cross-coupling of aryltrimethylammonium iodides with organozinc reagents.An alternative approach to PEPPSI catalysts: from palladium isonitriles to highly active unsymmetrically substituted PEPPSI catalysts.Synthesis and characterization of conformationally rigid chiral pyridine-N-heterocyclic carbene-based palladacycles with an unexpected Pd-N bond cleavage.Solid-state structure, solution-state behaviour and catalytic activity of electronically divergent C,N-chelating palladium-N-heterocyclic carbene complexes.Isoxazole-embedded allylic zinc reagent for the diastereoselective preparation of highly functionalized aldol-type derivatives bearing a stereocontrolled quaternary center.Dinuclear NHC-palladium complexes containing phosphine spacers: synthesis, X-ray structures and their catalytic activities towards the Hiyama coupling reaction.Identification of a higher-order organozincate intermediate involved in Negishi cross-coupling reactions by mass spectrometry and NMR spectroscopy.Synthesis of (NHC)Pd(salicylaldimine)Cl complexes through template-directed ortho-aromatic metaloxylation of NHC-palladacycles derived from arylimines.Hindered aryllithium reagents as partners in palladium-catalyzed cross-coupling: synthesis of tri- and tetra-ortho-substituted biaryls under ambient conditions.
P2860
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P2860
A user-friendly, all-purpose Pd-NHC (NHC=N-heterocyclic carbene) precatalyst for the negishi reaction: a step towards a universal cross-coupling catalyst.
description
2006 nî lūn-bûn
@nan
2006 թուականի Յունիսին հրատարակուած գիտական յօդուած
@hyw
2006 թվականի հունիսին հրատարակված գիտական հոդված
@hy
2006年の論文
@ja
2006年論文
@yue
2006年論文
@zh-hant
2006年論文
@zh-hk
2006年論文
@zh-mo
2006年論文
@zh-tw
2006年论文
@wuu
name
A user-friendly, all-purpose P ...... ersal cross-coupling catalyst.
@ast
A user-friendly, all-purpose P ...... ersal cross-coupling catalyst.
@en
A user-friendly, all-purpose P ...... ersal cross-coupling catalyst.
@nl
type
label
A user-friendly, all-purpose P ...... ersal cross-coupling catalyst.
@ast
A user-friendly, all-purpose P ...... ersal cross-coupling catalyst.
@en
A user-friendly, all-purpose P ...... ersal cross-coupling catalyst.
@nl
prefLabel
A user-friendly, all-purpose P ...... ersal cross-coupling catalyst.
@ast
A user-friendly, all-purpose P ...... ersal cross-coupling catalyst.
@en
A user-friendly, all-purpose P ...... ersal cross-coupling catalyst.
@nl
P2093
P356
P1476
A user-friendly, all-purpose P ...... ersal cross-coupling catalyst.
@en
P2093
Christopher J O'Brien
Cory Valente
Eric Assen B Kantchev
Igor Dubovyk
Michael G Organ
Niloufar Hadei
Stephanie Avola
P304
P356
10.1002/CHEM.200600206
P407
P577
2006-06-01T00:00:00Z