about
Tuning the Reactivity of Radical through a Triplet Diradical Cu(II) Intermediate in Radical Oxidative Cross-CouplingStabilization of Two Radicals with One Metal: A Stepwise Coupling Model for Copper-Catalyzed Radical-Radical Cross-CouplingFrom Mechanistic Study to Chiral Catalyst Optimization: Theoretical Insight into Binaphthophosphepine-catalyzed Asymmetric Intramolecular [3 + 2] Cycloaddition.Rhodium/Copper Cocatalyzed Highly trans-Selective 1,2-Diheteroarylation of Alkynes with Azoles via C-H Addition/Oxidative Cross-Coupling: A Combined Experimental and Theoretical Study.Insights into disilylation and distannation: sequence influence and ligand/steric effects on Pd-catalyzed difunctionalization of carbenes.Ruthenium(II)-Catalyzed C-H Difluoromethylation of Ketoximes: Tuning the Regioselectivity from the meta to the para Position.Reactivity and regioselectivity in Diels-Alder reactions of anion encapsulated fullerenes.Enantioselective alkynylation of N-sulfonyl α-ketiminoesters via a Friedel-Crafts alkylation strategy.Bioinspired Total Synthesis of Homodimericin A.Bioinspired Asymmetric Synthesis of Hispidanin A.Efficient Synthesis of Dimeric Oxazoles, Piperidines and Tetrahydroisoquinolines from N-Substituted 2-Oxazolones.Development of a Rhodium(II)-Catalyzed Chemoselective C(sp(3) )-H Oxygenation.Ruthenium(II)-enabled para-selective C-H difluoromethylation of anilides and their derivatives.Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2† †Electronic supplementary information (ESI) available: Experimental details and characterization data. See DOI: 10.1039/c8sc01299g.Mechanistic view of Ru-catalyzed C-H bond activation and functionalization: computational advancesAnnulation cascade of arylnitriles with alkynes to stable delocalized PAH carbocations via intramolecular rhodium migration.Catalytic Lactonization of Unactivated Aryl C-H Bonds with CO2: Experimental and Computational InvestigationLayered Chirality Relay Model in Rh(I)-Mediated Enantioselective C-Si Bond Activation: A Theoretical StudyProtecting-Group-Free Total Syntheses of (±)-Norascyronones A and BKinetically Controlled Radical Addition/Elimination Cascade: From Alkynyl Aziridine to Fluorinated AllenesWell-Designed Phosphine-Urea Ligand for Highly Diastereo- and Enantioselective 1,3-Dipolar Cycloaddition of Methacrylonitrile: A Combined Experimental and Theoretical StudyAn unusual [4 + 2] fusion strategy to forge meso-N/O-heteroarene-fused (quinoidal) porphyrins with intense near-infrared Q-bandsUnmasking the Ligand Effect in Manganese-Catalyzed Hydrogenation: Mechanistic Insight and Catalytic ApplicationFormal Asymmetric Cycloaddition of Activated α,β-Unsaturated Ketones with α-Diazomethylphosphonate Mediated by a Chiral Silver SPINOL Phosphate CatalystHighly Selective and Catalytic Generation of Acyclic Quaternary Carbon Stereocenters via Functionalization of 1,3-Dienes with CO2Enantiodivergence by minimal modification of an acyclic chiral secondary aminocatalystTheoretical Study of the Addition of Cu-Carbenes to Acetylenes to Form Chiral AllenesAsymmetric Propargylic Radical Cyanation Enabled by Dual Organophotoredox and Copper CatalysisRetro-metal-ene versus retro-Aldol: mechanistic insight into Rh-catalysed formal [3+2] cycloaddition
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P50
description
researcher (ORCID 0000-0002-7870-8469)
@en
name
Lei Zhu
@en
type
label
Lei Zhu
@en
prefLabel
Lei Zhu
@en
P31
P496
0000-0002-7870-8469