Gauche effect in 1,2-difluoroethane. Hyperconjugation, bent bonds, steric repulsion.
about
Understanding organofluorine chemistry. An introduction to the C-F bondConformational analysis of 2,2-difluoroethylamine hydrochloride: double gauche effectGUMBOS matrices of variable hydrophobicity for matrix-assisted laser desorption/ionization mass spectrometry.The chemoenzymatic synthesis of clofarabine and related 2'-deoxyfluoroarabinosyl nucleosides: the electronic and stereochemical factors determining substrate recognition by E. coli nucleoside phosphorylases.Facile carbon-fluorine bond activation and subsequent functionalisation of 1,1-difluoroethylene and tetrafluoroethylene promoted by adjacent metal centres.Transition State Gauche Effects Control the Torquoselectivities of the Electrocyclizations of Chiral 1-AzatrienesConformational impact of structural modifications in 2-fluorocyclohexanone.The preferred conformation of erythro- and threo-1,2-difluorocyclododecanes.Asymmetric nitrene transfer reactions: sulfimidation, aziridination and C-H amination using azide compounds as nitrene precursors.New torsion potential expression for molecules without rotational symmetry.Structural and Conformational Aspects of Equatorial and Axial Trifluoromethyl, Difluoromethyl, and Monofluoromethyl Groups.Can acyclic conformational control be achieved via a sulfur-fluorine gauche effect?DFT Studies on the Stereoselectivity of α-Silyloxy Diazoalkane Cycloadditions.All-cis 1,2,3,4,5,6-hexafluorocyclohexane is a facially polarized cyclohexaneHyperconjugationExperimental and theoretical evaluation of trans-3-halo-2-hydroxy-tetrahydropyran conformational preferences. Beyond anomeric interactionTheoretical and X-ray Crystallographic Evidence of a Fluorine-Imine Gauche Effect: An Addendum to Dunathan’s Stereoelectronic Hypothesis
P2860
Q28264762-003EDE5B-DD38-4C3E-B438-AB4C1D0E42A6Q30811040-694455E4-8A7D-4824-AFC7-9886EAFED95CQ30857223-B592984D-97A6-48C3-A0DA-FC78181E58B3Q34082241-73457873-4544-44F1-ADFC-C2B8242DC474Q34179624-E2ADDB3A-F864-4132-AC59-ADC78AEBE813Q41382289-D7BFA12C-5071-4995-BC46-0E2FB57992C9Q41592871-47E57C98-2BD2-4B9A-8CC8-6C74DC97DA91Q42610635-030E114B-6EE1-435B-AC97-12F48F7FCC56Q46943397-EB37FDF3-EBF8-4462-9186-E1C605ACB106Q47636135-8A5935FB-97BD-4F61-9AB3-ECAA14A7E5CDQ48054047-FD289504-7A74-471E-A416-C86C8A0A8ACAQ51579508-3307A026-737F-4EB1-B720-C31EB34AFE0EQ51619092-F80E2139-116B-492F-8279-D075969C00FFQ56638413-714511D2-1040-4B48-88BC-E7E913B81425Q57407820-4E7B8A12-E3C0-4145-8408-3B57DB005A16Q57782678-D8ABC8B5-9712-4792-9EB4-37E62CF7C1F4Q57971608-02C6B1F2-1F44-4EFD-AD47-EF8FC076EA90
P2860
Gauche effect in 1,2-difluoroethane. Hyperconjugation, bent bonds, steric repulsion.
description
2005 nî lūn-bûn
@nan
2005 թուականի Փետրուարին հրատարակուած գիտական յօդուած
@hyw
2005 թվականի փետրվարին հրատարակված գիտական հոդված
@hy
2005年の論文
@ja
2005年論文
@yue
2005年論文
@zh-hant
2005年論文
@zh-hk
2005年論文
@zh-mo
2005年論文
@zh-tw
2005年论文
@wuu
name
Gauche effect in 1,2-difluoroethane. Hyperconjugation, bent bonds, steric repulsion.
@ast
Gauche effect in 1,2-difluoroethane. Hyperconjugation, bent bonds, steric repulsion.
@en
type
label
Gauche effect in 1,2-difluoroethane. Hyperconjugation, bent bonds, steric repulsion.
@ast
Gauche effect in 1,2-difluoroethane. Hyperconjugation, bent bonds, steric repulsion.
@en
prefLabel
Gauche effect in 1,2-difluoroethane. Hyperconjugation, bent bonds, steric repulsion.
@ast
Gauche effect in 1,2-difluoroethane. Hyperconjugation, bent bonds, steric repulsion.
@en
P2093
P356
P1476
Gauche effect in 1,2-difluoroethane. Hyperconjugation, bent bonds, steric repulsion.
@en
P2093
Hongbing Gu
Lionel Goodman
Vojislava Pophristic
P304
P356
10.1021/JP046290D
P407
P577
2005-02-01T00:00:00Z