"When I Think About Angels" is a song co-written and recorded by Australian country music artist Jamie O'Neal. It was released in March 2001 as the second single from O'Neal's Shiver album. The song reached Number One on the Billboard Hot Country Singles & Tracks (now Hot Country Songs) charts. It also peaked at #35 on the U.S. Billboard Hot 100. The song was written by O'Neal, Roxie Dean and Sonny Tillis.