Catalytic enantioselective synthesis of quaternary carbon stereocentres
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Catalytic enantioselective 1,6-conjugate additions of propargyl and allyl groupsRh-Catalyzed Desymmetrization of α-Quaternary Centers by Isomerization-Hydroacylation.Nonenzymatic enantioselective synthesis of all-carbon quaternary centers through desymmetrization.Asymmetric copper-catalyzed C-N cross-couplings induced by visible lightRhodium-Catalyzed Enantioselective Cycloisomerization to Cyclohexenes Bearing Quaternary Carbon CentersDirect Catalytic Asymmetric Mannich Reactions for the Construction of Quaternary Carbon Stereocenters.Iridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic α-Alkoxy Ketones.Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols To Form Allylic Quaternary Centers.The Enantioselective Total Synthesis of Exochomine.Direct construction of vicinal all-carbon quaternary stereocenters in natural product synthesis.Total syntheses of natural products containing spirocarbocycles.Enantioselective syntheses of indanes: from organocatalysis to C-H functionalization.Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon AtomsAdvances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.Upstream biomanufacturing of pharmaceutical colchicine.Catalytic Enantioselective Conjugate Additions of (pin)B-Substituted Allylcopper Compounds Generated in situ from Butadiene or Isoprene.Stereochemical inversion of (S)-reticuline by a cytochrome P450 fusion in opium poppy.Modular, Catalytic Enantioselective Construction of Quaternary Carbon Stereocenters by Sequential Cross-Coupling Reactions.Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes.Concise Enantioselective Synthesis of Oxygenated Steroids via Sequential Copper(II)-Catalyzed Michael Addition/Intramolecular Aldol Cyclization Reactions.Enantioselective allylic alkylation of stereodefined polysubstituted copper enolates as an entry to acyclic quaternary carbon stereocentres.Acyclic quaternary centers from asymmetric conjugate addition of alkylzirconium reagents to linear trisubstituted enones.Efficient syntheses of (-)-crinine and (-)-aspidospermidine, and the formal synthesis of (-)-minfiensine by enantioselective intramolecular dearomative cyclization.Nitro-enabled catalytic enantioselective formal umpolung alkenylation of β-ketoesters.Studies on the Enantioselective Iminium Ion Trapping of Radicals Triggered by an Electron-Relay Mechanism.Ni-Catalyzed Enantioselective C-Acylation of α-Substituted LactamsA unique Pd-catalysed Heck arylation as a remote trigger for cyclopropane selective ring-openingAsymmetric addition of α-branched cyclic ketones to allenamides catalyzed by a chiral phosphoric acid.Enantioselective Formation of All-Carbon Quaternary Centers via C-H Functionalization of Methanol: Iridium-Catalyzed Diene Hydrohydroxymethylation.Diastereo- and enantioselective [3 + 3] cycloaddition of spirocyclopropyl oxindoles using both aldonitrones and ketonitrones.Asymmetric Synthesis of All-Carbon Quaternary Spirocycles via a Catalytic Enantioselective Allylic Alkylation Strategy.Iridium-Catalyzed Stereoselective Allylic Alkylation Reactions with Crotyl Chloride.Sequential Ruthenium Catalysis for Olefin Isomerization and Oxidation: Application to the Synthesis of Unusual Amino Acids.Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.Mizoroki-Heck Cyclizations of Amide Derivatives for the Introduction of Quaternary Centers.Lithium Enolates in the Enantioselective Construction of Tetrasubstituted Carbon Centers with Chiral Lithium Amides as Noncovalent Stereodirecting Auxiliaries.Diastereodivergent organocatalysis for the asymmetric synthesis of chiral annulated furans.Nickel-Catalyzed Asymmetric Reductive Heck Cyclization of Aryl Halides to Afford Indolines.Enantioselective Synthesis of Acyclic α-Quaternary Carboxylic Acid Derivatives through Iridium-Catalyzed Allylic Alkylation.Organocatalytic, Asymmetric Total Synthesis of (-)-Haliclonin A.
P2860
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P2860
Catalytic enantioselective synthesis of quaternary carbon stereocentres
description
2014 nî lūn-bûn
@nan
2014年の論文
@ja
2014年学术文章
@wuu
2014年学术文章
@zh-cn
2014年学术文章
@zh-hans
2014年学术文章
@zh-my
2014年学术文章
@zh-sg
2014年學術文章
@yue
2014年學術文章
@zh
2014年學術文章
@zh-hant
name
Catalytic enantioselective synthesis of quaternary carbon stereocentres
@ast
Catalytic enantioselective synthesis of quaternary carbon stereocentres
@en
type
label
Catalytic enantioselective synthesis of quaternary carbon stereocentres
@ast
Catalytic enantioselective synthesis of quaternary carbon stereocentres
@en
prefLabel
Catalytic enantioselective synthesis of quaternary carbon stereocentres
@ast
Catalytic enantioselective synthesis of quaternary carbon stereocentres
@en
P2860
P356
P1433
P1476
Catalytic enantioselective synthesis of quaternary carbon stereocentres
@en
P2093
Kyle W Quasdorf
P2860
P2888
P304
P356
10.1038/NATURE14007
P407
P577
2014-12-01T00:00:00Z
P6179
1022261759