Transition metal carbene complex
A transition metal carbene complex is an organometallic compound featuring a divalent organic ligand. The divalent organic ligand coordinated to the metal center is called a carbene. Carbene complexes for almost all transition metals have been reported. Many methods for synthesizing them and reactions utilizing them have been reported. The term carbene ligand is a formalism since many are not derived from carbenes and almost none exhibit the reactivity characteristic of carbenes. Described often as M=CR2, they represent a class of organic ligands intermediate between alkyls (−CR3) and carbynes (≡CR). They feature in some catalytic reactions, especially alkene metathesis, and are of value in the preparation of some fine chemicals.
primaryTopic
Transition metal carbene complex
A transition metal carbene complex is an organometallic compound featuring a divalent organic ligand. The divalent organic ligand coordinated to the metal center is called a carbene. Carbene complexes for almost all transition metals have been reported. Many methods for synthesizing them and reactions utilizing them have been reported. The term carbene ligand is a formalism since many are not derived from carbenes and almost none exhibit the reactivity characteristic of carbenes. Described often as M=CR2, they represent a class of organic ligands intermediate between alkyls (−CR3) and carbynes (≡CR). They feature in some catalytic reactions, especially alkene metathesis, and are of value in the preparation of some fine chemicals.
has abstract
A transition metal carbene com ...... ration of some fine chemicals.
@en
Carbenkomplexe sind Übergangsm ...... tathese eine Anwendung findet.
@de
Kompleksy alkilidenowe, zwane ...... imeryzacji cyklicznych olefin.
@pl
Un complesso metallo-carbene è ...... utti i metalli di transizione.
@it
カルベン錯体（カルベンさくたい）とは、カルベンを配位子として ...... 属以外との結合の数が2つしかないような構造を持つ錯体である。
@ja
过渡金属卡宾配合物可用通式LnM=CR2表示，它在形式上含有 ...... 卡宾不能直接和金属反应，但卡宾能和金属结合形成配合物而稳定。
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Wikipage page ID
Wikipage revision ID
730,283,618
hypernym
comment
A transition metal carbene com ...... ration of some fine chemicals.
@en
Carbenkomplexe sind Übergangsm ...... enstoffatoms entscheidend ist.
@de
@pl
Un complesso metallo-carbene è ...... utti i metalli di transizione.
@it
カルベン錯体（カルベンさくたい）とは、カルベンを配位子として ...... 属以外との結合の数が2つしかないような構造を持つ錯体である。
@ja
过渡金属卡宾配合物可用通式LnM=CR2表示，它在形式上含有 ...... 卡宾不能直接和金属反应，但卡宾能和金属结合形成配合物而稳定。
@zh
label
Carbenkomplexe
@de
Complesso metallo-carbene
@it
Kompleksy alkilidenowe
@pl
Transition metal carbene complex
@en
カルベン錯体
@ja
过渡金属卡宾配合物
@zh