about
Constrained geometry complexes—Synthesis and applicationsMetal-free binding and coupling of carbon monoxide at a boron-boron triple bond.Synthesis and structure-activity relationships of new quinolone-type molecules against Trypanosoma brucei.Ambient-temperature isolation of a compound with a boron-boron triple bond.Transition-metal complexes of boron-new insights and novel coordination modes.Transition metal borylene complexes.B═B and B≡E (E = N and o) multiple bonds in the coordination sphere of late transition metals.Reductive Insertion of Elemental Chalcogens into Boron-Boron Multiple Bonds.Formation and Reactivity of Electron-Precise B-B Single and Multiple Bonds.Jozimine A2: the first dimeric Dioncophyllaceae-type naphthylisoquinoline alkaloid, with three chiral axes and high antiplasmodial activity.Enantioselective synthesis of tricyclic amino acid derivatives based on a rigid 4-azatricyclo[5.2.1.0]decane skeleton.Ortho-methylated tribenzotriquinacenes--paving the way to curved carbon networks.Ring Expansions of Boroles with Diazo Compounds: Steric Control of C or N Insertion and Aromatic/Nonaromatic Products.O,N,B-Containing eight-membered heterocycles by ring expansion of boroles with nitrones.Synthesis of Functionalized Hydrazines: Facile Homogeneous (N-Heterocyclic Carbene)-Palladium(0)-Catalyzed Diboration and Silaboration of Azobenzenes.Generation of 1,2-azaboretidines via reduction of ADC borane adducts.Taming the beast: fluoromesityl groups induce a dramatic stability enhancement in boroles1,2-Bis(dimethyl-amino)-1,2-bis-(2,4,6-triisopropyl-phen-yl)diborane(4).Stepwise isolation of low-valent, low-coordinate Sn and Pb mono- and dications in the coordination sphere of platinum.Bis(μ-diisopropyl-phosphanido-κ(2)P:P)bis-[hydrido(triisopropyl-phosphane-κP)platinum(II)]cyclo-Tri-μ-oxido-tris-{[(η,η)-1,2-bis-(cyclo-penta-dien-yl)-1,1,2,2-tetra-methyl-disilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene.{N',N''-Bis[2,6-bis-(1-methyl-ethyl)phen-yl]-N,N-dimethyl-guanidinato-κN',N''}dibromido-borane.Dicyclohexyl(2',4',6'-triisopropylbiphenyl-2-yl)phosphine-dichlorophenylborane[1.1]Ferrocenophanes and bis(ferrocenyl) species with aluminum and gallium as bridging elements: synthesis, characterization, and electrochemical studies.Chemical reduction and dimerization of 1-chloro-2,3,4,5-tetraphenylborole.Synthesis and reactivity of boron-, silicon-, and tin-bridged ansa-cyclopentadienyl-cycloheptatrienyl titanium complexes (troticenophanes).Reactivity of [1],[1]disilamolybdenocenophane toward zerovalent platinum complexes.Structure and bonding energy analysis of M-Ga bonds in dihalogallyl complexes trans-[X(PMe3)2M(GaX2)] (M = Ni, Pd, Pt; X = Cl, Br, I).Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chlorido-borylene-1:2κ(2) B:B-[1(η(5))-penta-methyl-cyclo-penta-dien-yl](tri-cyclo-hexyl-phosphane-2κP)iron(II)platinum(II) benzene monosolvate.Oxoboryl complexes: boron-oxygen triple bonds stabilized in the coordination sphere of platinum.Interaction of (benzylidene-hydrazono)-1,4-dihydropyridines with beta-amyloid, acetylcholine, and butyrylcholine esterases.Electronic structure and reactivity of a [1],[1]disilamolybdenocenophane.Chemoselective boron-carbon bond cleavage by hydroboration of borirenes.Synthesis and structure of a carbene-stabilized boraallene coordinated to rhodium.Ditopic ambiphilicity of an anionic dimetalloborylene complex.Heteroleptic [n]chromoarenophanes: ansa complexes derived from [Cr(η(5)-C5H5)(η(6)-C6H6)].Spying on the boron-boron triple bond using spin-spin coupling measured from 11B solid-state NMR spectroscopy.Maximizing coordinative and electronic unsaturation: three-coordinate dicationic platinum complexes.Reductive borylene-CO coupling with a bulky arylborylene complex.Conversion of trans-diboran(4)yl platinum complexes into their cis-bisboryl analogues.
P50
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P50
description
hulumtues
@sq
onderzoeker
@nl
researcher
@en
հետազոտող
@hy
name
Holger Braunschweig
@ast
Holger Braunschweig
@en
Holger Braunschweig
@es
Holger Braunschweig
@sl
type
label
Holger Braunschweig
@ast
Holger Braunschweig
@en
Holger Braunschweig
@es
Holger Braunschweig
@sl
prefLabel
Holger Braunschweig
@ast
Holger Braunschweig
@en
Holger Braunschweig
@es
Holger Braunschweig
@sl
P108
P106
P1153
7003690670
P21
P31
P496
0000-0001-9264-1726