Enantioselective Rhodium-Catalyzed [2 + 2 + 2] Cycloadditions of Terminal Alkynes and Alkenyl Isocyanates: Mechanistic Insights Lead to a Unified Model that Rationalizes Product Selectivity - Wikidata - wikimedia - TriplyDB

Enantioselective Rhodium-Catalyzed [2 + 2 + 2] Cycloadditions of Terminal Alkynes and Alkenyl Isocyanates: Mechanistic Insights Lead to a Unified Model that Rationalizes Product Selectivity

Enantioselective Rhodium-Catalyzed [2 + 2 + 2] Cycloadditions of Terminal Alkynes and Alkenyl Isocyanates: Mechanistic Insights Lead to a Unified Model that Rationalizes Product Selectivity

http://www.wikidata.org/entity/Q28468194

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Enantioselective Rhodium-Catalyzed [2+2+2] Cycloaddition of Pentenyl Isocyanate and 4-Ethynylanisole: Preparation and Use of Taddolpyrrolidine Phosphoramidite.Ni-Catalyzed Asymmetric Cycloisomerization of Dienes by Using TADDOL Phosphoramidites.Enantioselective rhodium-catalyzed isomerization of 4-iminocrotonates: asymmetric synthesis of a unique chiral synthon Multi-component cycloaddition approaches in the catalytic asymmetric synthesis of alkaloid targets.Recent advances in [2+2+2] cycloaddition reactions.Preparation and synthetic applications of alkene complexes of group 9 transition metals in [2+2+2] cycloaddition reactions.Synthesis of indolizidines from optically pure α-amino acids via stereocontrolled rhodium-catalyzed hydroformylation of N-allylpyrroles.Alkenes in [2+2+2] Cycloadditions.Homogeneous rhodium(i)-catalysis in de novo heterocycle syntheses.Perfluorinated Taddol Phosphoramidite as an L,Z-Ligand on Rh(I) and Co(-I): Evidence for Bidentate Coordination via Metal-C6F5 Interaction.Enantioselective Synthesis of the Tricyclic Core of FR901483 Featuring a Rh-Catalyzed [2+2+2] Cycloaddition.A catalytic asymmetric synthesis of polysubstituted piperidines using a rhodium(I)-catalyzed [2+2+2] cycloaddition employing a cleavable tether.Enantioselective rhodium-catalyzed [4+2] cycloaddition of α,β-unsaturated imines and isocyanates.Enantioselective rhodium-catalyzed [4+2+2] cycloaddition of dienyl isocyanates for the synthesis of bicyclic azocine rings Metal-free [3 + 2 + 1]/[2 + 2 + 1] biscyclization: stereospecific construction with concomitant functionalization of indolizin-5(1H)-one.Excess substrate is a spectator ligand in a rhodium-catalyzed asymmetric [2 + 2 + 2] cycloaddition of alkenyl isocyanates with tolanes Catalytic, asymmetric indolizidinone aza-quaternary stereocenter synthesis: expedient synthesis of the cylindricine alkaloid core Phosphoramidite-Rhodium Complexes as Catalysts for the Asymmetric [2+2+2] Cycloaddition of Alkenyl Isocyanates and Alkynes.Rhodium-catalyzed oxidative cycloaddition of benzamides and alkynes via C-H/N-H activation.Atroposelective [2+2+2] cycloadditions catalyzed by a rhodium(I)-chiral phosphate system.A general strategy for the catalytic, highly enantio- and diastereoselective synthesis of indolizidine-based alkaloids.Enantioselective Aza-Sakurai Cyclizations: Dual Role of Thiourea as H-Bond Donor and Lewis Base.

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P2860

Enantioselective Rhodium-Catalyzed [2 + 2 + 2] Cycloadditions of Terminal Alkynes and Alkenyl Isocyanates: Mechanistic Insights Lead to a Unified Model that Rationalizes Product Selectivity

http://www.wikidata.org/entity/Q28468194

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2009 nî lūn-bûn

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2009 թուականի Նոյեմբերին հրատարակուած գիտական յօդուած

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2009 թվականի նոյեմբերին հրատարակված գիտական հոդված

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2009年の論文

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2009年論文

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2009年論文

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2009年論文

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2009年論文

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2009年論文

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2009年论文

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Enantioselective Rhodium-Catal ...... tionalizes Product Selectivity

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Enantioselective Rhodium-Catal ...... tionalizes Product Selectivity

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Enantioselective Rhodium-Catal ...... tionalizes Product Selectivity

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Journal of the American Chemical Society

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Enantioselective Rhodium-Catal ...... tionalizes Product Selectivity

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Derek M. Dalton

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Ernest E. Lee

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Guillaume Malik

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Kevin M. Oberg

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Mark Emil Oinen

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Melissa L. Pease

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Robert T. Yu

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Stéphane Perreault

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P2860

Indolizidine and quinolizidine alkaloids.

Alkaloids from amphibian skin: a tabulation of over eight-hundred compounds.

Synthetic applications of chiral 2,3-dihydro-4-pyridones.

The Domino Way to Heterocycles

The fascinating construction of pyridine ring systems by transition metal-catalysed [2 + 2 + 2] cycloaddition reactions.

Regioselective rhodium-catalyzed intermolecular [2+2+2] cycloaddition of alkynes and isocyanates to form pyridones

A theoretical study of steric and electronic effects in the rhodium-catalyzed carbonylation reactions.

Total synthesis of indolizidine alkaloid (-)-209D: overriding substrate bias in the asymmetric rhodium-catalyzed [2+2+2] cycloaddition.

Predictable and regioselective insertion of internal unsymmetrical alkynes in rhodium-catalyzed cycloadditions with alkenyl isocyanates.

Enantioselective synthesis of indolizidines bearing quaternary substituted stereocenters via rhodium-catalyzed [2+2+2] cycloaddition of alkenyl isocyanates and terminal alkynes.

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15717-15728

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scholarly article

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10.1021/JA905065J

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43

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131

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2009-11-04T00:00:00Z

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26883310

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19817441

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enantioselectivity

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2796191

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