Guiding principles for site selective and stereoselective intermolecular C-H functionalization by donor/acceptor rhodium carbenes.
about
Metal Catalysis in Thiolation and Selenation Reactions of Alkynes Leading to Chalcogen-Substituted Alkenes and DienesEnantioselective carbenoid insertion into C(sp(3))-H bondsAllylic functionalization of unactivated olefins with Grignard reagents.Copper-catalyzed regioselective ortho C-H cyanation of vinylarenes.Directed Evolution of RebH for Catalyst-Controlled Halogenation of Indole C-H BondsProfound methyl effects in drug discovery and a call for new C-H methylation reactions.Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalizationSyntheses of Cyclic Guanidine-Containing Natural Products.Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.Reactivity of N-(1,2,4-triazolyl)-substituted 1,2,3-triazoles.Enantioselective cis-β-lactam synthesis by intramolecular C-H functionalization from enoldiazoacetamides and derivative donor-acceptor cyclopropenes.Combined C-H functionalization/Cope rearrangement with vinyl ethers as a surrogate for the vinylogous Mukaiyama aldol reaction.Asymmetric Synthesis of Highly Functionalized Cyclopentanes by a Rhodium- and Scandium-Catalyzed Five-Step Domino Sequence.The combined C-H functionalization/Cope rearrangement: discovery and applications in organic synthesis.Scope and mechanistic analysis of the enantioselective synthesis of allenes by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and propargylic alcohols.Vinylogous reactivity of enol diazoacetates with donor-acceptor substituted hydrazones. Synthesis of substituted pyrazole derivatives.Alkynoate synthesis through the vinylogous reactivity of rhodium(II) carbenoids.Cascade alkylarylation of substituted N-allylbenzamides for the construction of dihydroisoquinolin-1(2H)-ones and isoquinoline-1,3(2H,4H)-diones(2aR*,5S*,6aS*,8aS*,E)-Ethyl 5-hy-droxy-7,7,8a-trimethyl-8-oxo-2,2a,6,6a,7,8,8a,8b-octa-hydro-1H-penta-leno[1,6-bc]oxepine-4-carboxyl-ate.Arylation of rhodium(II) azavinyl carbenes with boronic acids.Rhodium-catalyzed enantioselective cyclopropanation of electron deficient alkenes.Dirhodium(II)-catalyzed formal [3+2+1]-annulation of azomethine imines with two molecules of a diazo ketone.Enantioselective functionalization of allylic C-H bonds following a strategy of functionalization and diversification.Rh2(R-TPCP)4-catalyzed enantioselective [3+2]-cycloaddition between nitrones and vinyldiazoacetates.Copper carbenes alkylate guanine chemoselectively through a substrate directed reaction.Stereoselective 1,3-insertions of rhodium(II) azavinyl carbenesMaking expensive dirhodium(II) catalysts cheaper: Rh(II) recycling methods.Recent advances in the total synthesis of cyclopropane-containing natural products.Gas extrusion in natural products total synthesis.Versatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C-H bond functionalization.Gold-catalyzed C(sp3)-H bond functionalization.Chiral dirhodium(II) carboxylates and carboxamidates as effective chemzymes in asymmetric synthesis of three-membered carbocycles.Diazo compounds in continuous-flow technology.Ir-Catalyzed enantioselective group transfer reactions.Cycloaddition reactions of enoldiazo compounds.Trends in applying C-H oxidation to the total synthesis of natural products.The past, present, and future of the Yang reaction.Gold-catalyzed oxidative couplings of two indoles with one aryldiazo cyanide under oxidant-free conditions.New Approaches to the Synthesis of Metal Carbenes.Fluorinated diazoalkanes - a versatile class of reagents for the synthesis of fluorinated compounds.
P2860
Q26745720-A7DD9339-12E4-4294-B962-2CE31A7B31FDQ26747268-8F0BD615-6312-440D-ADC7-FEB4FF5EEEC7Q33684656-E9C75E61-E982-4CBA-BD23-1F92E18A195BQ34022018-0595BCD5-E41E-4034-9336-9FE4D6986F4FQ34532086-67B8D7AD-00EF-4482-997B-3B8D8FD634E9Q35024529-EDE4D182-6266-4FD7-A5B4-58F93F4774D3Q35029999-9ECE9B07-1600-4418-85FA-C88D3382EAD1Q35075948-C6AA5434-5824-48A8-A13B-0B87008AD241Q35125838-05D91598-9384-4992-BB90-31C80BF14785Q35575138-C357A55D-5E97-4527-A2C6-1F7E5DF8C3FDQ35647749-121006AC-B6C2-41E2-948B-A53F538875C6Q35858697-77526C40-2F8B-4BCA-A428-0274DCB62860Q36033836-5486FEAE-913B-497B-B0FE-C50F5D06CBA2Q36044451-FB30B666-7F3D-4F61-9E6A-A1C09F9009FFQ36546571-D540A2F5-9FE8-4159-A34C-27AB2EB51166Q36614815-D0204C90-989E-48F4-8F80-0D400E7B730FQ36631742-6FB88FBF-63A7-48B3-9DE7-9A49CED62032Q36652441-F3F68E99-91F4-4FF8-A5B9-4E6FCD414AB3Q36658765-5762CDB9-6C83-4BDA-BAC1-5A12C543BCC4Q36683776-4BEB2545-CFA3-4EB1-BB7F-2C8E1091232CQ37172196-D8B0CF5D-7AB6-47D1-A0A1-D7CEEF987767Q37313164-13581E96-02EB-4B1B-AFFA-AE69646ABC72Q37548669-9CBA8EBB-69D6-415E-B06C-08DF62355952Q37634366-5E83DB1C-CFD2-4AEA-AD69-B5090ED58E1BQ37686082-BCC84B1B-DB78-4860-BCAE-E5DBEDA9133CQ37723074-850E9675-0310-44E3-8081-3DFF2BD5B16BQ37994587-58EA9580-DDFB-4F52-BB1F-E32A095CAC9FQ38010631-4E2AD4E8-63CF-4858-9A36-5B78643F72BDQ38039828-431E9842-FA99-42CF-8799-9CDF823A2F28Q38195732-03FF6E1B-0CD6-42FA-B310-BE25FF75A6A9Q38213934-C44F2C80-E3BC-40D8-9661-D736008792C1Q38231755-C092D789-3AD9-42D2-A543-538C336B67A9Q38285577-E0754F8A-F756-4C46-8617-88C76548B9DBQ38519039-1215D7E4-75A8-455C-92B9-B4E66793671EQ38654525-F9DB18D3-B3C3-46EC-A8AF-FABDB4022577Q38723563-D2D43A17-E968-4475-826C-223A49792F7AQ38831956-490091F2-9DFF-4C27-84A3-A2EBE8D561CAQ38844543-8435D75E-6C81-4488-902A-FD349D689514Q38867130-797674B3-FF15-49CB-87DD-11557AF7AE07Q38976911-00125AE2-0100-4BE2-8914-E6AD04042479
P2860
Guiding principles for site selective and stereoselective intermolecular C-H functionalization by donor/acceptor rhodium carbenes.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on March 2011
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Guiding principles for site se ...... nor/acceptor rhodium carbenes.
@en
Guiding principles for site se ...... nor/acceptor rhodium carbenes.
@nl
type
label
Guiding principles for site se ...... nor/acceptor rhodium carbenes.
@en
Guiding principles for site se ...... nor/acceptor rhodium carbenes.
@nl
prefLabel
Guiding principles for site se ...... nor/acceptor rhodium carbenes.
@en
Guiding principles for site se ...... nor/acceptor rhodium carbenes.
@nl
P2093
P50
P356
P1476
Guiding principles for site se ...... onor/acceptor rhodium carbenes
@en
P2093
Daniel Morton
Huw M L Davies
P304
P356
10.1039/C0CS00217H
P577
2011-03-01T00:00:00Z