A sulfido-bridged diiron(II) compound and its reactions with nitrogenase-relevant substrates.
about
A Sulfide-Bridged Diiron(II) Complex with a cis-N2H4LigandComplexes of Bulky β-Diketiminate LigandsInsight into the Iron-Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride LigandsThree-coordinate terminal imidoiron(III) complexes: structure, spectroscopy, and mechanism of formation.Ammonia formation by a thiolate-bridged diiron amide complex as a nitrogenase mimic.A dinucleating ligand related to the beta-diketiminates.Tuning steric and electronic effects in transition-metal β-diketiminate complexesConversion of Fe-NH2 to Fe-N2 with release of NH3Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride.Reduction of CO2 to CO using low-coordinate iron: formation of a four-coordinate iron dicarbonyl complex and a bridging carbonate complex.The reactivity patterns of low-coordinate iron-hydride complexes.Electronic structure and reactivity of three-coordinate iron complexesMacrocyclic Binucleating β-Diketiminate Ligands and their Lithium, Aluminum, and Zinc ComplexesSynthesis, Radical Reactivity, and Thermochemistry of Monomeric Cu(II) Alkoxide Complexes Relevant to Cu/Radical Alcohol Oxidation CatalysisQuantitative geometric descriptions of the belt iron atoms of the iron-molybdenum cofactor of nitrogenase and synthetic iron(II) model complexes.Testing the polynuclear hypothesis: multielectron reduction of small molecules by triiron reaction sites.New Routes to Low-Coordinate Iron Hydride Complexes: The Binuclear Oxidative Addition of H(2).Oxidized and reduced [2Fe-2S] clusters from an iron(I) synthon.Synthesis, structure and reactivity of Fe(II/III)-NH3 complexes bearing a tripodal sulfonamido ligand.Isolation and characterization of stable iron(I) sulfide complexes.Synthesis, spectroscopy, and hydrogen/deuterium exchange in high-spin iron(II) hydride complexesThe discovery of Mo(III) in FeMoco: reuniting enzyme and model chemistry.Group 5 chemistry supported by β-diketiminate ligands.A mixed valence zinc dithiolene system with spectator metal and reactor ligandsSpectroscopic and computational studies of a series of high-spin Ni(II) thiolate complexes.Dinitrogen complexes of sulfur-ligated iron.Low-spin pseudotetrahedral iron(I) sites in Fe₂(μ-S) complexes.Tuning the stability and reactivity of metal-bound alkylperoxide by remote site substitution of the ligand.Substrate interaction at an iron-sulfur face of the FeMo-cofactor during nitrogenase catalysis.A functional model for the Rieske center: full characterization of a biomimetic N-ligated [2Fe-2S] cluster in different protonation states.Steric and electronic effects on arylthiolate coordination in the pseudotetrahedral complexes [(Tp(Ph,Me))Ni-SAr] (Tp(Ph,Me) = hydrotris{3-phenyl-5-methyl-1-pyrazolyl}borate).A three-coordinate Fe(ii) center within a [3Fe-(μ3-S)] cluster that provides an accessible coordination site.Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor.Heteroatom-free arene-cobalt and arene-iron catalysts for hydrogenations.Sterically directed nitronate complexes of 2,6-di-tert-butyl-4-nitrophenoxide with Cu(ii) and Zn(ii) and their H-atom transfer reactivity.Synthesis and reactivity of thiolate-bridged multi-iron complexes supported by cyclic (alkyl)(amino)carbene.Biomimetic [2Fe-2S] clusters with extensively delocalized mixed-valence iron centers.Biomimetische [2Fe-2S]-Cluster mit stark delokalisierten gemischtvalenten EisenzentrenA [3Fe–3S]3+ cluster with exclusively μ-sulfide donors
P2860
Q28468643-19694648-4BB7-45DE-8F6C-E5A04E571A69Q29028863-68D5612E-8325-45A1-8658-C688BEA7E33DQ33899998-B4EB226B-7CC5-4D07-A7FB-93AF8E1270B6Q34033141-CDC1DAC8-771D-4045-934C-6895D470F151Q34627945-A645597E-D97F-40A6-8182-681A7687514CQ35062097-3BFEB62D-3E49-4CB6-A42D-C2CA1C583B9EQ36090442-ACF4BFCD-1688-4ED5-83CA-8BB3694DBEFCQ36590595-690BF86A-CD73-4D39-972D-EF28754F3435Q36757271-BB321C43-EE1D-464C-A687-CB3DBBF79C8DQ36776453-8ED56F1C-28EC-49D4-B27F-E382FF564C33Q36776461-2A9F0AF4-9F6C-4700-838A-4A6F7ABF3D7EQ36982920-1D31BC24-8B01-43EF-91DC-CC5515542013Q37039258-B6C46F13-B8D4-4F4D-96B3-E23F36D7E3E0Q37148877-6522FA96-80F4-42A8-A6F0-B40C0217CC31Q37177023-4ED1960A-2EEB-4DFD-9A46-637C6A5D95D5Q37241023-20E59DD4-352C-48BE-BEF0-7A413D679182Q37265778-AAC03778-7168-4D6E-88E0-ED96ED2AAE8AQ37606935-2C8FEAF0-1A41-4A9C-B864-B968B4B23832Q37638156-21618551-CC3B-4D0B-BCAB-15B94CEEACA5Q37676001-4638F53E-4317-4CB1-BFBB-C9E93A96428CQ37714205-5997F367-617E-4A3C-BE67-019731D98654Q38303983-D744F81D-EDE8-4207-A215-06E85F654B49Q38872015-39822534-44F6-40A9-A86E-B271C9D4D657Q41155181-7B2EE0D0-6A4B-494B-B2BE-203048413B07Q41971648-0E9D4207-4008-4BBD-BCE1-262CF1EB12B7Q42758662-8931D585-9297-467F-AA96-0D97177A7144Q42864351-EE385885-5815-4531-8395-8551105CA25EQ43000106-766C4448-DDB0-4888-BE7E-5D37F7CDEB90Q45091107-3F2F496F-589D-410F-AEB3-3A98A521435EQ45901930-E0ADE74E-CF43-4C84-9913-6E14BA584468Q46503019-2ABAF245-578D-4FF7-AAE8-D1D34CF102ABQ46525012-0FAB79C4-DF70-45EB-8FEB-EEEB5E8A9AE6Q46833820-A398A014-279F-4592-917A-9EDA1B2013C8Q46921092-44FA3CF8-F2C9-486F-B0E6-FE84C19F435DQ48281699-B2BB0460-6AB3-42F8-9F76-D95773B06BB5Q50109354-FCC03BBC-7784-4FAD-9B1A-48F8790B2901Q52862263-FCCB8A94-F404-484B-8138-B71512C0AB55Q57903552-FF2EBCCA-5930-4868-B1D1-03CF06268F1DQ58466530-D043201D-6C3E-49B2-8BC2-BFD376AA1047
P2860
A sulfido-bridged diiron(II) compound and its reactions with nitrogenase-relevant substrates.
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年学术文章
@wuu
2004年学术文章
@zh
2004年学术文章
@zh-cn
2004年学术文章
@zh-hans
2004年学术文章
@zh-my
2004年学术文章
@zh-sg
2004年學術文章
@yue
2004年學術文章
@zh-hant
name
A sulfido-bridged diiron
@nl
A sulfido-bridged diiron(II) c ...... trogenase-relevant substrates.
@en
type
label
A sulfido-bridged diiron
@nl
A sulfido-bridged diiron(II) c ...... trogenase-relevant substrates.
@en
prefLabel
A sulfido-bridged diiron
@nl
A sulfido-bridged diiron(II) c ...... trogenase-relevant substrates.
@en
P2093
P356
P1476
A sulfido-bridged diiron(II) c ...... trogenase-relevant substrates.
@en
P2093
Christine J Flaschenriem
Eckard Münck
Javier Vela
Patrick L Holland
P304
P356
10.1021/JA049417L
P407
P577
2004-04-01T00:00:00Z