"Ain't Nothing Like the Real Thing" is a 1968 single released by American R&B/soul duo Marvin Gaye and Tammi Terrell, on the Tamla label in 1968. The B-side of the single is "Little Ole Boy, Little Ole Girl" from the duo's United LP. The first release off the duo's second album: You're All I Need, the song - written and produced by regular Gaye/Terrell collaborators Ashford & Simpson - became a hit within weeks of release eventually peaking at number 8 on the Billboard Hot 100 and number 1 on the Hot Soul Singles chart, the first of the duo's s two number 1 R&B hits. In the UK "Ain't Nothing Like the Real Thing" reached number 34.