Boryllithium: isolation, characterization, and reactivity as a boryl anion.
about
BN isosteres of indoleStable GaX2, InX2 and TlX2 radicals.New ligand platforms featuring boron-rich clusters as organomimetic substituents(.)Catalytic methodologies for the β-boration of conjugated electron deficient alkenes.A Combined Experimental/Computational Study of the Mechanism of a Palladium-Catalyzed Bora-Negishi Reaction.Formation and Reactivity of Electron-Precise B-B Single and Multiple Bonds.Formal nucleophilic borylation and borylative cyclization of organic halides.Acylboranes: synthetic strategies and applications.A Tale of Two Elements: The Lewis Acidity/Basicity Umpolung of Boron and Phosphorus.Borylenes: An Emerging Class of Compounds.(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B-H Activation at a Single Metal Center.Easy access to nucleophilic boron through diborane to magnesium boryl metathesis.Ambiphilic boron in 1,4,2,5-diazadiborinine.Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anionBorylation of fluorinated arenes using the boron-centred nucleophile B(CN)32- - a unique entry to aryltricyanoborates.Synthesis and minisci reactions of organotrifluoroborato building blocks.Isolation, structure and reactivity of a scandium boryl oxycarbene complex.Completing the series of boron-nucleophilic cyanoborates: boryl anions of type NHC-B(CN)2.Coordinative trapping of the boron β-diketiminato system [B(NMesCMe)2CH] via metal-templated synthesis.Experimental and theoretical studies on organic D-π-A systems containing three-coordinate boron moieties as both π-donor and π-acceptor.Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines.Single, double, triple bonds and chains: the formation of electron-precise B-B bonds.Divergent reactivity of nucleophilic 1-bora-7a-azaindenide anions.Magnesium Boryl Reactivity with 9-BBN and Ph3 B: Rational B-B' Bond Formation and Diborane Isomerization.A snapshot of inorganic Janovsky complex analogues featuring a nucleophilic boron center.An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH].From Borane to Borylene without Reduction: Ambiphilic Behavior of a Monovalent Silylisonitrile Boron Species.Two-dimensional liquid chromatography of PDMS-PS block copolymers.A generic one-pot route to acyclic two-coordinate silylenes from silicon(IV) precursors: synthesis and structural characterization of a silylsilylene.Catalytic Borylation using an Air-Stable Zinc Boryl Reagent: Systematic Access to Elusive Acylboranes.Boron as a powerful reductant: synthesis of a stable boron-centered radical-anion radical-cation pair.Light group 13 chloride diazadiene complexes: consequences of varying substituent bulk.Isolation of a bis(oxazol-2-ylidene)-phenylborylene adduct and its reactivity as a boron-centered nucleophile.Isolation of a neutral boron-containing radical stabilized by a cyclic (alkyl)(amino)carbene.Boron complexes of redox-active diimine ligand.Assessing the Brønsted basicity of diaminoboryl anions: reactivity toward methylated benzenes and dihydrogen.Alkali metal derivatives of an ortho-phenylene diamine.Diverse reactivity of a tricoordinate organoboron L2PhB: (L = oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors.Quantitative Structure-Activity Relationships for the Nucleophilicity of Trivalent Boron Compounds.A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene.
P2860
Q26863690-8ADF8DF2-BEDC-4051-95B5-218C803E1C6EQ34411198-2034D096-DCBA-426A-9D55-47F4C75B3213Q37354256-E38A352C-B4DC-42D7-8C08-D4F60F7D4D14Q38020331-DBEC65BB-FF45-47D7-99E2-6EF3BF5C523AQ38658819-F222CD7F-52CC-4234-AC81-B78046CB3FE7Q39012417-02E34D25-4393-4CAC-8BCA-6363C534D8D8Q39025528-E4E02D83-BEA2-4CD8-8227-8211CBD9A29AQ39026981-84104F86-DEB8-4239-8E9B-59A1880B7E93Q39134836-CE492DF4-65F9-4185-B573-16B98681BDF9Q39347604-7498CDA1-FD3C-4BCE-B253-8EF31B87F09AQ41105526-ED06B657-40B3-4C91-907A-4293D34B2BE0Q41841828-36495C1E-FA8B-4139-9A95-06EEC70C22C5Q42031036-4FD182D0-F6B6-40B1-A547-1F457775C9F4Q42042236-0685563C-DD39-49D6-8F13-A780DBEBC950Q42055547-861E7C24-090B-4BEA-92B9-4E676CC75650Q42148633-D485A772-8CC7-43E6-9030-7A7CDED12D76Q42250448-AD9DFDE9-40C4-4897-95EB-6AE454203F06Q42279109-34C0726D-1D2B-41F2-9A33-B2009F13BF7EQ43598470-86DB2ACC-6CDD-4420-852C-43AB6BDF7573Q44968672-76FFF7DB-5801-42DB-9212-A1018039A2B7Q45117505-C59B9A98-EECB-41AE-9F09-9FAD655F5D50Q45182515-B9044A68-AAEF-4691-81F1-03E90EDF1DA3Q46241454-A73B2B17-20BE-4ABF-AF4E-045DC351BC68Q46266018-F41995A5-C717-4CC9-8294-3DB97E1C6D1DQ46270406-7CE98118-9464-4649-B286-4A68100C0B38Q46320941-9168E284-05B0-4EE0-9A62-79866E29711DQ46346149-F06C4A30-E72B-4DB7-9E1B-3F5888F6F61BQ46501419-75645F4D-66AE-4679-859D-217FB649939CQ46629627-017FDC43-6864-425E-80B2-CE5EA3C6D79AQ46663171-697B93AF-F8C4-4EB8-B880-7462BEA5EF42Q46815400-4E1E2853-AEF8-4A4F-89E3-6BB3F48C4E51Q46838001-98CEF160-BDD9-4C48-A292-8622FEE79C65Q46872559-D4FD7BB6-C34D-4F92-B5A9-16CCB86D6AE5Q46881189-9B4FA528-6DE7-4AA8-8B32-12B63D4F7957Q46887801-6EFD208C-DC9C-4969-B32C-AC84B821B4E2Q46897413-9B0035E1-0341-471A-9A57-2138FBFC7EA7Q46974338-95038A98-6F61-4107-B26C-4D7318A6552AQ47118434-A230738D-474F-4B31-B199-048798EC5C7CQ48047829-913EABC5-D5EC-470A-8F9F-311A4F8E6AA8Q48108083-A751D295-77C4-418F-8027-AD57863ADB6A
P2860
Boryllithium: isolation, characterization, and reactivity as a boryl anion.
description
2006 nî lūn-bûn
@nan
2006 թուականի Հոկտեմբերին հրատարակուած գիտական յօդուած
@hyw
2006 թվականի հոտեմբերին հրատարակված գիտական հոդված
@hy
2006年の論文
@ja
2006年論文
@yue
2006年論文
@zh-hant
2006年論文
@zh-hk
2006年論文
@zh-mo
2006年論文
@zh-tw
2006年论文
@wuu
name
Boryllithium: isolation, characterization, and reactivity as a boryl anion.
@ast
Boryllithium: isolation, characterization, and reactivity as a boryl anion.
@en
type
label
Boryllithium: isolation, characterization, and reactivity as a boryl anion.
@ast
Boryllithium: isolation, characterization, and reactivity as a boryl anion.
@en
prefLabel
Boryllithium: isolation, characterization, and reactivity as a boryl anion.
@ast
Boryllithium: isolation, characterization, and reactivity as a boryl anion.
@en
P50
P356
P1433
P1476
Boryllithium: isolation, characterization, and reactivity as a boryl anion.
@en
P304
P356
10.1126/SCIENCE.1131914
P407
P577
2006-10-01T00:00:00Z