Catalytic asymmetric allylic and homoallylic diamination of terminal olefins via formal C-H activation
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Bis(dibenzylideneacetone)palladium(0)Copper-Catalyzed Alkene Diamination: Synthesis of Chiral 2-Aminomethyl Indolines and Pyrrolidines.Synthetic and mechanistic studies on Pd(0)-catalyzed diamination of conjugated dienes.An effective C-C double bond formation via Cu(I)-catalyzed dehydrogenation.Pd(II)-catalyzed oxidative 1,1-diarylation of terminal olefins.Cu(I)-catalyzed regioselective diamination of conjugated dienes via dual mechanistic pathways.Metal-free synthesis of allylic amines by cross-dehydrogenative-coupling of 1,3-diarylpropenes with anilines and amides under mild conditions.Asymmetric C-C Bond Formation between Chiral N-Phosphonyl Imines and Ni(II)-Complex of Glycine Schiff Base Provides a GAP Synthesis of α,β-syn-Diamino Acid Derivatives.Complementary regioselectivity in the Cu(I)-catalyzed diamination of conjugated dienes to form cyclic sulfamidesCopper-catalyzed oxidative homo- and cross-coupling of Grignard reagents using diaziridinonePalladium(0)-catalyzed Heck reaction/C-H activation/amination sequence with diaziridinone: a facile approach to indolines.Copper-promoted and copper-catalyzed intermolecular alkene diaminationCu(I)-catalyzed sequential diamination and dehydrogenation of terminal olefins: a facile approach to imidazolinones.Catalytic diamination of olefins via N-N bond activation.Advancing the mechanistic understanding of an enantioselective palladium-catalyzed alkene difunctionalization reactionA palladium-catalyzed three-component cross-coupling of conjugated dienes or terminal alkenes with vinyl triflates and boronic acidsAnti-Markovnikov hydroalkylation of allylic amine derivatives via a palladium-catalyzed reductive cross-coupling reactionCu(I)-catalyzed diamination of conjugated dienes. Complementary regioselectivity from two distinct mechanistic pathways involving Cu(II) and Cu(III) species.Heterocycle synthesis via direct C-H/N-H coupling.Catalytic enantioselective allylic amination of unactivated terminal olefins via an ene reaction/[2,3]-rearrangementA palladium-catalyzed dehydrogenative diamination of terminal olefins.Catalytic asymmetric synthesis of cyclic sulfamides from conjugated dienesHighly efficient Cu(I)-catalyzed oxidation of alcohols to ketones and aldehydes with diaziridinone.Facile Cu(I)-catalyzed oxidative coupling of anilines to azo compounds and hydrazines with diaziridinone under mild conditions.Cu(I)-catalyzed asymmetric diamination of conjugated dienes.Cu(I)-catalyzed diamination of disubstituted terminal olefins: an approach to potent NK1 antagonist.Cu(I)-catalyzed C-H alpha-amination of aryl ketones: direct synthesis of imidazolinones.Synthesis of (+)-CP-99,994 via Pd(0)-catalyzed asymmetric allylic and homoallylic C-H Diamination of terminal olefin.Pd(0)-catalyzed sequential C-N bond formation via allylic and aromatic C-H amination of α-methylstyrenes with diaziridinone.A facile copper(I)-catalyzed homocoupling of terminal alkynes to 1,3-diynes with diaziridinone under mild conditionsCu(I)-catalyzed diamination of conjugated olefins with tunable anionic counterions. A possible approach to asymmetric diamination.Palladium(II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications.Methods for direct alkene diamination, new & old.Chiral counteranion strategy for asymmetric oxidative C(sp³)-H/C(sp³)-H coupling: enantioselective α-allylation of aldehydes with terminal alkenes.Modular synthesis of 1,2-diamine derivatives by palladium-catalyzed aerobic oxidative cyclization of allylic sulfamides.Modular Synthesis of 1,2-Diamine Derivatives via Palladium-Catalyzed Aerobic Oxidative Cyclization of Allylic Sulfamides.Directed amination of non-acidic arene C-H bonds by a copper-silver catalytic system.Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions.Synthesis of enantiomerically enriched imidazolidin-2-ones through asymmetric palladium-catalyzed alkene carboamination reactions.Enantioselective Pd(II)-catalyzed aerobic oxidative amidation of alkenes and insights into the role of electronic asymmetry in pyridine-oxazoline ligands.
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P2860
Catalytic asymmetric allylic and homoallylic diamination of terminal olefins via formal C-H activation
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on 13 June 2008
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Catalytic asymmetric allylic a ...... fins via formal C-H activation
@en
Catalytic asymmetric allylic a ...... ins via formal C-H activation.
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type
label
Catalytic asymmetric allylic a ...... fins via formal C-H activation
@en
Catalytic asymmetric allylic a ...... ins via formal C-H activation.
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prefLabel
Catalytic asymmetric allylic a ...... fins via formal C-H activation
@en
Catalytic asymmetric allylic a ...... ins via formal C-H activation.
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P2093
P2860
P356
P1476
Catalytic asymmetric allylic a ...... fins via formal C-H activation
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P2093
P2860
P304
P356
10.1021/JA8027394
P407
P577
2008-06-13T00:00:00Z