Asymmetric fluorination, trifluoromethylation, and perfluoroalkylation reactions.
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Selective Pro-Apoptotic Activity of Novel 3,3'-(Aryl/Alkyl-Methylene)Bis(2-Hydroxynaphthalene-1,4-Dione) Derivatives on Human Cancer Cells via the Induction Reactive Oxygen SpeciesImpacts of Conformational Geometries in Fluorinated AlkanesTrisubstituted 2-trifluoromethyl pyrrolidines via catalytic asymmetric Michael addition/reductive cyclization.Copper-catalyzed trifluoromethylation of aryl iodides with potassium (trifluoromethyl)trimethoxyborate.Iridium-catalyzed anti-diastereo- and enantioselective carbonyl (α-trifluoromethyl)allylation from the alcohol or aldehyde oxidation level.A simple method for asymmetric trifluoromethylation of N-acyl oxazolidinones via Ru-catalyzed radical addition to zirconium enolates.An in situ directing group strategy for chiral anion phase-transfer fluorination of allylic alcoholsSynthesis and biological evaluation of new paclitaxel analogs and discovery of potent antitumor agents.Chemo-enzymatic fluorination of unactivated organic compounds.Iridium catalysis: application of asymmetric reductive hydrogenation.Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation.Three-component synthesis of C2F5-substituted pyrazoles from C2F5CH2NH2·HCl, NaNO2 and electron-deficient alkynes.The palladium-catalyzed trifluoromethylation of vinyl sulfonates.A highly regio- and stereoselective synthesis of α-fluorinated imides via fluorination of chiral enamidesAsymmetric synthesis of trifluoromethylated amines via catalytic enantioselective isomerization of imines.Enantioselective nucleophilic difluoromethylation of aromatic aldehydes with Me3SiCF2SO2Ph and PhSO2CF2H reagents catalyzed by chiral quaternary ammonium salts.Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand-zinc(II) complexes.Ultrasonic irradiation assisted efficient regioselective synthesis of CF3-containing pyrazoles catalyzed by Cu(OTf)2/Et3N.Recent developments on the trifluoromethylation of (hetero)arenes.Introduction of fluorine and fluorine-containing functional groups.Stereoselectively fluorinated N-heterocycles: a brief survey.Recent advances in trifluoromethylation reactions with electrophilic trifluoromethylating reagents.18F-labelled intermediates for radiosynthesis by modular build-up reactions: newer developments.Asymmetric palladium-catalyzed directed intermolecular fluoroarylation of styrenes.Various difunctionalizations of acrylamide: an efficient approach to synthesize oxindoles.Development of the titanium-TADDOLate-catalyzed asymmetric fluorination of β-ketoesters.Discovery of Quinoline-Derived Trifluoromethyl Alcohols, Determination of Their in vivo Toxicity and Anticancer Activity in a Zebrafish Embryo Model.Aryl-CF(3) bond-forming reductive elimination from palladium(IV)Fluorine Scanning by Nonselective Fluorination: Enhancing Raf/MEK Inhibition while Keeping Physicochemical Properties.Ruthenium-catalyzed C-C coupling of fluorinated alcohols with allenes: dehydrogenation at the energetic limit of β-hydride elimination.New preparation and synthetic reactions of 3,3,3-trifluoropropynyllithium, -borate and -stannane: facile synthesis of trifluoromethylated allenes, arylacetylenes and enynes.UV light-mediated difunctionalization of alkenes with CF3SO2Na: synthesis of trifluoromethyl phenanthrene and anthrone derivatives.Fluorination-dependent molecular orbital occupancy in ring-shaped perfluorocarbons.DBFOX-Ph/metal complexes: evaluation as catalysts for enantioselective fluorination of 3-(2-arylacetyl)-2-thiazolidinones.Cinchonium Betaines as Efficient Catalysts for Asymmetric Proton Transfer Catalysis: The Development of a Practical Enantioselective Isomerization of Trifluoromethyl Imines.Aminofluorination: transition-metal-free N-F bond insertion into diazocarbonyl compounds.Stereoselective synthesis of alpha,alpha-chlorofluoro carbonyl compounds leading to the construction of fluorinated chiral quaternary carbon centers.Nucleophilic difluoromethylation and difluoromethylenation of aldehydes and ketones using diethyl difluoromethylphosphonate.A convenient catalyst system for microwave accelerated cross-coupling of a range of aryl boronic acids with aryl chloridesPhotoredox catalysis: a mild, operationally simple approach to the synthesis of α-trifluoromethyl carbonyl compounds.
P2860
Q28552362-DBEEF90D-6223-4B54-8134-6FA2F3D09116Q28830233-6C42ACE7-18D1-41B6-AB64-68D501004223Q33572194-D1EF3220-6CB8-40BA-A4AD-3EF1341E116CQ34161203-E12E1D82-742B-43FF-9762-AFDFC2388B2FQ34176496-2E9E56A3-E762-41BC-AAE5-2367629E2220Q34266733-7E660EB3-EE56-4866-9AA6-4C8E635D5CACQ34282632-34EA4F4E-062C-41D0-9AAA-80954775E383Q34728078-D72B35DB-DC7F-4660-9132-F50BD6CA705AQ34881340-9E84DF8F-DF9D-4D27-AEA4-438130015195Q34940130-4DC96B66-E208-41C1-92F7-51A7770142A9Q34987089-B4DD5F27-6007-4DB7-BD84-576AE2056922Q35031035-F0C5F7E7-CC91-4F03-AC50-33AFB4FF4E70Q35623583-AB168ED8-ED6F-44AD-9EB3-13818AE02E48Q35966796-9709C4DC-DD28-4D49-B1BA-28A4A717D31FQ36329439-06F9D851-11EE-476B-BDA7-0DE26CD0585EQ36794113-2A1544DD-B208-418C-B1F7-CEF5DD8C6AD6Q36886848-74B9E553-832A-46A3-BA0B-CAEDD52CF1BCQ36960151-6E455725-33F4-407C-84CB-81384496B3CCQ38020151-C1B69C25-4F01-43CA-B3F9-D15C1B4FC843Q38123135-A1564DC3-6A47-4CFA-8308-169A7167E2ABQ38173757-D4784756-DC98-47B9-95A0-9A0D4DDF6AC1Q38261804-09EC2D84-D37E-4292-AD46-B0A6FDCEC0A4Q38262524-291D909A-8E58-45E0-9465-2200C1DDC226Q38582683-0E0AEEB4-615C-4B80-8CA8-8814E29BF442Q38811495-63DDA15F-2566-4A9F-AEFF-133447E05AEEQ38818941-0D9E2F2D-5915-4AB8-8E3E-3D6E7D43AEACQ38833965-20951AD2-E08D-4FF3-88AA-B3B4AC54F07CQ39400915-3975602C-8BF7-42DD-8E6E-A53644BB43B9Q39779987-44D9FC55-6F56-44FE-8E28-95CDFE144266Q39850599-74AC0207-8014-4769-9866-A0DCF245D2C5Q39959236-A6E28275-F3D4-4A39-9BF5-00F820D7EB20Q40375818-63CBBB52-0177-4BC6-B18C-4B2ED622745DQ40805519-BFCFF906-21F1-456B-8331-B765CA24254AQ40989455-4D5ECCB4-4C93-4E29-90AC-ACB72B85C0A1Q41517469-2FC8A929-ED0C-4311-8CB2-533ED07C025CQ41671219-347BC0FF-259E-4FD5-81FA-1829E04DD0ADQ41791232-F9DB4D22-CC2A-4A7C-B34B-61DA97F203B3Q42005185-8F972387-2B19-4099-9961-AC918C472702Q42013973-ABFBB5D1-4BD9-4C53-B0D8-1B69CFE25EFCQ42096518-99D7E235-C74C-4120-B2D0-1421C55145AC
P2860
Asymmetric fluorination, trifluoromethylation, and perfluoroalkylation reactions.
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年論文
@yue
2004年論文
@zh-hant
2004年論文
@zh-hk
2004年論文
@zh-mo
2004年論文
@zh-tw
2004年论文
@wuu
2004年论文
@zh
2004年论文
@zh-cn
name
Asymmetric fluorination, trifluoromethylation, and perfluoroalkylation reactions.
@ast
Asymmetric fluorination, trifluoromethylation, and perfluoroalkylation reactions.
@en
type
label
Asymmetric fluorination, trifluoromethylation, and perfluoroalkylation reactions.
@ast
Asymmetric fluorination, trifluoromethylation, and perfluoroalkylation reactions.
@en
prefLabel
Asymmetric fluorination, trifluoromethylation, and perfluoroalkylation reactions.
@ast
Asymmetric fluorination, trifluoromethylation, and perfluoroalkylation reactions.
@en
P356
P1433
P1476
Asymmetric fluorination, trifluoromethylation, and perfluoroalkylation reactions.
@en
P2093
Dominique Cahard
P304
P356
10.1021/CR030143E
P577
2004-12-01T00:00:00Z