Enantioselective copper-catalyzed conjugate addition and allylic substitution reactions.
about
Building Bridges: Biocatalytic C–C-Bond Formation toward Multifunctional ProductsRecent advances in copper-catalyzed asymmetric coupling reactionsAllylic functionalization of unactivated olefins with Grignard reagents.Concise methods for the synthesis of chiral polyoxazolines and their application in asymmetric hydrosilylationOperando X-ray absorption and EPR evidence for a single electron redox process in copper catalysisPreparation of stereodefined homoallylic amines from the reductive cross-coupling of allylic alcohols with imines.Regioselective and Diastereoselective Aminoarylation of 1,3-DienesSilylene-mediated polarity reversal of dienoates: additions of dienoates to aldehydes at the δ-position to form trans-dioxasilacyclononenesIridium catalysis: application of asymmetric reductive hydrogenation.Modulation of multifunctional N,O,P ligands for enantioselective copper-catalyzed conjugate addition of diethylzinc and trapping of the zinc enolate.Mobilizing Cu(I) for carbon-carbon bond forming catalysis in the presence of thiolate. Chemical mimicking of metallothioneins.Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsA direct approach to amines with remote stereocentres by enantioselective CuH-catalysed reductive relay hydroaminationEnantioselective CuH-Catalyzed Hydroallylation of Vinylarenes.Elimination of butylcycloheptylprodigiosin as a known natural product inspired by an evolutionary hypothesis for cyclic prodigiosin biosynthesis.On the Mechanism of Pd(0)-Catalyzed, Cu(I) Carboxylate-Mediated Thioorganic-Boronic Acid Desulfitative Coupling. A Non-innocent Role for Carboxylate Ligand.Mechanism and enantioselectivity in palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones: insights from computation and experiment.Copper-catalyzed divergent kinetic resolution of racemic allylic substrates.Catalytic asymmetric synthesis of allylic alcohols and derivatives and their applications in organic synthesis.A broadly applicable NHC-Cu-catalyzed approach for efficient, site-, and enantioselective coupling of readily accessible (pinacolato)alkenylboron compounds to allylic phosphates and applications to natural product synthesis.Asymmetric conjugate additions and allylic alkylations using nucleophiles generated by hydro- or carbometallation.C-C bond formation via copper-catalyzed conjugate addition reactions to enones in water at room temperatureCopper-catalysed cross-coupling: an untapped potential.Diastereoselective and enantioselective conjugate addition reactions utilizing α,β-unsaturated amides and lactams.Nucleophilic and Electrophilic Activation of Non-Heteroaromatic Amides in Atom-Economical Asymmetric Catalysis.Catalytic SN2'- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis.Catalytic enantioselective addition of Grignard reagents to aromatic silyl ketimines.Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.Enantioselective Nickel-Catalyzed Intramolecular Allylic Alkenylations Enabled by Reversible Alkenylnickel E/Z Isomerization.Quaternary carbon stereogenic centers through copper-catalyzed enantioselective allylic substitutions with readily accessible aryl- or heteroaryllithium reagents and aluminum chlorides.Rh-catalyzed intermolecular reactions of cyclic α-diazocarbonyl compounds with selectivity over tertiary C-H bond migration.Concise Enantioselective Synthesis of Oxygenated Steroids via Sequential Copper(II)-Catalyzed Michael Addition/Intramolecular Aldol Cyclization Reactions.Carboxylic acids as a traceless activation group for conjugate additions: a three-step synthesis of (±)-pregabalin.Pd-catalyzed carbonylative conjugate addition of dialkylzinc reagents to unsaturated carbonyls.Copper-catalyzed enantioselective allylic substitution with readily accessible carbonyl- and acetal-containing vinylboron reagents.Rh(I)-bisphosphine-catalyzed asymmetric, intermolecular hydroheteroarylation of α-substituted acrylate derivatives.Enantioselective synthesis of alkyne-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution reactions with (i-Bu)2(alkynyl)aluminum reagents.Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis.Enantioselective total synthesis of (-)-nardoaristolone B via a gold(I)-catalyzed oxidative cyclizationSynthesis and characterization of privileged monodentate phosphoramidite ligands and chiral Brønsted acids derived from d-mannitol.
P2860
Q26741385-967ED0C5-E2C4-44B0-9A8E-D4073FC364BFQ26770614-B4E26AB0-3DA6-4700-8DE9-F34476BAEC75Q33684656-E6A2F159-250E-439E-B73A-D816F9E41D5BQ33867988-D1D88F9D-44B7-47E2-8F71-1877BD699592Q33886440-C4790C13-50FB-4523-A125-559852744DCFQ34361152-6CE23E53-04BF-49AF-9523-A0543E15DA4DQ34565193-0ECE8707-E125-43A4-B285-0AE359D72A45Q34758024-9DE52EB8-E342-442D-85A9-CB8A659B7776Q34940130-A606D5FC-2DCE-4D2A-BC25-E16F6B14AE44Q34975386-659D6EA2-8EA1-4551-8071-1470AE18F24DQ35084585-F849365C-8860-4654-9FAE-49CEA682BEDFQ36049587-46FB3645-CAFE-4293-A5A6-525300E2E9E2Q36495458-BE564EE5-1E00-4C13-A317-B758908F5CA5Q36852041-AE0FAD40-16F5-4C22-8656-821770450345Q37308431-3ECA2B73-77A1-423C-A76C-DF110F2FF9DAQ37343019-273DB317-A1D6-44DD-A176-21054D533015Q37355498-416AFE31-65A8-499F-BE44-E9E35E238F9EQ37916384-9F4820DB-250F-4C26-82D4-8B390438AC43Q38074104-73B172DE-F82E-4E42-9CB0-1BF6C7278373Q38274670-11598DFF-B872-48E7-9E64-69D0280E9DBAQ38325282-FB676FD0-9FB7-4202-90FF-61ED79D85A1DQ38362852-F89EC4CE-CC44-43A9-8D16-64C30440C71CQ38398645-890BB456-41EF-49E5-993D-B0BDE1D08B75Q38482449-8B240FFA-F26F-4A9F-975D-428D1777883AQ38933450-08EF8BD4-0817-4AA3-8A6E-EA0CC1686067Q39672627-27A7E861-8D23-460C-B51B-E4AA8714833EQ40173315-9BD2769F-B9AF-455F-9BC2-4B0D59FC2BECQ40700153-7F997D86-F3BE-4488-A6D6-8AAB91D5161CQ40950927-8841DD33-D943-4C11-B9AE-B27028C68A36Q41131396-6E35718A-BDFA-421B-951C-5DB58D3AEC1BQ41558025-E915F70A-8C2C-45BA-A2E2-CC8B26E3832FQ41769030-63C75E79-6B2C-4203-938A-39326D7A0E64Q41807535-2142B860-E85A-4D29-9BE9-6101CBA91F28Q41816793-F5C18E9F-94D8-4C1A-B39D-7C34E23040CAQ41823171-8843410F-6F8C-4C54-8EA7-D91761CB6BA6Q41827744-7B8416F0-80E2-479E-A0EA-7F6C1FACC171Q41838586-E93876C1-6A50-4B50-B75D-686F52EADF02Q41854222-8AB5AB82-38FD-4AB2-8836-EF21D6367F24Q41856777-9DB40E36-3968-45FB-8D2C-882AEC4829C3Q41895784-B7C5D40F-FD29-409C-BAD3-2D9EA30C3230
P2860
Enantioselective copper-catalyzed conjugate addition and allylic substitution reactions.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on August 2008
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Enantioselective copper-catalyzed conjugate addition and allylic substitution reactions.
@en
Enantioselective copper-catalyzed conjugate addition and allylic substitution reactions.
@nl
type
label
Enantioselective copper-catalyzed conjugate addition and allylic substitution reactions.
@en
Enantioselective copper-catalyzed conjugate addition and allylic substitution reactions.
@nl
prefLabel
Enantioselective copper-catalyzed conjugate addition and allylic substitution reactions.
@en
Enantioselective copper-catalyzed conjugate addition and allylic substitution reactions.
@nl
P2093
P356
P1433
P1476
Enantioselective copper-catalyzed conjugate addition and allylic substitution reactions
@en
P2093
A Alexakis
J E Bäckvall
P304
P356
10.1021/CR0683515
P577
2008-08-01T00:00:00Z