Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex
about
How many metals does it take to fix N2? A mechanistic overview of biological nitrogen fixationSynthesis of ammonia directly from air and water at ambient temperature and pressureDinitrogen dissociation on an isolated surface tantalum atom.Infrared spectra and density functional theory calculations of the tantalum and niobium carbonyl dinitrogen complexes.N₂reduction and hydrogenation to ammonia by a molecular iron-potassium complex.Catalytic conversion of nitrogen to ammonia by an iron model complex.Metal-dioxygen and metal-dinitrogen complexes: where are the electrons?Inner-sphere two-electron reduction leads to cleavage and functionalization of coordinated dinitrogen.Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron.Theoretical studies of structure, function and reactivity of molecules--a personal account.Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen.Catalytic NH3 synthesis using N2/H2 at molecular transition metal complexes - concepts for lead structure determination using computational chemistry.N-H Bond Dissociation Enthalpies and Facile H Atom Transfers for Early Intermediates of Fe-N2 and Fe-CN Reductions.A [Fe(CB6)] platform for binding of small molecules: insights from DFT calculations.η(6) -Arene-Zirconium-PNP-Pincer Complexes: Mechanism of Their Hydrogenolytic Formation and Their Reactivity as Zirconium(II) Synthons.Facile Uptake and Release of Ammonia by Nickel Halide AmminesH-H and Si-H bond addition to Fe≡NNR2 intermediates derived from N2.Dissolved N(2) sensing by pH-dependent Ru complexes.Fast and reversible insertion of carbon dioxide into zirconocene-alkoxide bonds. A mechanistic study.Towards Catalytic Ammonia Oxidation to Dinitrogen: A Synthetic Cycle by Using a Simple Manganese Complex.Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex.Redox-induced N2 hapticity switching in zirconocene dinitrogen complexes.Non-dissociative activation of chemisorbed dinitrogen on Ni{110} by co-adsorbed lithium.Mononuclear iridium dinitrogen complexes bonded to zeolite HY.Tris(polyalkylcyclopentadienyl) complexes: the elusive [(η5-C5R5)2M(η1-C5R5)] structure and trihapto cyclopentadienyl coordination involving a methyl substituent.Structural analysis of zincocenes with substituted cyclopentadienyl rings.The importance of a single methyl group in determining the reaction chemistry of pentamethylcyclopentadienyl cyclooctatetraenyl uranium metallocenes.Activation and protonation of dinitrogen at the FeMo cofactor of nitrogenase.NH3 Synthesis in the N2/H2 Reaction System using Cooperative Molecular Tungsten/Rhodium Catalysis in Ionic Hydrogenation: A DFT Study.Direct Synthesis of Silylamine from N2 and a Silane: Mediated by a Tridentate Phosphine Molybdenum Fragment.Coordination Behavior of [Cp''2 Zr(η1:1 -P4 )] towards Different Lewis Acids.Different Reactivity of As4 towards Disilenes and Silylenes.Conversion of Dinitrogen to Nitriles at a Multinuclear Titanium Framework.Dinitrogen functionalization with bis(cyclopentadienyl) complexes of zirconium and hafnium.C-H and H-H activation at a di-titanium centre.Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes.Catalytic Dinitrogen Reduction to Ammonia at a Triamidoamine-Titanium Complex.Efficient ammonia synthesis over a Ru/La0.5Ce0.5O1.75 catalyst pre-reduced at high temperature.Dinitrogen cleavage and hydrogenation by a trinuclear titanium polyhydride complex.Increased thermal stability of activated N2 adsorbed on K-promoted Ni{110}.
P2860
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P2860
Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex
description
2004 թուականի Փետրուարին հրատարակուած գիտական յօդուած
@hyw
2004 թվականի փետրվարին հրատարակված գիտական հոդված
@hy
article publié dans la revue scientifique Nature
@fr
artículu científicu espublizáu en 2004
@ast
scientific article (publication date: 5 February 2004)
@en
wetenschappelijk artikel (gepubliceerd op 2004/02/05)
@nl
наукова стаття, опублікована в лютому 2004
@uk
مقالة علمية (نشرت في 5-2-2004)
@ar
name
Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex
@ast
Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex
@en
type
label
Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex
@ast
Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex
@en
prefLabel
Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex
@ast
Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex
@en
P2093
P356
P1433
P1476
Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex
@en
P2093
Emil Lobkovsky
Jaime A. Pool
Paul J. Chirik
P2888
P304
P356
10.1038/NATURE02274
P407
P577
2004-02-05T00:00:00Z
P6179
1000480079