Pentafluorophenylboranes: from obscurity to applications
about
From group 13-group 13 donor-acceptor bonds to triple-decker cations.Fluorinated antimony(v) derivatives: strong Lewis acidic properties and application to the complexation of formaldehyde in aqueous solutions.A unified survey of Si-H and H-H bond activation catalysed by electron-deficient boranes.A Combined Experimental/Computational Study of the Mechanism of a Palladium-Catalyzed Bora-Negishi Reaction.B(C6F5)3: A Lewis Acid that Brings the Light to the Solid State.Acylboranes: synthetic strategies and applications.Frustrated Lewis Pair Chemistry: Searching for New Reactions.Exploring the fate of the tris(pentafluorophenyl)borane radical anion in weakly coordinating solvents.Boron-Catalyzed N-Alkylation of Amines using Carboxylic Acids.Electrophilic bis-fluorophosphonium dications: Lewis acid catalysts from diphosphinesTetraarylborate polymer networks as single-ion conducting solid electrolytes.A computational and conceptual DFT study on the mechanism of hydrogen activation by novel frustrated Lewis pairs.Bulky derivatives of boranes, boronic acids and boronate esters via reaction with diazomethanes.Reaction of strongly electrophilic alkenylboranes with phosphanylalkynes: rare examples of intermolecular 1,1-alkenylboration reactions.Synthesis and Lewis acid properties of a ferrocene-based planar-chiral borenium cation.H(OEt2)2[P(1,2-O2C6Cl4)3]: synthesis, characterization, and application as a single-component initiator for the carbocationic polymerization of olefins.Formation of a bifunctional zirconocene complex that favours intramolecular -B(C6F5)2 addition to a Cp ring over sigma-ligand abstraction.A di-substituted boron dication and its hydride-induced transformation to an NHC-stabilized borabenzene.(CF3 )3 Au as a Highly Acidic Organogold(III) Fragment.Color tuning in polymer light-emitting diodes with Lewis acids.Aluminum Hydride Catalyzed Hydroboration of Alkynes.Lewis acid catalysis: catalytic hydroboration of alkynes initiated by Piers' borane.Synthesis of a silylium zwitterion.Catalytic Borylation using an Air-Stable Zinc Boryl Reagent: Systematic Access to Elusive Acylboranes.Σ- versus π-activation of alkynyl benzoates using B(C₆F₅)₃.Reactions of iodine-nitrene reagents with boranes.Expanded-ring N-heterocyclic carbenes for the stabilization of highly electrophilic gold(I) cations.Formylborane formation with frustrated Lewis pair templates.Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept.Synthesis and structure of amido- and imido(pentafluorophenyl)borane zirconocene and hafnocene complexes: N-H and B-H activation.Tris(perfluorotolyl)borane-A Boron Lewis Superacid.Stoichiometric and Catalytic C-C and C-H Bond Formation with B(C6 F5 )3 via Cationic Intermediates.Room temperature transmetallation from tris(pentafluorophenyl)borane to cyclometallated iridium(iii).An ambiphilic phosphine/H-bond donor ligand and its application to the gold mediated cyclization of propargylamides.Selective C-O Bond Cleavage of Sugars with Hydrosilanes Catalyzed by Piers' Borane Generated In Situ.3-Silylated cyclohexa-1,4-dienes as precursors for gaseous hydrosilanes: the B(C6 F5)3-catalyzed transfer hydrosilylation of alkenes.The Propargyl Rearrangement to Functionalised Allyl-Boron and Borocation Compounds.Photo Lewis acid generators: photorelease of B(C6F5)3 and applications to catalysis.Reactivity of a frustrated lewis pair and small-molecule activation by an isolable Arduengo carbene-B{3,5-(CF3)2C6H3}3 complex.A Catalyst Platform for Unique Cationic (Co)Polymerization in Aqueous Emulsion.
P2860
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P2860
Pentafluorophenylboranes: from obscurity to applications
description
1997 թուականին հրատարակուած գիտական յօդուած
@hyw
1997 թվականին հրատարակված գիտական հոդված
@hy
artículu científicu espublizáu en 1997
@ast
im Januar 1997 veröffentlichter wissenschaftlicher Artikel
@de
scientific article (publication date: 1997)
@en
wetenschappelijk artikel (gepubliceerd in 1997)
@nl
наукова стаття, опублікована в 1997
@uk
مقالة علمية (نشرت عام 1997)
@ar
name
Pentafluorophenylboranes: from obscurity to applications
@ast
Pentafluorophenylboranes: from obscurity to applications
@en
type
label
Pentafluorophenylboranes: from obscurity to applications
@ast
Pentafluorophenylboranes: from obscurity to applications
@en
prefLabel
Pentafluorophenylboranes: from obscurity to applications
@ast
Pentafluorophenylboranes: from obscurity to applications
@en
P356
P1476
Pentafluorophenylboranes: from obscurity to applications
@en
P2093
Tristram Chivers
Warren E. Piers
P356
10.1039/CS9972600345
P577
1997-01-01T00:00:00Z