Copper Catalyzed Cross-Coupling of Iodobenzoates with Bromozinc-difluorophosphonate
about
Introduction of fluorine and fluorine-containing functional groups.In situ generation of N-unsubstituted imines from alkyl azides and their applications for imine transfer via copper catalysis.Highly selective nickel-catalyzed gem-difluoropropargylation of unactivated alkylzinc reagents.Copper-Mediated Aromatic 1,1-Difluoroethylation with (1,1-Difluoroethyl)trimethylsilane (TMSCF2 CH3 ).Copper-mediated aerobic (phenylsulfonyl)difluoromethylation of arylboronic acids with difluoromethyl phenyl sulfone.Copper/B2pin2-catalyzed C-H difluoroacetylation-cycloamidation of anilines leading to the formation of 3,3-difluoro-2-oxindoles.New Prospects toward the Synthesis of Difluoromethylated Phosphate Mimics.Copper-Mediated Introduction of the CF2 PO(OEt)2 Motif: Scope and Limitations.Direct C-H difluoromethylenephosphonation of arenes and heteroarenes with bromodifluoromethyl phosphonate via visible-light photocatalysis.Enhancement of neighbouring-group participation in Cu0-promoted cross-coupling gem-difluoromethylenation of aryl/alkenyl halides with 1,3-azolic difluoromethyl bromides.Silver-catalyzed oxidative decarboxylation of difluoroacetates: efficient access to C-CF2 bond formation.Stereoselective cobalt-catalyzed halofluoroalkylation of alkynes.Ag(i)-Catalyzed oxidative decarboxylation of difluoroacetates with activated alkenes to form difluorooxindoles.An efficient regioselective hydrodifluoromethylation of unactivated alkenes with TMSCF₂CO₂Et at ambient temperature.Highly effective copper-mediated gem-difluoromethylenation of arylboronic acids.Recent Progress toward the Introduction of Functionalized Difluoromethylated Building Blocks onto C(sp(2) ) and C(sp) Centers.Carbonylation of Difluoroalkyl Bromides Catalyzed by PalladiumCopper-catalyzed cross-coupling of bromozinc-difluoromethylphosphonate with iodo/bromo-aryl triazenesPalladium-Catalyzed Difluoroalkylation of Aryl Boronic Acids: A New Method for the Synthesis of Aryldifluoromethylated Phosphonates and Carboxylic Acid DerivativesCopper-Catalyzed Innate Ethoxycarbonyldifluoromethylation of Electron-Rich ArenesCopper-Mediated Formation of Aryl, Heteroaryl, Vinyl and Alkynyl Difluoromethylphosphonates: A General Approach to Fluorinated Phosphate MimicsCopper-Mediated Synthesis of Aryldifluoromethylphosphonates: A Sandmeyer Approach
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P2860
Copper Catalyzed Cross-Coupling of Iodobenzoates with Bromozinc-difluorophosphonate
description
im März 2012 veröffentlichter wissenschaftlicher Artikel
@de
scientific article published on 21 March 2012
@en
wetenschappelijk artikel
@nl
наукова стаття, опублікована в березні 2012
@uk
name
Copper Catalyzed Cross-Coupling of Iodobenzoates with Bromozinc-difluorophosphonate
@en
Copper Catalyzed Cross-Coupling of Iodobenzoates with Bromozinc-difluorophosphonate
@nl
type
label
Copper Catalyzed Cross-Coupling of Iodobenzoates with Bromozinc-difluorophosphonate
@en
Copper Catalyzed Cross-Coupling of Iodobenzoates with Bromozinc-difluorophosphonate
@nl
prefLabel
Copper Catalyzed Cross-Coupling of Iodobenzoates with Bromozinc-difluorophosphonate
@en
Copper Catalyzed Cross-Coupling of Iodobenzoates with Bromozinc-difluorophosphonate
@nl
P356
P1433
P1476
Copper catalyzed cross-coupling of iodobenzoates with bromozinc-difluorophosphonate
@en
P2093
Xingang Zhang
P304
P356
10.1021/OL3006425
P407
P50
P577
2012-03-21T00:00:00Z