Hydrogen-bonding effects on the reactivity of [X-Fe(III)-O-Fe(IV)═O] (X = OH, F) complexes toward C-H bond cleavage.
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High-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic Fe(IV)=O Complexes.Toward the synthesis of more reactive S = 2 non-heme oxoiron(IV) complexes.Magnetic circular dichroism and computational study of mononuclear and dinuclear iron(IV) complexes.[CuO](+) and [CuOH](2+) complexes: intermediates in oxidation catalysis?Spectroscopic and theoretical investigation of a complex with an [O═Fe(IV)-O-Fe(IV)═O] core related to methane monooxygenase intermediate Q.X-ray absorption spectroscopic characterization of the diferric-peroxo intermediate of human deoxyhypusine hydroxylase in the presence of its substrate eIF5aIsolation and characterization of a dihydroxo-bridged iron(III,III)(μ-OH)2 diamond core derived from dioxygen.Interplay of Electronic Cooperativity and Exchange Coupling in Regulating the Reactivity of Diiron(IV)-oxo Complexes towards C-H and O-H Bond Activation.Formation and High Reactivity of the anti-Dioxo Form of High-Spin μ-Oxodioxodiiron(IV) as the Active Species That Cleaves Strong C-H Bonds.Activation parameters as mechanistic probes in the TAML iron(V)-oxo oxidations of hydrocarbons.Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes.Acid-facilitated product release from a Mo(IV) center: relevance to oxygen atom transfer reactivity of molybdenum oxotransferases.
P2860
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P2860
Hydrogen-bonding effects on the reactivity of [X-Fe(III)-O-Fe(IV)═O] (X = OH, F) complexes toward C-H bond cleavage.
description
2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年論文
@yue
2013年論文
@zh-hant
2013年論文
@zh-hk
2013年論文
@zh-mo
2013年論文
@zh-tw
2013年论文
@wuu
2013年论文
@zh
2013年论文
@zh-cn
name
Hydrogen-bonding effects on th ...... exes toward C-H bond cleavage.
@en
type
label
Hydrogen-bonding effects on th ...... exes toward C-H bond cleavage.
@en
prefLabel
Hydrogen-bonding effects on th ...... exes toward C-H bond cleavage.
@en
P2093
P2860
P356
P1433
P1476
Hydrogen-bonding effects on th ...... lexes toward C-H bond cleavage
@en
P2093
Adam T Fiedler
Genqiang Xue
Lawrence Que
Shengfa Ye
P2860
P304
P356
10.1021/IC3027896
P407
P577
2013-03-15T00:00:00Z