Teaching the right reasons: lessons from the mistaken origin of the rotational barrier in ethaneHeats of formation of platonic hydrocarbon cages by means of high-level thermochemical proceduresSteric Crowding Can Stabilize a Labile Molecule: Solving the Hexaphenylethane Riddle1,2-Didehydro[10]annulenes: Structures, Aromaticity, and CyclizationsUltrafast two-dimensional infrared spectroscopy resolves the conformational change of an Evans auxiliary induced by Mg(ClO4)2.The "non-reaction" of ground-state triplet carbon atoms with water revisited.[123]Tetramantane: parent of a new family of sigma-helicenes.H-bonding additives act like Lewis acid catalysts.Metal-free, noncovalent catalysis of diels-alder reactions by neutral hydrogen bond donors in organic solvents and in water.Unconventional molecule-resolved current rectification in diamondoid-fullerene hybridsEvidence of diamond nanowires formed inside carbon nanotubes from diamantane dicarboxylic acid.The lipophilic bullet hits the targets: medicinal chemistry of adamantane derivativesThe Enantioselective Dakin-West Reaction.Electronic stabilization of ground state triplet carbenes.A formal carbon-sulfur triple bond: H-C[triple bond]S-O-H.(Thio)urea organocatalysis--what can be learnt from anion recognition?Heuristic thinking makes a chemist smart.Organocatalytic enantioselective acyl transfer onto racemic as well as meso alcohols, amines, and thiols.Preparation and Characterization of Parent Phenylphosphinidene and Its Oxidation to Phenyldioxophosphorane: The Elusive Phosphorus Analogue of Nitrobenzene.Uncovering Key Structural Features of an Enantioselective Peptide-Catalyzed Acylation Utilizing Advanced NMR Techniques.Two-dimensional infrared spectroscopy reveals the structure of an Evans auxiliary derivative and its SnCl4 Lewis acid complex.(Thio)urea organocatalyst equilibrium acidities in DMSO.Three structurally homologous isothiocyanates exert "Janus" characteristics in human HepG2 cells.Intramolecular hydroxycarbene C-H-insertion: The curious case of (o-methoxyphenyl)hydroxycarbene.Phenylhydroxycarbene.Sizing the role of London dispersion in the dissociation of all-meta tert-butyl hexaphenylethane.Electronic effects on atom tunneling: conformational isomerization of monomeric para-substituted benzoic acid derivatives.Stereospecific consecutive epoxide ring expansion with dimethylsulfoxonium methylide.Oxathiirane.Metal oxide-organic frameworks (MOOFs), a new series of coordination hybrids constructed from molybdenum(VI) oxide and bitopic 1,2,4-triazole linkers.Chemistry. Cooperativity tames reactive catalysts.The influence of a single thiol group on the electronic and optical properties of the smallest diamondoid adamantane.Understanding the torquoselectivity in 8pi-electrocyclic cascade reactions: synthesis of fenestradienes versus cyclooctatrienes.Carbonyl- and carboxyl-substituted enediynes: synthesis, computations, and thermal reactivity.Covalent attachment of diamondoid phosphonic acid dichlorides to tungsten oxide surfaces.Origin of the monochromatic photoemission peak in diamondoid monolayers.Halogenation of cubane under phase-transfer conditions: single and double C-H-bond substitution with conservation of the cage structure.The rearrangement of the cubane radical cation in solution.The cyclization of parent and cyclic hexa-1,3-dien-5-ynes--a combined theoretical and experimental study.Molecule-induced alkane homolysis with dioxiranes.
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P50
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Duits scheikundige
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Saksamaa keemik
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ceimiceoir Gearmánach
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Peter R. Schreiner
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