Characterization and dioxygen reactivity of a new series of coordinatively unsaturated thiolate-ligated manganese(II) complexes.
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Tuning the Relative Stability and Reactivity of Manganese Dioxygen and Peroxo Intermediates via Systematic Ligand ModificationX-ray Absorption and Emission Study of Dioxygen Activation by a Small-Molecule Manganese ComplexReaction landscape of a pentadentate N5-ligated Mn(II) complex with O2˙- and H2O2 includes conversion of a peroxomanganese(III) adduct to a bis(μ-oxo)dimanganese(III,IV) species.Water-soluble Fe(II)-H2O complex with a weak O-H bond transfers a hydrogen atom via an observable monomeric Fe(III)-OH.Synthesis and structural characterization of a series of Mn(III)OR complexes, including a water-soluble Mn(III)OH that promotes aerobic hydrogen-atom transfer.Correlation between structural, spectroscopic, and reactivity properties within a series of structurally analogous metastable manganese(III)-alkylperoxo complexesCharacterization of metastable intermediates formed in the reaction between a Mn(II) complex and dioxygen, including a crystallographic structure of a binuclear Mn(III)-peroxo species.
P2860
Q28829572-FD6674A1-EFA5-421B-AC6D-3FB1F293B897Q35828336-296A8B08-C78B-4664-A15A-F57B8740155EQ35838133-E563D513-F249-4C05-9877-034DF7355819Q41595533-2D79AD1F-9D58-4469-8C14-DB504ADB1AF0Q41859915-1DA64F0A-6661-4BC8-AB59-8CA4F62D12ACQ42550709-D0E417F8-0958-4CB3-8EF5-D0E3E1F501C6Q43094771-F875FB81-DB7F-46C8-B8DA-974DD5727803
P2860
Characterization and dioxygen reactivity of a new series of coordinatively unsaturated thiolate-ligated manganese(II) complexes.
description
2012 nî lūn-bûn
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2012年の論文
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2012年論文
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2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
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2012年论文
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2012年论文
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name
Characterization and dioxygen ...... ted thiolate-ligated manganese
@nl
Characterization and dioxygen ...... gated manganese(II) complexes.
@en
type
label
Characterization and dioxygen ...... ted thiolate-ligated manganese
@nl
Characterization and dioxygen ...... gated manganese(II) complexes.
@en
prefLabel
Characterization and dioxygen ...... ted thiolate-ligated manganese
@nl
Characterization and dioxygen ...... gated manganese(II) complexes.
@en
P2093
P2860
P356
P1433
P1476
Characterization and dioxygen ...... gated manganese(II) complexes.
@en
P2093
Erika Shaffer
Jason Shearer
Michael K Coggins
Santiago Toledo
P2860
P304
P356
10.1021/IC300192Q
P407
P577
2012-05-29T00:00:00Z