1,n-Dicarbanionic Titanium Intermediates from Monocarbanionic Organometallics and Their Application in Organic Synthesis
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Studies on the intramolecular Kulinkovich-de Meijere reaction of disubstituted alkenes bearing carboxylic amide groups.Stereochemical lability of azatitanacyclopropanes: dynamic kinetic resolution in reductive cross-coupling reactions with allylic alcohols.A convergent stereoselective synthesis of quinolizidines and indolizidines: chemoselective coupling of 2-hydroxymethyl-substituted allylic silanes with imines.Chemoselective reductive cross-coupling of 1,5-diene-3-ols with alkynes: a facile entry to stereodefined skipped trienes.Total synthesis of the Aspidosperma alkaloid (±)-subincanadine F via a titanium-mediated intramolecular nucleophilic acyl substitution strategyPreparation of stereodefined homoallylic amines from the reductive cross-coupling of allylic alcohols with imines.Efficient synthesis of substituted 3-azabicyclo[3.1.0]hexan-2-ones from 2-iodocyclopropanecarboxamides using a copper-free Sonogashira coupling.Synthesis of conformationally locked L-deoxythreosyl phosphonate nucleosides built on a bicyclo[3.1.0]hexane template.Generation of quaternary centers by reductive cross-coupling: shifting of regioselectivity in a subset of allylic alcohol-based coupling reactions.Diastereoselective Prins-type reaction of cycloalkenylcyclopropanol silyl ethers and alpha,beta-unsaturated aldehyde acetalsOlefin Exchange-Mediated Cyclopropanation of Nitriles with Homoallylic Alcohols.The regio- and stereochemical course of reductive cross-coupling reactions between 1,3-disubstituted allenes and vinylsilanes: Synthesis of (Z)-dienes.Asymmetric synthesis of naturally occurring spiroketals.Synthetic approaches to (smif)2Ti (smif = 1,3-di-(2-pyridyl)-2-azaallyl) reveal redox non-innocence and C-C bond-formation.Regioselective Reductive Cross-Coupling Reactions of Unsymmetrical Alkynes.Metallacycle-Mediated Cross-Coupling with Substituted and Electronically Unactivated Alkenes.Recent Advances in the One-Step Synthesis of Distally Fluorinated Ketones.The Development of Alkoxide-Directed Metallacycle-Mediated Annulative Cross-Coupling Chemistry.A rapid route to aminocyclopropanes via carbamatoorganozinc carbenoids.Reaction design, discovery, and development as a foundation to function-oriented synthesis.Stereochemistry of the Kulinkovich cyclopropanation of nitriles.Catalytic Carbonylative Spirolactonization of HydroxycyclopropanolsTotal synthesis of cyathin A(3) and cyathin B(2).Ti-Catalyzed Multicomponent Oxidative Carboamination of Alkynes with Alkenes and Diazenes.Defying ring strain: new approaches to cyclopropanes.Palladium-catalyzed cross-coupling of cyclopropanol-derived ketone homoenolates with aryl bromides.General one-pot reductive gem-bis-alkylation of tertiary lactams/amides: rapid construction of 1-azaspirocycles and formal total synthesis of (±)-cephalotaxine.Synthesis and absolute configuration of demethyl (C-11) cezomycin.Synthetic Reactions Using Low-valent Titanium Reagents Derived from Ti(OR)4 or CpTiX3 (X = O-i-Pr or Cl) in the Presence of Me3SiCl and Mg.Ultrasound-assisted 1,3-dipolar cycloaddition and cyclopropanation reactions for the synthesis of bis-indolizine and bis-cyclopropane derivatives.A Germylene/Borane Lewis Pair and the Remarkable C=O Bond Cleavage Reaction toward Isocyanate and Ketone Molecules.Construction of polysubstituted olefins through Ni-catalyzed direct activation of alkenyl C-O of substituted alkenyl acetates.Copper-catalysed ring-opening trifluoromethylation of cyclopropanols.Direct reductive coupling of secondary amides: chemoselective formation of vicinal diamines and vicinal amino alcohols.Titanium redox catalysis: insights and applications of an earth-abundant base metal.
P2860
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P2860
1,n-Dicarbanionic Titanium Intermediates from Monocarbanionic Organometallics and Their Application in Organic Synthesis
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2000 nî lūn-bûn
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2000 թուականի Օգոստոսին հրատարակուած գիտական յօդուած
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2000 թվականի օգոստոսին հրատարակված գիտական հոդված
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2000年の論文
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2000年論文
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2000年論文
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2000年論文
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2000年論文
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2000年論文
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2000年论文
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name
1,n-Dicarbanionic Titanium Int ...... plication in Organic Synthesis
@ast
1,n-Dicarbanionic Titanium Int ...... plication in Organic Synthesis
@en
1,n-Dicarbanionic Titanium Int ...... plication in Organic Synthesis
@nl
type
label
1,n-Dicarbanionic Titanium Int ...... plication in Organic Synthesis
@ast
1,n-Dicarbanionic Titanium Int ...... plication in Organic Synthesis
@en
1,n-Dicarbanionic Titanium Int ...... plication in Organic Synthesis
@nl
prefLabel
1,n-Dicarbanionic Titanium Int ...... plication in Organic Synthesis
@ast
1,n-Dicarbanionic Titanium Int ...... plication in Organic Synthesis
@en
1,n-Dicarbanionic Titanium Int ...... plication in Organic Synthesis
@nl
P356
P1433
P1476
1,n-Dicarbanionic Titanium Int ...... plication in Organic Synthesis
@en
P2093
A de Meijere
O G Kulinkovich
P304
P356
10.1021/CR980046Z
P407
P577
2000-08-09T00:00:00Z