Synthesis and properties of allenic natural products and pharmaceuticals.
about
The Renaissance of an Old Problem: Highly Regioselective Carboxylation of 2-Alkynyl Bromides with Carbon Dioxide.Allenes in molecular materials.Reaction of cis-3-chloroacrylic acid dehalogenase with an allene substrate, 2,3-butadienoate: hydration via an enamine.Generation of N-Heterocycles via Tandem Reactions of N '-(2-Alkynylbenzylidene)hydrazides.Organo-manganese η2-auxiliary directed reactions: a diastereoselective approach to 2,3-allenols.3-(4-Chloro-benzo-yl)-6-(4-chloro-phen-yl)-2,4-dimethyl-benzonitrile.Efficient Synthesis of Chiral Trisubstituted 1,2-Allenyl Ketones by Catalytic Asymmetric Conjugate Addition of Malonic Esters to Enynes.Palladium(0)-catalyzed synthesis of chiral ene-allenes using alkenyl trifluoroborates.A C-H bond activation-based catalytic approach to tetrasubstituted chiral allenesPd-catalyzed asymmetric β-hydride elimination en route to chiral allenes.Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut-Currier reaction of allenoates.Exploiting [2+2] cycloaddition chemistry: achievements with allenes.Rapid Asymmetric Synthesis of Disubstituted Allenes by Coupling of Flow-Generated Diazo Compounds and Propargylated AminesAllenyl-β-lactams: versatile scaffolds for the synthesis of heterocycles.Allenes and computational chemistry: from bonding situations to reaction mechanisms.Cyclization reactions of bis(allenes) for the synthesis of polycarbo(hetero)cycles.New preparation and synthetic reactions of 3,3,3-trifluoropropynyllithium, -borate and -stannane: facile synthesis of trifluoromethylated allenes, arylacetylenes and enynes.Structural Revisions of a Class of Natural Products: Scaffolds of Aglycon Analogues of Fusicoccins and Cotylenins Isolated from Fungi.Copper-catalyzed propargylation of diborylmethane.Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.Palladium-Catalyzed Oxidative Domino Carbocyclization-Arylation of Bisallenes.Allenylphosphine oxides as simple scaffolds for phosphinoylindoles and phosphinoylisocoumarins.A cationic gold(I) complex as a general catalyst for the intermolecular hydroamination of alkynes: application to the one-pot synthesis of allenes from two alkynes and a sacrificial amine.Iron-catalyzed Cross-Coupling of Propargyl Carboxylates and Grignard Reagents: Synthesis of Substituted Allenes.Asymmetric Protonation of Cumulenolates: Synthesis of Allenyl Aldehydes Facilitated by an Organomanganese Auxiliary.A Versatile Room-Temperature Route to Di- and Trisubstituted Allenes Using Flow-Generated Diazo Compounds.Stereoretentive Suzuki-Miyaura coupling of haloallenes enables fully stereocontrolled access to (-)-peridininTetrasubstituted allenes by Pd0-catalyzed three-component tandem Michael addition/cross-coupling reaction.Silver(I)-mediated highly enantioselective synthesis of axially chiral allenes under thermal and microwave-assisted conditions.Four new aromatic allenic ethers from the fungus Xylaria sp. No. 2508.Direct α-vinylidenation of aldehydes and subsequent cascade: gold and amine catalysts work synergistically.Synthesis of allene triazole through iron catalyzed regioselective addition to propargyl alcohols.Cadmium iodide-mediated allenylation of terminal alkynes with ketones.Enantioselective decarboxylative amination: synthesis of axially chiral allenyl amines.Alkynyl N-Nosylhydrazones: Easy Decomposition to Alknynl Diazomethanes and Application in Allene Synthesis.NiI Catalyzes the Regioselective Cross-Coupling of Alkylzinc Halides and Propargyl Bromides to Allenes.From allene to allene: a palladium-catalyzed approach to beta-allenyl butenolides and their application to the synthesis of polysubstituted benzene derivatives.The conversion of allenes to strained three-membered heterocycles.Catalytic transient leaving group for atom-economic synthesis of allenes from 2-alkynols.Pd/Cu cooperative catalysis: an efficient synthesis of (3-isoindazolyl)allenes via cross-coupling of 2-alkynyl azobenzenes and terminal alkynes.
P2860
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P2860
Synthesis and properties of allenic natural products and pharmaceuticals.
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年論文
@yue
2004年論文
@zh-hant
2004年論文
@zh-hk
2004年論文
@zh-mo
2004年論文
@zh-tw
2004年论文
@wuu
2004年论文
@zh
2004年论文
@zh-cn
name
Synthesis and properties of allenic natural products and pharmaceuticals.
@ast
Synthesis and properties of allenic natural products and pharmaceuticals.
@en
type
label
Synthesis and properties of allenic natural products and pharmaceuticals.
@ast
Synthesis and properties of allenic natural products and pharmaceuticals.
@en
prefLabel
Synthesis and properties of allenic natural products and pharmaceuticals.
@ast
Synthesis and properties of allenic natural products and pharmaceuticals.
@en
P356
P1476
Synthesis and properties of allenic natural products and pharmaceuticals.
@en
P2093
Anja Hoffmann-Röder
Norbert Krause
P304
P356
10.1002/ANIE.200300628
P407
P577
2004-02-01T00:00:00Z