Alkane C–H activation and functionalization with homogeneous transition metal catalysts: a century of progress—a new millennium in prospect
about
Catalytic oxy-functionalization of methane and other hydrocarbons: fundamental advancements and new strategies.Formation of a C-C double bond from two aliphatic carbons. Multiple C-H activations in an iridium pincer complex.Enzymatic functionalization of carbon-hydrogen bonds.A panel of cytochrome P450 BM3 variants to produce drug metabolites and diversify lead compounds.Gas-phase catalysis by atomic and cluster metal ions: the ultimate single-site catalysts.Diastereotopos-differentiating C-H activation reactions at methylene groups.Regioselectivity of the borylation of alkanes and arenes.If C-H bonds could talk: selective C-H bond oxidationC-H activation: a complementary tool in the total synthesis of complex natural products.Catalytic, mild, and selective oxyfunctionalization of linear alkanes: current challenges.Organometallic aspects of transition-metal catalysed regioselective C-H bond functionalisation of arenes and heteroarenes.Catalytic C-H bond functionalisation of purine and pyrimidine nucleosides: a synthetic and mechanistic perspective.Discrepancy Between Experimental and Theoretical Predictions of the Adiabaticity of Ti+ +CH3 OH.Carboxylic Acids as Directing Groups for C-H Bond Functionalization.Strain release in C-H bond activation?Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex.Rhodium(III)-Catalyzed Allylic C(sp(3))-H Activation of Alkenyl Sulfonamides: Unexpected Formation of Azabicycles.A Highly Selective Vanadium Catalyst for Benzylic C-H Oxidation.Potassium-alkane interactions within a rigid hydrophobic pocket.Rhodium bis(quinolinyl)benzene complexes for methane activation and functionalization.Two complexes derived from the reaction of M3(CO)12 clusters (M = Ru, Os) with the 9-(triphenylphosphonio)fluorenide ylide: tricarbonyl[9-(triphenylphosphonio)fluorenylidene]ruthenium and nonacarbonyl-μ3-fluorenylidene-μ2-hydrido-triangulo-triosmiumTheoretical study of reaction pathways for the rhodium phosphine-catalysed borylation of C-H bonds with pinacolborane.Activation of carbon-hydrogen bonds and dihydrogen by 1,2-CH-addition across metal-heteroatom bonds.Transition metal complexes of the chelating phosphine borane ligand Ph2PCH2Ph2P.BH3.Microwave-promoted rhodium-catalyzed arylation of heterocycles through C--H bond activation.Observation of Spontaneous C=C Bond Breaking in the Reaction between Atomic Boron and Ethylene in Solid Neon.Coordination chemistry of Co complexes containing tridentate SNS ligands and their application as catalysts for the oxidation of n-octane.Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes.Contrasting electronic requirements for C-H binding and C-H activation in d(6) half-sandwich complexes of rhenium and tungsten.Copper-Catalyzed Oxidative Dehydrogenative C(sp3 )-H Bond Amination of (Cyclo)Alkanes using NH-Heterocycles as Amine Sources.A whole cell biocatalyst for double oxidation of cyclooctane.Aroylhydrazone Cu(II) Complexes in keto Form: Structural Characterization and Catalytic Activity towards Cyclohexane Oxidation.Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes.Csp3 -H Activation without Chelation Assistance in an Iridium Pincer Complex Forming Cyclometallated Products.Divergent reactivity of platinum(ii) and palladium(ii) methylperoxo complexes and the formation of an unusual hemi-aminal complex.Alkane Activation Initiated by Hydride Transfer: Co-conversion of Propane and Methanol over H-ZSM-5 Zeolite.Combined experimental and theoretical investigation into C-H activation of cyclic alkanes by Cp'Rh(CO)2 (Cp' = η5-C5H5 or η5-C5Me5).Oxy-functionalization of Group 9 and 10 transition metal methyl ligands: use of pyridine-based hemi-labile ligandsDFT studies of the methyl exchange reaction between Cp2M–CH3or Cp*2M–CH3(Cp = C5H5, Cp* = C5Me5, M = Y, Sc, Ln) and CH4. Does M ionic radius control the reaction?Methyltransferase Activity of an Iridium Center with Methylpyridinium as Methylene Source
P2860
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P2860
Alkane C–H activation and functionalization with homogeneous transition metal catalysts: a century of progress—a new millennium in prospect
description
2001 nî lūn-bûn
@nan
2001 թուականին հրատարակուած գիտական յօդուած
@hyw
2001 թվականին հրատարակված գիտական հոդված
@hy
2001年の論文
@ja
2001年論文
@yue
2001年論文
@zh-hant
2001年論文
@zh-hk
2001年論文
@zh-mo
2001年論文
@zh-tw
2001年论文
@wuu
name
Alkane C–H activation and func ...... s—a new millennium in prospect
@ast
Alkane C–H activation and func ...... s—a new millennium in prospect
@en
type
label
Alkane C–H activation and func ...... s—a new millennium in prospect
@ast
Alkane C–H activation and func ...... s—a new millennium in prospect
@en
prefLabel
Alkane C–H activation and func ...... s—a new millennium in prospect
@ast
Alkane C–H activation and func ...... s—a new millennium in prospect
@en
P356
P1476
Alkane C–H activation and func ...... s—a new millennium in prospect
@en
P2093
Robert H. Crabtree
P304
P356
10.1039/B103147N
P577
2001-01-01T00:00:00Z