Enantioselective allylic alkylation of stereodefined polysubstituted copper enolates as an entry to acyclic quaternary carbon stereocentres.A unique Pd-catalysed Heck arylation as a remote trigger for cyclopropane selective ring-openingBrook Rearrangement as Trigger for Carbene Generation: Synthesis of Stereodefined and Fully Substituted Cyclobutenes.Asymmetric Copper-Catalyzed Carbomagnesiation of Cyclopropenes.Zirconocene-assisted remote cleavage of C-C and C-O bonds: application to acyclic stereodefined metalated hydrocarbons.Preparation and Reactivity of Acyclic Chiral Allylzinc Species by a Zinc-Brook Rearrangement.Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.Asymmetric Catalytic Preparation of Polysubstituted Cyclopropanol and Cyclopropylamine Derivatives.Rh-Catalyzed Arylation of Cyclopropenes Based on Asymmetric Directed Functionalization of Three-Membered Carbocycles.Zirconocene-Mediated Selective C-C Bond Cleavage of Strained Carbocycles: Scope and Mechanism.Tandem Hydroalumination/Cu-Catalyzed Asymmetric Vinyl Metalation as a New Access to Enantioenriched Vinylcyclopropane Derivatives.Versatility in the Brook Rearrangement for the Selective Ring-Opening of Three-Membered RingsDiastereo- and enantioselective copper catalyzed hydroallylation of disubstituted cyclopropenesDiastereo- and enantioselective preparation of cyclopropanol derivativesPd-Catalyzed Selective Remote Ring Opening of Polysubstituted CyclopropanolsMetal-Catalyzed Remote Functionalization of ω-Ene Unsaturated Ethers: Towards Functionalized Vinyl SpeciesStereoselective Formation of Fully Substituted Ketone EnolatesDiastereoselective ring opening of fully-substituted cyclopropanes via intramolecular Friedel-Crafts alkylationNucleophilic Substitution at Quaternary Carbon StereocentersRegio- and Diastereoselective Copper-Catalyzed Carbometalation of CyclopropenylsilanesTotal Synthesis of C30 Botryococcene and epi-Botryococcene by a Diastereoselective Ring Opening of AlkenylcyclopropanesEfficient and stereodivergent synthesis of unsaturated acyclic fragments bearing contiguous stereogenic elementsAsymmetric Preparation of Polysubstituted Cyclopropanes Based on Direct Functionalization of Achiral Three-Membered CarbocyclesCorrection to "Nucleophilic Substitution at Quaternary Carbon Stereocenters"Synthesis of Enantioenriched Vicinal Tertiary and Quaternary Carbon Stereogenic Centers within an Acyclic ChainRegio- and Stereoselective Synthesis of Fully Substituted Silyl Enol Ethers of Ketones and Aldehydes in Acyclic SystemsHighly E-Selective, Stereoconvergent Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Alkenyl EthersCobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes
P50
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P50
description
Frans scheikundige
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French-Israeli chemist
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químicu israelín
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כימאי צרפתי-ישראלי
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Ilan Marek
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Ilan Marek
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Ilan Marek
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Ilan Marek
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Ilan Marek
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Ilan Marek
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Ilan Marek
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Ilan Marek
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Ilan Marek
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Ilan Marek
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Ilan Marek
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Ilan Marek
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Ilan Marek
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Ilan Marek
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P1006
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