Transition metal catalyzed enantioselective α-heterofunctionalization of carbonyl compounds.
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Nickel-catalyzed reductive conjugate addition to enones via allylnickel intermediates.Radical cascade reaction of alkynes with N-fluoroarylsulfonimides and alcohols.Enantioselective synthesis of tertiary α-chloro esters by non-covalent catalysisCu(II)-catalyzed aerobic hydroperoxidation of Meldrum's acid derivatives and application in intramolecular oxidation: a conceptual blueprint for O2/H2 dihydroxylation.Asymmetric synthesis of diverse glycolic acid scaffolds via dynamic kinetic resolution of α-keto estersReagent-controlled enantioselectivity switch for the asymmetric fluorination of β-ketocarbonyls by chiral primary amine catalysis.Asymmetric organocatalysis mediated by α,α-L-diaryl prolinols: recent advances.Electrophilic amination: the case of nitrenoids.Asymmetric α-amination of β-keto esters using a guanidine-bisurea bifunctional organocatalyst.Formal Asymmetric Hydrobromination of Styrenes via Copper-Catalyzed 1,3-Halogen Migration.Chiral phase-transfer catalysis in the asymmetric α-heterofunctionalization of prochiral nucleophilesChemo- and Stereoselective Transition-Metal-Free Amination of Amides with Azides.Direct asymmetric amination of α-branched cyclic ketones catalyzed by a chiral phosphoric acid.Iridium-catalyzed 1,3-hydrogen shift/chlorination of allylic alcohols.Asymmetric Catalysis with Ethylene. Synthesis of Functionalized Chiral Enolates.Enantioselective decarboxylative chlorination of β-ketocarboxylic acids.Catalytic enantioselective intermolecular desymmetrization of 3-substituted oxetanes.Enantioselective α-hydroxylation of β-ketoamides.Enantioselective electrophilic cyanation of β-keto amides catalysed by a cinchona organocatalyst.Reversing Polarity: Carbonyl α-Aminations with Nitrogen Nucleophiles.Bifunctional Ammonium Salt Catalyzed Asymmetric α-Hydroxylation of β-Ketoesters by Simultaneous Resolution of Oxaziridines.Stereoselective Construction of Halogenated Quaternary Carbon Centers by Brønsted Base Catalyzed [4+2] Cycloaddition of α-Haloaldehydes.Why different ligands can control stereochemistry selectivity of Ni-catalyzed Suzuki-Miyaura cross-coupling of benzylic carbamates with arylboronic esters: a mechanistic study.Lewis Acid-Assisted Photoinduced Intermolecular Coupling between Acylsilanes and Aldehydes: A Formal Cross Benzoin-Type Condensation.Chiral N,N'-Dioxide-Scandium(III)-Catalyzed Asymmetric Dearomatization of 2-Naphthols through an Amination Reaction.Reductive umpolung reactions with low-valent titanium catalysts.Renovation of Optically Active Phenanthrolines as Powerful Chiral Ligands for Versatile Asymmetric Metal Catalysis.Cu(ii)-catalyzed enantioselective oxygen atom transfer from oxaziridine to oxindole derivatives with chiral phenanthroline.Asymmetric α-amination reaction of alkenyl trifluoroacetates catalyzed by a chiral phosphine-silver complex.Brønsted acid mediated N-O bond cleavage for α-amination of ketones through the aromatic nitroso aldol reaction.The Mukaiyama aldol reaction of in situ generated nitrosocarbonyl compounds: selective C-N bond formation and N-O bond cleavage in one-pot for α-amination of ketones.Synthesis of Amathaspiramides by Aminocyanation of Enoates.Highly efficient C-H hydroxylation of carbonyl compounds with oxygen under mild conditions.Williamson Ether Synthesis with Phenols at a Tertiary Stereogenic Carbon: Formal Enantioselective Phenoxylation of β-Keto Esters.The direct electrophilic cyanation of β-keto esters and amides with cyano benziodoxole.Merging aerobic oxidation and enamine catalysis in the asymmetric α-amination of β-ketocarbonyls using N-hydroxycarbamates as nitrogen sources.Direct catalytic enantioselective amination of ketones for the formation of tri- and tetrasubstituted stereocenters.Asymmetric Lewis acid catalysis directed by octahedral rhodium centrochirality.Visible-light-induced dual C–C bond formation via selective C(sp3)–H bond cleavage: efficient access to alkylated oxindoles from activated alkenes and simple ethers under metal-free conditions
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P2860
Transition metal catalyzed enantioselective α-heterofunctionalization of carbonyl compounds.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
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artigo científico
@pt
bilimsel makale
@tr
scientific article published on 18 October 2010
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vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
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vědecký článek
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name
Transition metal catalyzed ena ...... ization of carbonyl compounds.
@en
Transition metal catalyzed ena ...... ization of carbonyl compounds.
@nl
type
label
Transition metal catalyzed ena ...... ization of carbonyl compounds.
@en
Transition metal catalyzed ena ...... ization of carbonyl compounds.
@nl
prefLabel
Transition metal catalyzed ena ...... ization of carbonyl compounds.
@en
Transition metal catalyzed ena ...... ization of carbonyl compounds.
@nl
P356
P1433
P1476
Transition metal catalyzed ena ...... ization of carbonyl compounds.
@en
P2093
Alexander M R Smith
P304
P356
10.1021/CR100197Z
P577
2010-10-18T00:00:00Z