Palladium-catalysed transannular C-H functionalization of alicyclic amines
about
Native functionality in triple catalytic cross-coupling: sp³ C-H bonds as latent nucleophilesAssociative Covalent Relay: An Oxadiazolone Strategy for Rhodium(III)-Catalyzed Synthesis of Primary Pyridinylamines.Nickel-Catalyzed Esterification of Aliphatic Amides.Palladium-Catalyzed Transformations of Alkyl C-H Bonds.Single operation palladium catalysed C(sp3)-H functionalisation of tertiary aldehydes: investigations into transient imine directing groupsIron-Catalyzed Oxyfunctionalization of Aliphatic Amines at Remote Benzylic C-H SitesRemote C(sp3)-H Oxygenation of Protonated Aliphatic Amines with Potassium Persulfate.Nickel-Catalyzed Reduction of Secondary and Tertiary Amides.Breaking Amides using Nickel Catalysis.Ruthenium(II)-catalysed remote C-H alkylations as a versatile platform to meta-decorated arenesA unique Pd-catalysed Heck arylation as a remote trigger for cyclopropane selective ring-openingAmide-directed photoredox-catalysed C-C bond formation at unactivated sp3 C-H bonds.Pd-Catalyzed γ-C(sp3)-H Arylation of Free Amines Using a Transient Directing Group.Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer.Synthesis of Diverse 11- and 12-Membered Macrolactones from a Common Linear Substrate Using a Single Biocatalyst.Complementary Strategies for Directed C(sp3 )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer.The underlying factors controlling the Pd-catalyzed site-selective alkenylation of aliphatic amines.meta-C-H Bromination on Purine Bases by Heterogeneous Ruthenium Catalysis.General, Mild, and Selective Method for Desaturation of Aliphatic Amines.Selective Palladium(II)-Catalyzed Carbonylation of Methylene β-C-H Bonds in Aliphatic Amines.Buttressing Salicylaldehydes: A Multipurpose Directing Group for C(sp3 )-H Bond Activation.Remote C-H Functionalization by a Palladium-Catalyzed Transannular Approach.Direct α-C-H bond functionalization of unprotected cyclic amines.Palladium-Catalyzed Pyrazole-Directed sp3 C-H Bond Arylation for the Synthesis of β-Phenethylamines.General, Auxiliary-Enabled Photoinduced Pd-Catalyzed Remote Desaturation of Aliphatic Alcohols.Synthesis of Bicyclo[n.1.0]alkanes by a Cobalt-Catalyzed Multiple C(sp3 )-H Activation Strategy.Palladium-catalyzed aerobic (1+2) annulation of Csp3-H bonds with olefin for the synthesis of 3-azabicyclo[3.1.0]hex-2-ene.Ruthenium(II)-Catalyzed meta C-H Mono- and Difluoromethylations by Phosphine/Carboxylate Cooperation.Remote, Late-Stage Oxidation of Aliphatic C-H Bonds in Amide-Containing Molecules.Synthesis of 3-azabicyclo[3.1.0]hexane derivatives via palladium-catalyzed cyclopropanation of maleimides with N-tosylhydrazones: practical and facile access to CP-866,087.Second-Generation Palladium Catalyst System for Transannular C-H Functionalization of Azabicycloalkanes.Ligand-Enabled γ-C(sp3)-H Activation of Ketones.γ-Functionalizations of Amines through Visible-Light-Mediated, Redox-Neutral C-C Bond Cleavage.Oxidative β-C-H sulfonylation of cyclic amines.The α-tertiary amine motif drives remarkable selectivity for Pd-catalyzed carbonylation of β-methylene C-H bonds.Exploring the mechanism of the Pd-catalyzed spirocyclization reaction: a combined DFT and experimental study.Ruthenium(II)-Catalyzed meta C−H Mono- and Difluoromethylations by Phosphine/Carboxylate CooperationKinetic Resolution and Deracemization of Racemic Amines Using a Reductive AminaseDiastereoselective C-H carbonylative annulation of aliphatic amines: a rapid route to functionalized γ-lactams
P2860
Q37422362-CC4EDC4C-0703-455A-81A6-27125BE8884CQ38734826-3657C82E-81A3-4C9B-9E7F-967FCD7593FEQ38798597-0E265D51-2623-4604-980A-DCC57A1CEE10Q39428953-076ABA59-2701-4326-87D5-E515576CE77EQ41671104-15AECB8C-DE05-48D9-90FD-1E1959C65F98Q42056766-E402FBEA-F61E-4A93-9523-FAAA435BBC6CQ42155995-A564A19A-446A-4C5F-B625-ABC43865E0B2Q42187326-6333F1E3-DF50-4A55-A9AB-C506B5D86078Q42199307-781BC42D-906E-474E-B63A-2901C3DEE05EQ42200049-3EA0C13F-CAE3-4CCB-9981-D257C31F33FFQ42321460-3A15E1BB-8621-4166-8D4B-AE28558C5000Q43279712-F01F2E58-C9E9-4FD9-8080-B2F66D4AD026Q43980973-49584EC6-E0DF-4506-9CDC-602D498047A9Q46642667-9A95EB24-F257-4B1E-B751-FF5B6A606EC3Q47108193-16A84844-2843-42B0-89A4-E6A8913B52DDQ47128234-9DAE4719-9EFE-492D-B689-84F2E925217CQ47799904-FB7570BE-8696-40F5-8D0C-02D78FA2415AQ47937781-0CBF95C4-2614-42D7-9DD3-39A759E2B07AQ48050668-8E014054-327A-4469-8B4D-DEE49C129DC0Q48105970-0FB54B48-16B8-40EB-83AA-11E9511D950DQ48127132-CDDD73D8-754A-44FD-B8C3-A95F0D406555Q48141631-0F68BCE8-4061-4AEE-85ED-5E8DDC852AACQ48168186-B7A21EE5-1FF2-4B97-A23E-6398B7E20BAEQ48186924-8BEBB798-352B-4E53-A8F0-2AA877FA9F46Q48198648-231042CB-6F39-4E7A-A2D1-6101403C3809Q48220526-DD849E77-A5C3-44CB-BA3A-44CC2763B128Q48225251-EF470956-3FB9-4A1F-9435-C29A124EA572Q48275055-B9D34403-80EF-4E67-A472-F494B472FAF4Q48330567-8F53D465-3487-42E0-9F90-E0EB426B3751Q48330898-AF229E94-23EE-463D-974F-CA54450B1A93Q48347192-69C98040-D399-47C7-90CA-FCA6ED37F6B9Q52590108-41DCE304-24E3-4DA4-8BF2-B70C2A3825F3Q52685327-B216C403-AB1D-4359-AA3B-EC35F2481D94Q52765215-8B0D9F13-7CF3-44E4-A1CE-31E82AB759CBQ54943497-DF33948A-D826-4275-84B5-18C1DA4C6BA3Q55013276-43C2555F-9203-4291-B487-9A68E7DAE22BQ55262006-9D2B7652-E718-4CAF-BB03-7561DF7F9C9FQ57905598-E7C4C74E-3E77-49DC-A51A-F90934BCB6A8Q58048461-5773C1C6-7345-4D54-BFA1-1D574D1BF32FQ58567639-7012785F-8416-4825-8288-EA93EC947551
P2860
Palladium-catalysed transannular C-H functionalization of alicyclic amines
description
2016 nî lūn-bûn
@nan
2016 թուականի Մարտին հրատարակուած գիտական յօդուած
@hyw
2016 թվականի մարտին հրատարակված գիտական հոդված
@hy
2016年の論文
@ja
2016年論文
@yue
2016年論文
@zh-hant
2016年論文
@zh-hk
2016年論文
@zh-mo
2016年論文
@zh-tw
2016年论文
@wuu
name
Palladium-catalysed transannular C-H functionalization of alicyclic amines
@ast
Palladium-catalysed transannular C-H functionalization of alicyclic amines
@en
type
label
Palladium-catalysed transannular C-H functionalization of alicyclic amines
@ast
Palladium-catalysed transannular C-H functionalization of alicyclic amines
@en
prefLabel
Palladium-catalysed transannular C-H functionalization of alicyclic amines
@ast
Palladium-catalysed transannular C-H functionalization of alicyclic amines
@en
P2860
P356
P1433
P1476
Palladium-catalysed transannular C-H functionalization of alicyclic amines
@en
P2093
Joseph J Topczewski
Pablo J Cabrera
P2860
P2888
P356
10.1038/NATURE16957
P407
P577
2016-03-10T00:00:00Z
P6179
1005933867