Olefin cis-dihydroxylation versus epoxidation by non-heme iron catalysts: two faces of an Fe(III)-OOH coin.
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Osmium-free direct syn-dihydroxylation of alkenesAn FeIV=O complex of a tetradentate tripodal nonheme ligandIron-catalyzed asymmetric epoxidation of β,β-disubstituted enonesHigh-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic Fe(IV)=O Complexes.Mono- and dinuclear iron complexes of bis(1-methylimidazol-2-yl)ketone (bik): structure, magnetic properties, and catalytic oxidation studies.One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center.Effective alkaline metal-catalyzed oxidative delignification of hybrid poplarHydrogen peroxide dependent cis-dihydroxylation of benzoate by fully oxidized benzoate 1,2-dioxygenaseMechanisms in manganese catalysed oxidation of alkenes with H2O2.A DFT study of the cis-dihydroxylation of nitroaromatic compounds catalyzed by nitrobenzene dioxygenase.Molecular Epoxidation Reactions Catalyzed by Rhenium, Molybdenum, and Iron Complexes.Dioxygen activation by nonheme iron enzymes with the 2-His-1-carboxylate facial triad that generate high-valent oxoiron oxidants.Oxygen activation by mononuclear nonheme iron dioxygenases involved in the degradation of aromatics.Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations.Scalable Synthesis of Piperazines Enabled by Visible-Light Irradiation and Aluminum Organometallics.Characterization of a high-spin non-heme Fe(III)-OOH intermediate and its quantitative conversion to an Fe(IV)═O complex.Rate-Determining Attack on Substrate Precedes Rieske Cluster Oxidation during Cis-Dihydroxylation by Benzoate DioxygenaseRadical intermediates in monooxygenase reactions of rieske dioxygenases.A Highly Selective Vanadium Catalyst for Benzylic C-H Oxidation.The Catalytic Function of Nonheme Iron (III) Complex for Hydrocarbon OxidationIron complexes of tetramine ligands catalyse allylic hydroxyamination via a nitroso-ene mechanism.Regio- and enantioselective catalytic monoepoxidation of conjugated dienes: synthesis of chiral allylic cis-epoxides.Osmium(III) and osmium(V) complexes bearing a macrocyclic ligand: a simple and efficient catalytic system for cis-dihydroxylation of alkenes with hydrogen peroxide.Hydrogen peroxide-coupled cis-diol formation catalyzed by naphthalene 1,2-dioxygenase.Nonheme iron mediated oxidation of light alkanes with oxone: characterization of reactive oxoiron(IV) ligand cation radical intermediates by spectroscopic studies and DFT calculations.Acid-triggered O-O bond heterolysis of a nonheme FeIII(OOH) species for the stereospecific hydroxylation of strong C-H bonds.Equilibrating (L)FeIII-OOAc and (L)FeV(O) Species in Hydrocarbon Oxidations by Bio-Inspired Nonheme Iron Catalysts Using H2O2 and AcOH.Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with FeV═O and FeIV═O Units.H2 oxidation versus organic substrate oxidation in non-heme iron mediated reactions with H2O2.The mechanism of stereospecific C-H oxidation by Fe(Pytacn) complexes: bioinspired non-heme iron catalysts containing cis-labile exchangeable sites.Olefin cis-Dihydroxylation and Aliphatic C-H Bond Oxygenation by a Dioxygen-Derived Electrophilic Iron-Oxygen Oxidant.Properties and reactivities of nonheme iron(IV)-oxo versus iron(V)-oxo: long-range electron transfer versus hydrogen atom abstraction.Titanium salan catalysts for the asymmetric epoxidation of alkenes: steric and electronic factors governing the activity and enantioselectivity.H2O2 activation with biomimetic non-haem iron complexes and AcOH: connecting the g = 2.7 EPR signal with a visible chromophore.Making Fe(BPBP)-catalyzed C-H and C[double bond, length as m-dash]C oxidations more affordable.Identification of a low-spin acylperoxoiron(III) intermediate in bio-inspired non-heme iron-catalysed oxidations.(Aceto-nitrile-κN)aqua-[N,N'-bis-(pyridin-2-yl-methyl)ethane-1,2-di-amine-κ4N,N',N'',N''']zinc(II) perchlorate.Supported C-Scorpionate Vanadium(IV) Complexes as Reusable Catalysts for Xylene Oxidation.Computational analysis of site differences in selective aliphatic C-H hydroxylation by nonheme iron-oxo complexes.MnO2-promoted carboesterification of alkenes with anhydrides: a facile approach to γ-lactones.
P2860
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P2860
Olefin cis-dihydroxylation versus epoxidation by non-heme iron catalysts: two faces of an Fe(III)-OOH coin.
description
2002 nî lūn-bûn
@nan
2002年の論文
@ja
2002年学术文章
@wuu
2002年学术文章
@zh
2002年学术文章
@zh-cn
2002年学术文章
@zh-hans
2002年学术文章
@zh-my
2002年学术文章
@zh-sg
2002年學術文章
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2002年學術文章
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name
Olefin cis-dihydroxylation ver ...... catalysts: two faces of an Fe
@nl
Olefin cis-dihydroxylation ver ...... faces of an Fe(III)-OOH coin.
@en
type
label
Olefin cis-dihydroxylation ver ...... catalysts: two faces of an Fe
@nl
Olefin cis-dihydroxylation ver ...... faces of an Fe(III)-OOH coin.
@en
prefLabel
Olefin cis-dihydroxylation ver ...... catalysts: two faces of an Fe
@nl
Olefin cis-dihydroxylation ver ...... faces of an Fe(III)-OOH coin.
@en
P2093
P356
P1476
Olefin cis-dihydroxylation ver ...... faces of an Fe(III)-OOH coin.
@en
P2093
Adrianne K Tipton
Jinheung Kim
Lawrence Que
P304
P356
10.1021/JA0120025
P407
P577
2002-03-01T00:00:00Z