Characterization of Porphyrin-Co(III)-'Nitrene Radical' Species Relevant in Catalytic Nitrene Transfer Reactions. - Test2 - elhamkhani - TriplyDB

Characterization of Porphyrin-Co(III)-'Nitrene Radical' Species Relevant in Catalytic Nitrene Transfer Reactions.

Characterization of Porphyrin-Co(III)-'Nitrene Radical' Species Relevant in Catalytic Nitrene Transfer Reactions.

http://www.wikidata.org/entity/Q36570787

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Homolytic N-H activation of ammonia: hydrogen transfer of parent iridium ammine, amide, imide, and nitride species.Catalytic Synthesis of N-Heterocycles via Direct C(sp3)-H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand.A Stable Aminyl Radical Coordinated to Cobalt.Metal-Catalysed Azidation of Organic Molecules Cobalt-Porphyrin-Catalysed Intramolecular Ring-Closing C-H Amination of Aliphatic Azides: A Nitrene-Radical Approach to Saturated Heterocycles.Intramolecular Radical Aziridination of Allylic Sulfamoyl Azides by Cobalt(II)-Based Metalloradical Catalysis: Effective Construction of Strained Heterobicyclic Structures.Metal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and Benzenes Nitrene Radical Intermediates in Catalytic Synthesis.Direct Comparison of C-H Bond Amination Efficacy through Manipulation of Nitrogen-Valence Centered Redox: Imido versus Iminyl.Mechanistic insights into intramolecular ortho-amination/hydroxylation by nonheme FeIV[double bond, length as m-dash]NTs/FeIV[double bond, length as m-dash]O species: the σ vs. the π channels.Porphyrin Cobalt(III) "Nitrene Radical" Reactivity; Hydrogen Atom Transfer from Ortho-YH Substituents to the Nitrene Moiety of Cobalt-Bound Aryl Nitrene Intermediates (Y = O, NH).Cobalt(ii)-catalyzed bis-isocyanide insertion reactions with sulfonyl azides via nitrene radicals: chemoselective synthesis of sulfonylamidyl amide and 3-imine indole derivatives.Electronic Structures of Mono-Oxidized Copper and Nickel Phosphasalen Complexes.Asymmetric Radical Bicyclization of Allyl Azidoformates via Cobalt(II)-Based Metalloradical Catalysis.Difluorocarbene transfer from a cobalt complex to an electron-deficient alkene.A Two-Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis, Structure, and Reactivity.An iridium(iii/iv/v) redox series featuring a terminal imido complex with triplet ground state.Hydroformylation of 1-Octene Mediated by the Cobalt Complex [CoH(dchpf)(CO)2]EPR Spectroscopy as a Tool in Homogeneous Catalysis Research Synthesis, characterisation and catalytic use of iron porphyrin amino ester conjugates

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P2860

Characterization of Porphyrin-Co(III)-'Nitrene Radical' Species Relevant in Catalytic Nitrene Transfer Reactions.

http://www.wikidata.org/entity/Q36570787

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Characterization of Porphyrin- ...... ic Nitrene Transfer Reactions.

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Journal of the American Chemical Society

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Characterization of Porphyrin- ...... ic Nitrene Transfer Reactions.

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Edward J Reijerse

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Florian Felix Pfaff

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Hongjian Lu

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Ivana Ivanović-Burmazović

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Kallol Ray

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Oliver Troeppner

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Sander Woutersen

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Serena DeBeer

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Volodymyr Lyaskovskyy

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Wybren Jan Buma

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P2860

Chemistry. Radical ligands confer nobility on base-metal catalysts

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

Molecular and Electronic Structures of Bis(pyridine-2,6-diimine)metal Complexes [ML2](PF6)n(n= 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn)†

Redox Noninnocence of Carbene Ligands: Carbene Radicals in (Catalytic) C−C Bond Formation

Lewis acid trapping of an elusive copper-tosylnitrene intermediate using scandium triflate.

Experimental evidence for cobalt(III)-carbene radicals: key intermediates in cobalt(II)-based metalloradical cyclopropanation.

High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions.

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Recent advances in transition metal-catalyzed N-atom transfer reactions of azides

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16

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137

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Sérgio R Domingos

Monalisa Goswami

Matti M van Schooneveld

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