Asymmetric total synthesis of (+)-aphanamol I based on the transition metal catalyzed [5 + 2] cycloaddition of allenes and vinylcyclopropanes.
about
Propargyltrimethylsilanes as allene equivalents in transition metal-catalyzed [5 + 2] cycloadditions.Reactivity and chemoselectivity of allenes in Rh(I)-catalyzed intermolecular (5 + 2) cycloadditions with vinylcyclopropanes: allene-mediated rhodacycle formation can poison Rh(I)-catalyzed cycloadditionsToward the Ideal Synthesis and Transformative Therapies: The Roles of Step Economy and Function Oriented Synthesis.Metal-catalyzed cycloisomerization as a powerful tool in the synthesis of complex sesquiterpenoids.Synthetic applications of vinyl cyclopropane opening.3-Acyloxy-1,4-enyne: a New Five-carbon Synthon for Rhodium-Catalyzed (5+2) CycloadditionsA Short Synthesis of Aphanamol I in Both Racemic and Enantiopure FormsRhodium-catalyzed intra- and intermolecular [5 + 2] cycloaddition of 3-acyloxy-1,4-enyne and alkyne with concomitant 1,2-acyloxy migrationInterception of a Rautenstrauch intermediate by alkynes for [5+2] cycloaddition: rhodium-catalyzed cycloisomerization of 3-acyloxy-4-ene-1,9-diynes to bicyclo[5.3.0]decatrienes.Rhodium-Catalyzed Stereoselective Intramolecular [5 + 2] Cycloaddition of 3-Acyloxy 1,4-Enyne and Alkene.Intramolecular [1 + 4 + 1] cycloaddition: establishment of the method.Synthesis of the First (1-3:6,7-eta-Cyclodecadienyl)ruthenium Complex by the Intramolecular Reaction of an Alkene and a Vinylcyclopropane We thank the National Science Foundation and the National Institutes of Health (NIH), General Medical Sciences,Rhodium(I)-Catalyzed Bridged [5+2] Cycloaddition of cis-Allene-vinylcyclopropanes to Synthesize the Bicyclo[4.3.1]decane Skeleton.A Boron Alkylidene-Alkene Cycloaddition Reaction: Application to the Synthesis of Aphanamal.Modular Access to the Stereoisomers of Fused Bicyclic Azepines: Rhodium-Catalyzed Intramolecular Stereospecific Hetero-[5+2] Cycloaddition of Vinyl Aziridines and Alkenes.
P2860
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P2860
Asymmetric total synthesis of (+)-aphanamol I based on the transition metal catalyzed [5 + 2] cycloaddition of allenes and vinylcyclopropanes.
description
2000 nî lūn-bûn
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2000 թուականի Յուլիսին հրատարակուած գիտական յօդուած
@hyw
2000 թվականի հուլիսին հրատարակված գիտական հոդված
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2000年の論文
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2000年論文
@yue
2000年論文
@zh-hant
2000年論文
@zh-hk
2000年論文
@zh-mo
2000年論文
@zh-tw
2000年论文
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name
Asymmetric total synthesis of ...... llenes and vinylcyclopropanes.
@ast
Asymmetric total synthesis of ...... llenes and vinylcyclopropanes.
@en
type
label
Asymmetric total synthesis of ...... llenes and vinylcyclopropanes.
@ast
Asymmetric total synthesis of ...... llenes and vinylcyclopropanes.
@en
prefLabel
Asymmetric total synthesis of ...... llenes and vinylcyclopropanes.
@ast
Asymmetric total synthesis of ...... llenes and vinylcyclopropanes.
@en
P356
P1433
P1476
Asymmetric total synthesis of ...... llenes and vinylcyclopropanes.
@en
P2093
P304
P356
10.1021/OL006085Q
P407
P577
2000-07-01T00:00:00Z