about
Lytic polysaccharide monooxygenases: a crystallographer's view on a new class of biomass-degrading enzymesElaboration of copper-oxygen mediated C-H activation chemistry in consideration of future fuel and feedstock generationPerturbing the Copper(III)–Hydroxide Unit through Ligand Structural VariationImino-oxy acetic acid dealkylation as evidence for an inner-sphere alcohol intermediate in the reaction catalyzed by peptidylglycine alpha-hydroxylating monooxygenase.CO and O2 binding to pseudo-tetradentate ligand-copper(I) complexes with a variable N-donor moiety: kinetic/thermodynamic investigation reveals ligand-induced changes in reaction mechanism.Generating Cu(II)-oxyl/Cu(III)-oxo species from Cu(I)-alpha-ketocarboxylate complexes and O2: in silico studies on ligand effects and C-H-activation reactivity.Thioether S-ligation in a side-on micro-eta2:eta2-peroxodicopperii complex.Geometric and electronic structure and reactivity of a mononuclear "side-on" nickel(III)-peroxo complex.The copper centers of tyramine β-monooxygenase and its catalytic-site methionine variants: an X-ray absorption study.Synthesis, structural, and spectroscopic characterization and reactivities of mononuclear cobalt(III)-peroxo complexes.Cupric superoxo-mediated intermolecular C-H activation chemistry.The C-H bond activation in 1-ethyl-3-methylimidazolium acetate-copper(II) acetate-water-air (dioxygen) systems.Rapid C-H bond activation by a monocopper(III)-hydroxide complex.Amine oxidative N-dealkylation via cupric hydroperoxide Cu-OOH homolytic cleavage followed by site-specific fenton chemistryDioxygen reactivity of new bispidine-copper complexes.Spectroscopic and computational characterization of CuII-OOR (R = H or cumyl) complexes bearing a Me6-tren ligandFactors that control catalytic two- versus four-electron reduction of dioxygen by copper complexesGeometric and electronic structure of [{Cu(MeAN)}2(μ-η2:η2(O2(2-)))]2+ with an unusually long O-O bond: O-O bond weakening vs activation for reductive cleavage.Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituentKinetics and thermodynamics of formation and electron-transfer reactions of Cu-O2 and Cu2-O2 complexes.Mononuclear nickel(II)-superoxo and nickel(III)-peroxo complexes bearing a common macrocyclic TMC ligand.Mononuclear Cu-O2 complexes: geometries, spectroscopic properties, electronic structures, and reactivityCopper(I)-alpha-ketocarboxylate complexes: characterization and O2 reactions that yield copper-oxygen intermediates capable of hydroxylating arenesPeroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy.Copper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO).Copper-hydroperoxo-mediated N-debenzylation chemistry mimicking aspects of copper monooxygenases.Toluene and ethylbenzene aliphatic C-H bond oxidations initiated by a dicopper(II)-mu-1,2-peroxo complex.Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct.Copper(I)/O2 chemistry with imidazole containing tripodal tetradentate ligands leading to mu-1,2-peroxo-dicopper(II) species.Quantum mechanical calculations suggest that lytic polysaccharide monooxygenases use a copper-oxyl, oxygen-rebound mechanism.Synthesis, characterization, and reactivity of cobalt(III)-oxygen complexes bearing a macrocyclic N-tetramethylated cyclam ligand.Access to a Cu(II)-O-Cu(II) motif: spectroscopic properties, solution structure, and reactivity.Artificial metalloenzymes as catalysts in stereoselective Diels-Alder reactions.Copper/alpha-ketocarboxylate chemistry with supporting peralkylated diamines: reactivity of copper(I) complexes and dicopper-oxygen intermediates.Intermediates in reactions of copper(I) complexes with N-oxides: from the formation of stable adducts to oxo transfer.Cu(I)/O2 chemistry using a β-diketiminate supporting ligand derived from N,N-dimethylhydrazine: a [Cu3O2]3+ complex with novel reactivity.An anionic, tetragonal copper(II) superoxide complex.Effects of electron-deficient beta-diketiminate and formazan supporting ligands on copper(I)-mediated dioxygen activation.Hydrogen atom abstraction from hydrocarbons by a copper(III)-hydroxide complex
P2860
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P2860
description
2006 nî lūn-bûn
@nan
2006年の論文
@ja
2006年学术文章
@wuu
2006年学术文章
@zh-cn
2006年学术文章
@zh-hans
2006年学术文章
@zh-my
2006年学术文章
@zh-sg
2006年學術文章
@yue
2006年學術文章
@zh
2006年學術文章
@zh-hant
name
Mononuclear copper active-oxygen complexes.
@ast
Mononuclear copper active-oxygen complexes.
@en
type
label
Mononuclear copper active-oxygen complexes.
@ast
Mononuclear copper active-oxygen complexes.
@en
prefLabel
Mononuclear copper active-oxygen complexes.
@ast
Mononuclear copper active-oxygen complexes.
@en
P1476
Mononuclear copper active-oxygen complexes.
@en
P2093
Shinobu Itoh
P304
P356
10.1016/J.CBPA.2006.02.012
P577
2006-02-28T00:00:00Z