Enantioselective catalytic alpha-alkylation of aldehydes via an SN1 pathway.
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Enantioselective α-benzylation of aldehydes via photoredox organocatalysisInfluence of the substitution and conformation of C--H-bond-based bis-triazole acceptors in anion-binding catalysis.Generation of α,β-unsaturated iminium ions by laser flash photolysis.Dioxindole in asymmetric catalytic synthesis: direct access to 3-substituted 3-hydroxy-2-oxindoles via 1,4-additions to nitroalkenes.Thiourea-catalyzed enantioselective addition of indoles to pyrones: alkaloid cores with quaternary carbons.Palladium-catalyzed, pyrrolidine-mediated arylmethylation of ketones and aldehydes with coumarinyl(methyl) acetatesAsymmetric intramolecular α-cyclopropanation of aldehydes using a donor/acceptor carbene mimetic.Cinchona-based primary amine catalysis in the asymmetric functionalization of carbonyl compounds.Asymmetric ion-pairing catalysis.Bifunctional primary amine-thioureas in asymmetric organocatalysis.Dual catalysis in enantioselective oxidopyrylium-based [5 + 2] cycloadditions.1,3,5-Tri(iodoethynyl)-2,4,6-trifluorobenzene: halogen-bonded frameworks and NMR spectroscopic analysis.Enantioselective formal aza-Diels-Alder reactions of enones with cyclic imines catalyzed by primary aminothioureasA quantitative approach to nucleophilic organocatalysis.Thiourea-catalysed ring opening of episulfonium ions with indole derivatives by means of stabilizing non-covalent interactions.Enantioselective Formal α-Methylation and α-Benzylation of Aldehydes by Means of Photo-organocatalysis.On- and Off-Cycle Catalyst Cooperativity in Anion-Binding Catalysis.A Simple Primary Amine Catalyst for Enantioselective α-Hydroxylations and α-Fluorinations of Branched Aldehydes.Synergistic Catalysis: A Powerful Synthetic Strategy for New Reaction Development.Enantioselective selenocyclization via dynamic kinetic resolution of seleniranium ions by hydrogen-bond donor catalysts.Otherwise inert reaction of sulfonamides/carboxamides with formamides via proton transfer-enhanced reactivity.Thiophosphoramide-based cooperative catalysts for Brønsted acid promoted ionic Diels-Alder reactions.Asymmetric α-alkylation of aldehydes with 3-hydroxy-3-indolylox-indoles in aqueous media.Remote enantioselective Friedel-Crafts alkylations of furans through HOMO activation.Efficient Access to All-Carbon Quaternary and Tertiary α-Functionalized Homoallyl-type Aldehydes from Ketones.An Aminocatalyzed Stereoselective Strategy for the Formal α-Propargylation of Ketones.Chiral Primary Amine Catalyzed Asymmetric α-Benzylation with In Situ Generated ortho-Quinone Methides.Mechanism-Guided Development of a Highly Active Bis-Thiourea Catalyst for Anion-Abstraction Catalysis.Chiral amine-catalyzed asymmetric conjugate addition of aldehydes to α-phenylselenoenones as formal Z-allylating agents.Asymmetric direct α-alkylation of 2-oxindoles with Michler's hydrol catalyzed by bis-cinchona alkaloid-Brønsted acid via an SN1-type pathway.The versatile roles of ammonium salt catalysts in enantioselective reduction and alkylation of α,β-unsaturated aldehydes: iminium catalysis, enamine catalysis and acid catalysis.A novel iridium/acid co-catalyzed transfer hydrogenative C(sp(3))-H bond alkylation to access functionalized N-heteroaromatics.A general Pd-catalyzed α- and γ-benzylation of aldehydes for the formation of quaternary centers.The acid free asymmetric intermolecular α-alkylation of aldehydes in fluorinated alcohols.Direct regiospecific and highly enantioselective intermolecular α-allylic alkylation of aldehydes by a combination of transition-metal and chiral amine catalysts.Highly enantioselective intermolecular alkylation of aldehydes with alcohols by cooperative catalysis of diarylprolinol silyl ether with Brønsted acid.Brønsted acid catalyzed α-alkylation of aldehydes with diaryl methyl alcohols.Synergistic gold and enamine catalysis: intermolecular α-alkylation of aldehydes with allenamides.Catalytic Enantioselective Synthesis of Lactams through Formal [4+2] Cycloaddition of Imines with Homophthalic Anhydride.Conjugate-base-stabilized Brønsted acids as asymmetric catalysts: enantioselective Povarov reactions with secondary aromatic amines.
P2860
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P2860
Enantioselective catalytic alpha-alkylation of aldehydes via an SN1 pathway.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Enantioselective catalytic alpha-alkylation of aldehydes via an SN1 pathway.
@en
type
label
Enantioselective catalytic alpha-alkylation of aldehydes via an SN1 pathway.
@en
prefLabel
Enantioselective catalytic alpha-alkylation of aldehydes via an SN1 pathway.
@en
P2093
P2860
P356
P1476
Enantioselective catalytic alpha-alkylation of aldehydes via an SN1 pathway.
@en
P2093
Adam R Brown
Eric N Jacobsen
Wen-Hsin Kuo
P2860
P304
P356
10.1021/JA103618R
P407
P577
2010-07-01T00:00:00Z